基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

Estimating Influence of Crystallizing Latent Heat on Cooling-Crystallizing Process of a Granitic Melt and Its Geological Implications

Based on the theory of thermal conductivity, in this paper we derived a formula to estimate the prolongation period （AtL） of cooling-crystallization process of a granitic melt caused by latent heat of crystallization as follows：△tL=QL×△tcol/（TM-TC）×CP where TM is initial temperature of the granite melt, Tc crystallization temperature of the granite melt, Cp specific heat, △tcol cooling period of a granite melt from its initial temperature （TM） to its crystallization temperature （Tc）, QL latent heat of the granite melt.
The cooling period of the melt for the Fanshan granodiorite from its initial temperature （900℃） to crystallization temperature （600℃） could be estimated -210,000 years if latent heat was not considered. Calculation for the Fanshan melt using the above formula yields a AtL value of -190,000 years, which implies that the actual cooling period within the temperature range of 900°-600℃ should be 400,000 years. This demonstrates that the latent heat produced from crystallization of the granitic melt is a key factor influencing the cooling-crystallization process of a granitic melt, prolongating the period of crystallization and resulting in the large emplacement-crystallization time difference （ECTD） in granite batholith.     

Research Advances and Exploration Significance of Large-area Accumulation of Low and Medium Abundance Lithologic Reservoirs

In recent years, a series of large low and medium abundance oil and gas fields are discovered through exploration activities onshore China, which are commonly characterized by low porosity-permeability reservoirs, low oil/gas column height, multiple thin hydrocarbon layers, and distribution in overlapping and connection, and so on. The advantageous conditions for large-area accumulation of low-medium abundance hydrocarbon reservoirs include： （1） large （fan） delta sandbodies are developed in the hinterland of large flow-uncontrolled lake basins and they are alternated with source rocks extensively in a structure like ＂sandwiches＂; （2） effective hydrocarbon source kitchens are extensively distributed, offering maximum contact chances with various sandbodies and hydrocarbon source rocks; （3） oil and gas columns are low in height, hydrocarbon layers are mainly of normal-low pressure, and requirements for seal rock are low; （4） reservoirs have strong inheterogeneity and gas reservoirs are badly connected; （5） the hydrocarbon desorption and expulsion under uplifting and unloading environments cause widely distributed hydrocarbon source rocks of coal measures to form large-area reservoirs; （6） deep basin areas and synclinal areas possess reservoir-forming dynamics. The areas with great exploration potential include the Paleozoic and Mesozoic in the Ordos Basin, the Xujiahe Formation in Dachuanzhong in the Sichuan basin, deep basin areas in the Songliao basin etc. The core techniques of improving exploration efficiency consist of the sweetspot prediction technique that focuses on fine characterization of reservoirs, the hydrocarbon layer protecting and high-speed drilling technique, and the rework technique for enhancing productivity.     

The distribution and geological significance of carbazole compounds in Silurian paleo-pools of the Tarim Basin,Northwest China

The results presented in this paper indicated that the carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and （or） bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin （at the end of the Silurian period） and at the second stage in the Awati area （in Permian）, the hydrocarbons experienced a long-distance migration.     

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.     

Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag

Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas： the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion： free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps.     

Origin of Oils in “Subtle pools” in the Dongying Depression, Bohai Bay Basin, China

Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation （Es3）. Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph （〉1）, low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph （〈1） and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.     

基于AHP和BP神经网络的深部地热水可持续开发能力评价

采用资料完整性、开采潜力、回灌量、平均水压下降速率、地面沉降速率、水温、水质、地热井布局8项指标构建天津地热可持续开发能力评价指标体系;运用层次分析法确定了各项指标的权重,建立起评价因素集和评语集,给出了归一化数值;建立了天津地热可持续开发能力的BP神经网络模型,以层次分析法得出的结果作为样本,对BP网络进行了训练和测试,实例评价结果表明了AHP和BP神经网络方法的可行性,为地热资源的可持续开发能力评价提供了一种新的评价方法。     

兰州—白银多目标地球化学调查野外工作方法浅析

多目标区域地球化学调查从调查区表层、深层采样土壤元素分布特征入手建立土壤元素地球化学分配机制,以景观、地貌及地质特征为基础,选择合理的采样位置,正确的采样方法、采样层位,应用掌上机（Pocket PC）及数字填图系统（Rgmap）采集野外样品,本文以兰州—白银黄土覆盖区景观区为例,对表层、深层采样方法和技术要求进行探讨,对全省开展多目标地球化学调查,特别是野外工作方法提供借鉴。     

金沙江下咱日堆积体的成因和稳定性初步分析

下咱日堆积体的稳定性对拟建的梨园水电站大坝和附近的水力设施有着重要的意义。利用下咱日堆积体的勘察资料,本文分析后认为下咱日堆积体经历了中更新世的金江冰期和晚更新世的丽江冰期两次冰期的作用,是由冰碛物、河流沉积物、湖相沉积物及崩积物组成的复杂成因堆积体;稳定性初步分析认为,下咱日堆积体局部有坍塌,但是整体稳定,以后稳定与否的关键是堆积体中湖相沉积层及坡脚的松散砾石层的稳定性。