浙江雁荡山火山-侵入杂岩的岩浆混合作用——暗色包体中长石环带的证据

浙江雁荡山是中国东南部燕山晚期巨型火山-侵入杂岩带的重要组成部分。对其中央侵入相石英正长斑岩的暗色微粒包体中的斑晶和基质斜长石进行了详细的内部结构和成分分析,揭示了斜长石复杂环带的成因和相关的岩浆作用过程。斑晶斜长石由熔蚀的核部和表面干净的幔部组成,边部包裹有钾长石膜。核部斜长石呈浑圆状或港湾状,内部发育筛状结构,An成分显著低于幔部斜长石,代表来自酸性岩浆房中早期结晶的斜长石捕掳晶。同时,幔部斜长石与自形、表面干净的基质斜长石具有类似的An含量,且两者均含有针状磷灰石的包裹体,应结晶自与暗色微粒包体相应的基性岩浆。长石的复杂结构记录了雁荡山火山-侵入杂岩形成过程中的岩浆混合作用和岩浆演化过程。岩浆混合之后的火山喷发活动,造成岩浆房的压力突然减小,温压条件达到钾长石结晶的区域,在石英正长斑岩的斑晶斜长石和暗色包体中的斑晶与基质斜长石外均形成钾长石膜,构成反环斑结构。     

Plagioclase porphyroblast growth and its relation to deformation in the Alhamilla unit (Sierra Alhamilla, Betic Cordilleras, SE Spain)

Abstract. Plagioclase porphyroblasts from silvergrey schists belonging to the Nevado Filabride Complex in the Sierra Alhamilla (Betic Zone, SE Spain) are interpreted as having been formed preand synkinematically with respect to the second phase of deformation. Different types of inclusion patterns represent 'snap-shots'(high growth-rate/strain-rate ratio features) of the formation of a diffentiated crenulation cleavage during this second phase of deformation, by the processes of kinking, crenulation and associated differentiation.
Regional considerations indicate an Alpine age for this tectono-metamorphic event, which can be explained by the'hot emplacement'of the higher Nevado Filabride units. The observed structural evolution is not consistent with a pre-Alpine polyphase deformation history.     

Continuous reactions with amphibole, garnet and plagioclase

Abstract End-member, continuous and degenerate reactions are derived for the multisystem with the six components Na₂O, CaO, (Mg/Fe)O, Al₂O₃, SiO₂, H₂O among the phases plagioclase_ss, garnet_ss, amphibole_ss, cpx, opx, olivine, spinel, quartz and an aqueous fluid. The chemography of this system is degenerate due to the co-linearity 2Opx = Ol + Qtz. This co-linearity has its implications both on reaction space and phase equilibria. From a total of 28 reaction systems, reaction space is derived for nine subsystems (phases in parentheses are absent): Case A₁: (Cpx,Ol) (Cpx,Opx) and (Cpx,Qtz), Case A₂: (Spl,Ol) (Spl,Opx) and (Spl,Qtz), Case B: (Ol,Opx) (Ol,Qtz) and (Opx,Qtz). In the absence of either cpx or spl (case A), three reactions form an invariant point, either [Cpx] or [Spl], where the co-linear phases olivine, opx and quartz coexist on the transformation line 2Opx = Ol + Qtz. Changing mineral compositions force invariant points to move along the line with the different reaction curves changing their relative position according to Schreinemakers’rules. Zero contours, i.e. the location where (a) phase(s) disappear(s) in reaction space correspond to singular points in phase diagrams. Two types are distinguished; singular points of indispensable and of substitutable phases. In the first case the phase disappears from the entire bundle while in the second it disappears from a single reaction. In the specific case where the substitutable phases are also the co-linear ones, two of the three co-linear phases disappear simultaneously. Two of the three reaction curves coincide. In the system including Cpx and Spl (Case B) three reactions, (Ol,Opx) (Ol,Qtz) and (Opx,Qtz), oppose three invariant points, [Ol], [Opx] and [Qtz]. Invariant points no longer move along the line 2Opx = Ol + Qtz. The coincidence of the zero contours of all three co-linear phases in reaction space-the result of the chemographic degeneracy-causes the respective singular points to coincide in the phase diagrams. This is the location where curves must be rearranged in a bundle to conform Schreinemakers’rules. The reaction Grs₁Prp₂= 2 Ol + An is fourth order degenerate and part of all nine subsystems (cases A and B). It can be used to relate the different phase diagrams to one another.     

河北承德大庙黑山钒钛磁体矿床地质特征与成因探讨

河北承德大庙黑山铁矿床位于大庙斜长岩体南部边缘,红石砬—大庙深断裂附近北侧。矿区内主要岩类为斜长岩,根据蚀变作用可分为钠黝帘石化斜长岩、绿泥石化斜长岩及混染斜长岩等,前者广泛分布于矿区内,后二者常构成铁矿的直接围岩。黑山铁矿苏长岩体与铁矿体有成因联系,主要受近东西向压扭性断层和龙潭沟—岔沟压扭性断裂带构造控制,分布于黑山斜长岩体内。部分苏长岩体中有分异式浸染矿体,在苏长岩接触带及其围岩中的矿体则为贯入式矿体。苏长岩体根据其特征和共生组合,可划分为两个岩石系列：①苏长岩岩石系列（苏长岩类型岩体、含橄苏长岩苏长岩类型岩体）;②二长岩苏长岩岩石系列（二长岩苏长岩类型岩体、二长岩橄榄苏长岩类型岩体）。矿石结构主要为自形—半自形晶粒状结构、格状熔离结构、海绵陨铁结构。矿石构造有致密块状构造、浸染状构造。矿石金属矿物主要为含钒钛磁铁矿（含量3%～60%）、钛铁矿（含量2%～19%）、含钒磁铁矿（含量7%～27%）,次有少量含钴黄铁矿、黄铜矿。脉石矿物主要为绿泥石（含量7%～33%）,次为斜长石（0%～45%）,及其它少量矿物。黑山的矿源苏长岩和中国及世界同类岩石有显著不同,Si、Al、Fe、Ti、P、Na、K含量高,Ca、Mg含量低,这类岩体为形成铁磷矿床提供了物质来源。本区斜长岩、矿源苏长岩铁矿床和铁磷矿床的氧同位素组成δ18O限于一个很窄的变化范围,反映了它们的物质来源和成因类型的同一性。黑山苏长岩、伟晶苏长岩δ34S 为+1.3‰～+2.1‰,反映苏长岩浆来源于上地幔。黑山铁磷矿体经铁钛氧化物矿物对形成温度计计算得出生成温度为615~975℃,显示该岩浆矿床高温成矿特点。研究认为黑山铁矿主要①、②号铁矿体为岩浆贯入成矿。     

低温条件下长石溶解模拟实验研究

为了研究有机酸和无机酸对长石的溶解能力以及不同有机酸对长石溶解能力的差异,笔者等在80℃条件下,在不同pH值（4、6和8）的分别含有盐酸、乙酸和草酸的溶液中,对碱性长石和斜长石进行了溶解模拟实验研究。实验结果表明：酸性(pH=4)和弱酸性(pH=6)条件下,乙酸对两种长石的溶解能力大于草酸,碱性条件(pH=8)下草酸的溶解能力最大,无论在酸性或碱性条件下,有机酸对长石的溶解能力均高于无机酸,酸性(pH=4)条件下,斜长石与碱性长石溶解量差别不大,在弱酸性(pH=6)和碱性(pH=8) 条件下,斜长石的溶解量高于碱性长石。     

俄罗斯塔尔纳赫岩浆铜镍硫化物矿床中流体参与成矿的矿物学证据

岩浆铜镍硫化物矿床研究中“硫化物矿浆”组成及上侵聚集机制一直存在争议。在新近提出的“岩浆通道成矿系统”的思路下,文章研究了来自俄罗斯诺里尔斯克地区塔尔纳赫铜镍硫化物矿床中的赋矿橄榄苏长辉长岩,发现其主要造岩矿物存在两种类型,在微量元素分配上出现了明显的差异。文章重点报告了其中斜长石的特点。以微量元素的分配模式为依据,所有斜长石可以分为两类：Ⅰ型斜长石强烈富集大离子亲石元素和轻稀土元素,强烈亏损高场强元素,成分为钠长石倍长石,与硫化物共存,指示在含矿硫化物珠滴中应含有大量流体;Ⅱ型斜长石富集轻稀土元素,强烈亏损高场强元素,成分为中长石倍长石,产于岩体中遭受交代改造较弱的区域,指示它们由熔体结晶形成。据此我们认为“硫化物矿浆”在上侵过程中包含大量流体,应该为“熔体流体”。文章为流体在硫化物矿浆富集和运移过程中起着重要作用的论点提供了新的证据。     

内蒙古乌拉特中旗色尔腾山岩群东五分子岩组锆石SHRIMP定年及其地质意义

色尔腾山岩群是华北克拉通中西部早前寒武纪变质结晶基底的主要组成部分,对研究华北克拉通基底演化具有十分重要的意义。色尔腾山岩群的形成时代是目前研究的热点之一,本文通过岩石学和锆石SHRIMP U-Pb定年研究,查明了内蒙古乌拉特中旗乌兰乡查干哈达地区色尔腾山岩群东五分子岩组的岩石组成和年代学特征。东五分子岩组遭受了后期岩浆和构造作用的强烈破坏,未见顶底,主要由中细粒斜长角闪岩、细粒黑云斜长片麻岩、眼球状细粒黑云斜长片麻岩、条带状细粒黑云斜长片麻岩和细粒黑云角闪片岩组成,矿物组合特征指示岩石经历了低绿片岩相-低角闪岩相变质。其中,眼球状细粒黑云斜长片麻岩出露相对较厚,与细粒黑云斜长片麻岩多呈互层状产出,局部偶夹细粒黑云斜长片麻岩。本次研究选取其中新鲜的细粒黑云斜长片麻岩进行了锆石SHRIMP U-Pb测年分析,其锆石多呈自形-半自形,发育震荡环带,主体为岩浆成因,锆石SHRIMP U-Pb定年结果为（1 930.7±9.6）Ma,代表原岩（中酸性火山岩）冷凝结晶年龄,表明东五分子岩组经历变质作用的时代应晚于1 930 Ma。     

斜长石组构的显微测量方法及应用

介绍了目前国外用费氏台测量斜长石组构的三种方法：（１）ＢＰＷ图解法;（２）（０１０）,（００１）双面交点法;（３）（０１０）消光角法;并分析了其适用范围及各自的优缺点。最后总结了确定斜长石组构的应用意义;（１）确定滑移系;（２）判断剪切方向;（３）计算地震波速。     

Metamorphic charnockite in contact aureoles around intrusive enderbite from Natal, South Africa

In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration reaction Bt + Qtz → Opx + Kfs + H₂O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions show systematic variation with: (1) the Port Edward Enderbite being dominated by CO₂ and N₂ fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity with minor CO₂. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range (up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization (brines, CO₂) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry” enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred. Received: 8 November 1998 / Accepted: 21 June 1999     

腾冲火山岩斜长石斑晶的过剩氩兼论火山活动的分期

在腾冲黑空山、打鹰山和马鞍山火山岩的斜长石斑晶里首次发现存在过剩氩,并从基质中得到比以往的全岩年龄更年轻的KAr年龄,论证了以往所发表这一时间段的KAr 年龄结果可能因过剩氩而偏老,结合马鞍山已经取得的10 ka左右的U系年龄结果认为,腾冲最近一期火山活动的终止时间应为全新世。