利用X射线衍射和岩矿鉴定等技术研究河南汤家坪钼矿区主要矿物标型特征

汤家坪钼矿床是2006年探明的一处大型斑岩型钼矿床,前人用常规地质方法对该矿区基础地质工作和成矿规律研究已比较系统和完整,认为汤家坪钼矿床属于深源浅成斑岩型钼矿床,汤家坪花岗斑岩体为矿区钼矿的成矿母岩;但是没有从矿物学角度来应证这些成矿规律。本文从矿物学角度,采用分离单矿物进行化学分析、X射线衍射(XRD)及岩矿鉴定等技术,对汤家坪钼矿区的辉钼矿、黄铁矿、石英、长石4种矿物标型特征(化学组成、微量元素、晶体结构、晶胞参数、结构状态等)进行研究。结果表明:1该矿区辉钼矿全部是2H型多型变体,且成分中Re含量很低;辉钼矿的δ34S值为3.0‰,硫同位素变化范围小,接近于陨石硫,具深源硫的特点,硫来源于花岗斑岩。2黄铁矿微量元素以富含Mo、Co、Cu,贫Ni、Pb、Zn为标型特征,另外Au、Ag含量低,S/Se大于250000,与前人"S/Se大于250000~500000的地区不可能找到金矿"的结论相符。3石英富含Mo;成矿期石英脉中δ18O降低,表明成矿晚期有少量大气降水参与热液蚀变成矿。4长石富含Mo;轻稀土(La~Nd)含量大于中稀土(Sm~Ho)和重稀土(Er~Y)含量;钾长石的有序度、三斜度以及结构参数的值均较高,结构温度较低,表明该矿区钾长石为低温状态下的三斜对称的微斜长石,是热液作用的产物,岩体钾长石化对钼矿化最为有利。本研究应证了汤家坪钼矿床属于深源浅成斑岩型钼矿床,对于总结斑岩型钼矿成矿规律、找矿标志有重要意义。     

东昆仑造山带东段哈图沟–清水泉–沟里韧性剪切带塑性变形及动力学条件研究

东昆仑造山带东段哈图沟–清水泉–沟里韧性剪切带记录了多个旋回的造山作用,本文通过对韧性剪切带中石英c轴组构和显微构造特征测试分析,探讨东昆仑造山带东段陆块间俯冲拼合及地壳伸展减薄的形成机制。结果显示,韧性剪切带变形温度介于380~650℃之间,形成环境为中–高绿片岩相到低角闪岩相,剪切带内差异应力值介于173~509 MPa之间,应变速率介于6.93×10–14~1.43×10–8 s–1之间,主体为10–11~10–10 s–1,显示韧性剪切带变形是快速俯冲作用下的产物,越靠近东昆仑造山带东段东昆中断裂带其变形温度、差异应力值及相应的应变速率值越大,表明东昆仑造山带东段韧性剪切变形中心为东昆中断裂带。利用不同方法所计算出的韧性剪切带运动学涡度值,显示韧性剪切带早期瞬时运动学涡度(0.56~1)对应于东昆仑造山带东段东昆南与东昆仑造山带东段东昆北陆块间俯冲的初始阶段,中后期运动学涡度(0.25~0.91)应当对应于东昆南与东昆北陆块间的俯冲碰撞阶段,最晚期的C′瞬时运动学涡度(0.19~0.51)则对应于后造山的伸展阶段。通过石英c轴组构结合其宏微观构造特征,认为东昆中构造带至少经历了3个期次的构造运动,分别为加里东晚期的逆冲兼左行走滑剪切作用、晚海西–印支期的逆冲兼右行走滑剪切作用和燕山早期及之后的脆韧性–脆性的左行走滑剪切作用。     

A middle surface concept (MSC) model for saturated sands in general stress space

An elastoplastic constitutive model is proposed for saturated sands in general stress space using the middle surface concept (MSC). In MSC, different features of stress–strain response of a material are divided into different pseudo‐yield surfaces. The true‐yield surface representing the true response is established by using various links between the yield surfaces. In this MSC sand model, several well‐known features of sand response are represented by three different pseudo‐yield surfaces, which are developed in a simple and straightforward way. These features include the critical state behaviour, the effects of state parameter, unloading and reloading plastic deformation, the influence of fabric anisotropy, and phase transformation line related behaviour. Finally, the model predictions and test results are compared for two different types of sands under a variety of loading conditions and good comparisons are obtained. The application of MSC to saturated sand modelling shows the versatility of MSC as a general concept for modelling stress–strain response of materials. Copyright © 2006 John Wiley & Sons, Ltd.     

A least-squares method for determining the best-fit point maximum, great circle, and small circle to nondirectional orientation data

Given a set of nondirectional orientation data (fold axes, lineations, dip and dip direction of bedding, universal stage readings of crystallographic axes, etc.),the best-fit line (point maximum),plane (great circle),or cone (small circle)can be determined by minimizing the sum of the squares of the angular residuals using a simplex convergence technique. Stereoplots of the angular deviation over the complete lower hemisphere for these distributions may also be generated when consideration of the constraint on the best-fit position is important; for example in comparing different data sets of the same structural element. The routines are available as a FORTRAN coded computer program.     

辽南北瓦沟长英质岩石应变组构演化

岩石的应变组构型式与岩石成分、变形环境和应变过程有着密切关系。北瓦沟地区低角闪岩相条作下的长英质岩石,表现脆性、韧性和韧脆性过渡,因而在剪切作用过程中形成了相应的应变组构型式,即脆性应变组构、韧性应变组构和脆-韧性应变组构。而且随着应变过程的发展,应变组构也表现出一定的演化规律。     

Syntectonic emplacement of the Middle Jurassic Concón Mafic Dike Swarm, Coastal Range, central Chile (33° S)

The Concón Mafic Dike Swarm (CMDS) consists of basaltic to andesitic dikes emplaced into deformed Late Paleozoic granitoids during the development of the Jurassic arc of central Chile. The dikes are divided into an early group of thick dikes (5–12 m) and a late group of thin dikes (0.5–3 m). Two new amphibole ⁴⁰Ar/³⁹Ar dates obtained from undeformed and deformed dikes, constrain the age of emplacement and deformation of the CMDS between 163 and 157 Ma. Based on radiometric ages, field observations, AMS studies and petrographic data, we conclude that the emplacement of the CMDS was syntectonic with the Jurassic arc extension and associated with sinistral displacements along the NW-trending structures that host the CMDS. The common occurrence of already deformed and rotated xenoliths in the dikes indicates that deformation in the granitoids started previously.The early thick dikes and country rocks appear to have been remagnetized during the exhumation of deep-seated coastal rocks in the Early Cretaceous (around 100 Ma). The remanent magnetization in late thin dikes is mainly retained by small amounts of low-Ti magnetite at high temperature and pyrrhotite at low temperature. The magnetization in these dikes appears to be primary in origin. Paleomagnetic results from the thin dikes also indicate that the whole area was tilted  23° to the NNW during cooling of the CMDS.The NNW–SSE extension vectors deduced from the paleomagnetic data and internal fabric of dikes are different with respect to extension direction deduced for the Middle–Late Jurassic of northern Chile, pointing to major heterogeneities along the margin of the overriding plate during the Mesozoic or differences in the mechanisms driving extension during such period.     

Crystallographic orientations of high-angle grain boundaries in dynamically recrystallized quartz: First results

The crystallography and geometry of high-angle grain boundaries from dynamically recrystallized quartz have been studied. On the basis of combined electron backscatter diffraction and universal stage measurements, the complete crystallographic orientation of the grain boundaries could be calculated. The u-stage rotation of the grain boundaries to a vertical position reveals that they are never curved but always consist of straight segments. Our results show that these segments preferentially occupy rhombohedral, trapezohedral and bipyramidal orientations, i.e., orientations in a  25–50° girdle to the c-axis. A specific, albeit low, number of segments with special crystallographic orientation, with respect to a neighbouring quartz grain, often shows another special orientation with respect to the other neighbouring grain. Preferred combinations of grain boundary orientations related to both neighbouring grains are (i) low-index rhombohedral and high index trapezohedral, (ii) low-index bipyramidal and low-index trapezohedral or high-index rhombohedral, and (iii) low-index trapezohedral and low or high index trapezohedral. In certain cases, such as at triple junctions, the boundaries occupy specific trapezohedral orientations with a constant angle to the c-axis. This argues for energy isotropy of trapezohedral planes with the same angle to the quartz c-axis. In general, good match coincidence site lattice (CSL) orientations are not preferentially occupied so that most of the studied grain boundaries represent general boundaries. The formation of straight segments in special crystallographic orientations indicates the crystallographic control and implies an energy reduction of certain general boundaries.     

下三叠统鲕粒灰岩中微生物矿化组构特征及意义 ——以川东北地区飞仙关组为例

PTB全球最大生物灭绝事件后,早三叠世被认为是微生物发育繁殖的黄金时期,浅水环境是微生物活动及微生物岩形成的最有利环境。借助高分辨率扫描电镜和能谱分析,在川东北地区开江—梁平海槽西侧下三叠统飞仙关组浅水碳酸盐岩台地边缘的鲕粒灰岩中发现了三种微生物矿化组构:空腔状微生物矿化组构、显微瘤状微生物矿化组构和纤状微生物矿化组构;通过沉积学、岩石学及地球化学的综合分析,认为显微瘤状微生物矿化组构是微生物新陈代谢时形成的纳米球状云质颗粒,纤状微生物矿化组构是微生物的胞外聚合物,而空腔状微生物矿化组构则属于微生物个体。这些微生物矿化组构的发现,为早三叠世微生物大爆发提供了一定的直观证据;推测大量的微生物活动是早三叠世碳酸盐快速沉积现象的直接诱因,并导致于二叠纪末发育的克拉通内裂陷——开江—梁平海槽在早三叠世被快速填平。     

新资深大断裂变质带特征、成因及活动演化

在前人研究成果和野外调查基础上,对新资深大断裂变质带特征进行系统总结,从宏观构造、显微构造与组构、岩石矿物学、年代学和地球化学等多学科角度综合研究,分析了新资断裂带各类岩石组构成因,并建立了其活动演化期次。新资深大断裂变质带构造岩主要包括定向组构系列岩石和块状系列岩石,主要是由早期的韧性变形变质作用阶段和晚期的脆性破碎作用阶段先后作用形成。越城岭岩体西侧规模巨大的花岗片麻岩带应属新资深大断裂变质带的一部分,属早期活动的产物,其原岩为越城岭岩体,为断裂变质和动力热流变质作用形成。韧性剪切系列岩石按变形变质强度可分为高温高压韧性剪切带和中温高压韧性剪切带,表明韧性剪切作用具有多期性。新资断裂带活动演化主要经历了四个阶段,始于加里东期,至喜山期均有活动,现在的新资断裂带是经过多个阶段不同类型变质作用由东向西不断迁移和相互叠加的结果。