Transport of water in frozen soil: V, Method for measuring the vapor diffusivity when ice is absent

A new experimental method is introduced for determining the relative magnitudes of liquid and vapor diffusion by using a small amount of soluble chemical as a tracer. The theoretical justification of the method is presented for the case where ice is absent. The feasibility of the method is demonstrated by an experiment using marine-deposited clay.     

岩浆不混溶的物理化学条件—以河北阳原杂岩体为例

本文主要讨论了岩浆不混溶的内在因素和物化条件。研究提出阳原杂岩大于零的过剩自由能是出现不混溶的内在原因。岩浆中高P_2O_5、TiO_2、Zr、Hf、Ta、REE是岩浆不混溶的诱导因素。化学位计算揭示了球状黑云辉石正长岩之球体、基质两相及正长质和辉石质岩浆单元在液态时曾处于平衡状态。岩浆不混溶可能是在温度约1200℃、上地壳深度范围内发生的。阳原母岩浆不混溶的两液相可以分离聚集成两大岩浆单元,岩浆分溶不充分,便产生中间成分的黑云辉石正长岩。     

Efficiency of heavy liquid separation to concentrate magnetic particles

Low-temperature rock magnetic measurements have distinct diagnostic value. However, in most bulk marine sediments the concentration of ferrimagnetic and antiferromagnetic minerals is extremely low, so even sensitive instrumentation often responds to the paramagnetic contribution of the silicate matrix in the residual field of the magnetometer. Analysis of magnetic extracts is usually performed to solve the problems raised by low magnetic concentrations. Additionally magnetic extracts can be used for several other analyses, for example electron microscopy or X-ray diffraction. The magnetic extraction technique is generally sufficient for sediments dominated by magnetite. In this study however, we show that high-coercivity components are rather underrepresented in magnetic extracts of sediments with a more complex magnetic mineralogy. We test heavy liquid separation, using hydrophilic sodium polytungstenate solution Na₆[H₂W₁₂O₄₀], to demonstrate the efficiencies of both concentration techniques. Low-temperature cycling of zero-field-cooled, field-cooled and saturation isothermal remanent magnetization acquired at room temperature was performed on dry bulk sediments, magnetic extracts, and heavy liquid separates of clay-rich pelagic sediments originating from the Equatorial Atlantic. The results of the thermomagnetic measurements clarify that magnetic extraction favours components with high spontaneous magnetization, such as magnetite and titanomagnetite. The heavy liquid separation is unbiased with respect to high- and low-coercive minerals, thus it represents the entire magnetic assemblage.     

Progress in isotope paleohydrology using lake sediment cellulose

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.     

水平地震激励下储罐液体晃动与提离分析

在考虑地基与储罐相互作用的情况下,采用有限元法对储罐在水平地震荷载作用下的液面晃动及储罐提离反应进行了分析。结果表明:罐内液体的晃动是长周期运动,其周期受地震动影响。无论是小体积罐还是大体积罐,在一定的地震烈度下均可以发生提离,而且储罐发生提离的时刻大多数是在地震动的峰值过后的一段时间内。大体积的储罐的提离明显小于小体积的罐。底板提离区域为月牙形。     

用雷达垂直累积液态含水量资料预测冰雹

通过对雷达垂直累积液态含水量的资料进行总结、分析，阐述了垂直累积液态含水量的大小和面积与对流性天气的关系。并且利用多元回归的方法，建立了预报方程。     

铼—锇同位素分析中试样化学预处理方法进展

评述了用于Re-Os同位素体系分析的化学前处理技术的发展。简要介绍了卡洛斯管熔样法、Os的CCl4提取、溴提取和微蒸馏方法。卡洛斯管封闭熔样方法，有效地防止了Os的挥发损失和保证了Os同位素平衡，是一种很有发展前景的熔样方法。蒸馏法仍是分离和纯化Os的有效方法，溶剂（CCl4)提取和溴提取法在许多实验室里应用，而微蒸馏则是Os的二次纯化的主要方法。Re的化学分离和纯化仍是离子交换和萃取法。引用主要文献29篇。     

利用地基双通道微波辐射计遥感青藏高原大气云水特征

利用1997年春季西宁市地基双通道（22．235和35．3GHz)微波辐射计观测的资料，分析了不同月份、不同天气条件下的大气总含水量（V）和云中液态水积分含量（L）的分布规律。结果表明，在相同天气条件下，L值3－5月均呈逐渐递增的趋势，增加幅度一般为20％－40％，V值变化幅度很小；春季高原L值大约只有V的1%。与河北省的资料进行对比后发现，L值基本相当，而V值高原只有平原地区的30％－50％。     

低本底液闪仪计算机控制系统的改进

新研制改进的低本底液闪计算机控制系统，具有数据获取和数据处理、实时能谱测量、谱显示选取工作点以及测量中断后继续测量等功能，从而使液闪仪的自动化和智能化程度得到了进一步提高。     

硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。