低品位氧化钴矿石钴的赋存状态和浸取实验研究

基于我国钴资源分布分散、且多为伴生、品位低的现状，对某铜钴矿化区钴矿石中的钴碳酸盐矿物、含钴铁氧化物和具有吸附态的粘土矿物进行了钴的赋存状态和浸取试验研究，查明了钴的赋存状态，并以此为依据，运用逐一条件试验和正交试验相互验证的办法，确定了最优化的浸取试验方案，该方法对此低品位氧化钴矿石中钴的浸出率达到90%以上。     

Prediction of minesite-drainage chemistry through closure using operational monitoring data

Post-mining drainage chemistry depends strongly on geochemical and hydrologic processes that occur during the operational years. Where routine operational monitoring data are abundant, the dominant processes can often be evaluated with no additional, special studies. Thus, post-mining drainage chemistry can be predicted with confidence based on the operational data. This is referred to here as ‘empirical drainage-chemistry modelling’ (EDCM).This paper presents examples of EDCM using routine monitoring databases from several minesites, each containing thousands of analyses and spanning up to 30 years of mine operation and closure. Simple statistical interpretations in the EDCM can reveal annual cycles and trends that aqueous concentrations display during operation and into closure.A new compilation of 12 EDCM equations for copper versus pH is presented to illustrate similar trends with pH among the sites. However, this compilation also shows that average-annual copper concentrations at a particular pH can vary by three orders of magnitude, reflecting site-specific factors. Also, a new case study comparing actual closure concentrations to those predicted with EDCM in 1991 demonstrates that predictive accuracy is within a factor of two.     

某砂岩型铀矿床原地浸出采矿的地质及水文地质条件可行性探讨

本文引用大量实际资料同国内外同类型铀矿床采用原地浸出采矿的各种条件进行了对比研究,得出了内蒙古某砂岩型铀矿床基本具备原地浸出采矿的地质和水文地质条件的结论,并提出了今后工作设想和建议。     

Economic aspects of pad construction costs on heap leach projects

Summary Pad construction costs can affect the overall economics of heap leach projects. Costs for single- and double-lined pads, using various designs, are listed for a typical small and large project. Double-lined pads are now frequently required by regulatory agencies. Unless such designs significantly reduce the risk of site-specific contamination, the extra costs cannot be justified from an economical viewpoint. Specific attention is given to the short project life (typically five years) of heap leach projects. A few numerical examples are presented to demonstrate the overall impact of these costs on economic parameters.     

贵州猫场超大型铝土矿床成因浅析

猫场铝土矿床位于大威岭背斜北东端猫场穹窿背斜。由于寒武系碳酸盐岩古喀斯特侵蚀面,经长期风化溶蚀淋滤作用,在古喀斯特正地形上先形成粘土层,粘土层进一步风化溶蚀经脱硅、脱铁形成三水铝石的矿源层,而古喀斯特负地形则为铝土矿的沉积提供了充足的场所。本文通过对含矿岩系的特征分析,结合沉积相与古地理环境等研究,揭示了猫场铝土矿床的形成严格受大地构造和古喀斯特地形的控制。     

控制砂岩型铀矿床中铀迁移转化的主要水文地球化学作用实验

采集中国北方某砂岩型铀矿床中的含铀矿石样品,共进行7组土柱模拟实验,分别探究氧化-还原条件、HCO-3浓度、有机质和微生物对铀迁移转化的影响。结果表明:氧化-还原条件改变对铀迁移转化会产生重要影响,含氧入渗水带来的氧化环境使含水介质中沉淀态铀大量氧化溶解;HCO-3的促解吸作用及铀酰络合物的强迁移能力对地下水中铀迁移转化影响较大;有机质会参与含水介质中矿物吸附点位竞争,从而造成铀的解吸;微生物作为氧化-还原反应的催化剂,在氧化剂氧化沉淀态铀的反应中起重要作用;氧化作用、解吸作用和溶解作用对地下水中铀迁移转化的贡献比例分别为65.28%、23.91%和10.81%。     

酸洗法测定海洋沉积物有机碳和无机碳含量的致命缺陷

Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments.     

浸矿开采对离子型稀土基岩力学特性的影响研究

为研究原地浸矿母液对离子型稀土矿收液底板的侵蚀影响,以离子型稀土矿基岩（半/弱风化花岗岩）为研究对象,开展了室内浸矿模拟试验。对比分析了不同浸矿时间岩样的应力−应变曲线、峰值应力、峰值应变和弹性模量,获取了不同浸矿历时岩样的孔隙度和细观形貌特征,并运用盒维法对岩样的非线性裂纹特征进行了定量化描述。结果表明：浸矿侵蚀作用对离子型稀土矿底板基岩力学性质的影响主要表现在前150 d,破坏形式由贯穿破坏转变为贯穿破坏与片状剥落并存;浸矿母液侵蚀作用下,基岩力学特性呈现先大幅减小后大幅回升,其后在小范围波动现象,浸矿约60 d对基岩力学特性的影响程度最大;浸矿母液侵蚀造成基岩内小孔隙增长,导致表面出现腐蚀及孔洞现象;浸矿时间不同将造成岩石不同的微观结构变化。     

淋溶时间对红黏土物理力学特性的影响

以湖北省鄂州市庙岭镇的红黏土为研究对象,以化学选择溶解法结合淋溶作用为处理手段,将原状土样中的游离氧化铁按梯度去除,获得连二亚硫酸钠-柠檬酸钠-碳酸氢钠(DCB)溶液淋溶时间与除铁率的关系,并分析了不同淋溶时间对红黏土物理力学特性及微观孔隙结构的影响。试验结果表明,DCB溶液淋溶时间与除铁率相关性较强,除铁率与时间呈先快速增长后逐渐稳定的关系。由于游离氧化铁在土颗粒间主要起胶结作用,故淋溶时间对红黏土的物理力学特性有较大影响。随着淋溶时间的增长,黏粒与胶粒含量逐渐增大,耐热性小幅提升,无侧限抗压强度显著减小,且无侧限抗压强度变化整体趋势为前期急剧降低至后期趋于平稳。核磁共振、差热分析和电镜扫描的结果表明,随着淋溶时间的增大,庙岭红黏土内部孔隙增大,自由水减少,结合水增多,微观形态上团粒结构遭到破坏,胶结物质明显减少,结构形式从紧凑的粒团堆叠结构逐渐转化为聚集体-松散颗粒状结构。     

沉积型铝土矿原位溶浸技术可行性分析及开采设想

沉积型铝土矿是我国主要的铝土矿类型,经过几十年的开发,储采比逐渐下降,深部难动用资源的绿色开发迫在眉睫. 通过开展静态溶浸实验和电极加热仿真模拟,结合原位溶浸技术在铀矿和稀土矿开采中的成功经验,总结出该技术在固体矿产开采中应用的适用条件包括:矿物可溶性、矿体分布稳定性、顶底板条件、矿体渗透性. 我国北方铝土矿资源与以上条件切合程度高,适合采用原位溶浸技术进行开采. 本次研究还提出了沉积型铝土矿原位溶浸开采的工艺方案,为下一步开展先导试验提供了设计思路.