大别山北部中酸性片麻岩的岩石地球化学特征及其古大地构造意义

大别山北部变质镁铁－ 超镁铁质岩带中的中酸性片麻岩主要可分为三类：①英云闪长质片麻岩、②花岗闪长质片麻岩和③二长花岗质片麻岩,其原岩属于一套钙碱性的中酸性花岗岩系列。岩石地球化学特征表明,它们分别形成于板块碰撞前消减地区（ 消减的活动板块边缘） 、板块碰撞后隆起花岗石区和同碰撞花岗岩区。其中,形成于８００ ～１０００ Ｍａ 左右的英云闪长质片麻岩经受过麻粒岩相变质作用并与该带中属于蛇绿岩成员的变基性熔岩有亲缘关系, 可能属于蛇绿岩中的浅色组分。     

贵州南加花岗岩类特征及其与成矿的关系

从江县南加花岗岩类包括似斑状花岗岩及二长花岗斑岩。本文论述了它们的地球化学特征,并对其形成的构造环境及与成矿作用的关系进行了不的分析。（１）主状花岗岩类具Ｓ型花岗岩的特点,这可能形成于先封闭“弧后盆地碰撞带”;（２）二长花岗斑岩既具有Ｉ型花岗岩的某些特点,也有Ｓ型花岗岩的一些特点,可能属碰撞后形成的钙碱性岩石;（３）似斑状花岗岩类与钨锡矿化关系密切,二长花岗斑岩则可能与铜矿化有关系。     

柴达木盆地北缘超高压变质岩的围岩长英质片麻岩锆石LA—ICP—MS定年

柴达木盆地北缘大柴旦地区超高压变质岩的围岩--长英质片麻岩的主要矿物组合为石榴子石 蓝晶石 多硅白云母 条纹长石 石英 斜长石,形成压力在800MPa以上.在阴极发光图像内部结构研究的基础上,利用LA-ICP-MS对该长英质片麻岩中锆石的变质微区进行了详细的原位微区U-Pb定年,得到206Pb.238U加权平均年龄为427.2 Ma±4.5 Ma,对应的Th/U为0.01～0.06.该年龄与本区已有的榴辉岩的围岩超高压泥质片麻岩、石榴子石橄榄岩的变质年龄在误差范围内一致.     

甘肃北山小草湖超单元地质特征

小草湖超单元是北山地区最晚一期的花岗侵入岩体，从早到晚依次可划分为花岗闪长岩单元，斑状二长花岗岩单元，黑云母二长花岗岩单元，含白云母二长花岗岩单元共4个单元。侵入于石炭纪扫子山组和华力西中晚期四顶黑山序列及印支早期马鞍山北超单元中，形成时代为晚三叠纪，属印支晚期花岗质侵入岩体。各单元间为脉动型侵入接触关系。岩石化学成分及地球化学特征显示具“S”型花岗岩的特征，形成于板块同碰撞期到碰撞后期的造山环境。     

锡在流体和花岗质硅酸盐熔体间分配行为的实验研究

锡的成矿与花岗岩有着密切关系。为深入了解不同的岩浆组成及流体变化对锡分配行为的影响,以不同化学组成的凝胶和不同的流体分别作为初始固液相,进行了锡在流体与花岗质熔体间的分配行为实验研究。实验温度为850℃,压力为100 MPa。结果显示,当液相为0.1 mol/L的HCl时,熔体组成的变化对锡的分配行为有着明显的影响,锡在流熔体间的分配系数DSn随熔体中碱质(Na2O K2O)含量、钠钾(Na/K)和碱铝(AlK/Al)摩尔比的增加而减小;在固相(富钾过碱质熔体)不变的前提下,DSn随流体相中HCl浓度的增加而增大,而流体相中HF及K 、Na 浓度的改变对DSn影响不大;流体Cl-浓度和酸度升高有利于锡分配进入流体相。     

大别山超高压榴辉岩和花岗片麻岩中锆石Lu-Hf同位素研究

对大别山超高压榴辉岩和花岗片麻岩进行了锆石Lu-Hf同位素分析,结果为原岩来源提供了制约,表明扬子陆块在Rodinia超大陆裂解时的裂谷岩浆活动中发生了显著的陆壳生长。对这些锆石的不同区域进行的U-Pb和Lu-Hf同位素分析和比较表明,不同成因的锆石在~(206)Pb/~(238)U年龄、初始Hf同位素组成、Th/U及Lu/Hf比值等方面具有明显的差异。与年龄较老的岩浆核部和幔部相比,年轻的变质增生边具有低的Th/U和Lu/Hf比值但高的ε_(Hf)(t)值。不同成因锆石的Th/U和Lu/Hf比值存在着正相关性,表明变质作用对锆石的U-Th-Pb和Lu-Hf同位素体系有着相似的影响。高级变质作用有时能够引起岩浆锆石增生边~(176)Hf/~(177)Hf比值的显著升高,导致变质新生颗粒或增生边类似于新生地壳的高ε_(Hf)(t)值假象。对榴辉岩和片麻岩锆石核部的分析发现,镁铁质和长英质原岩在大约750Ma左右形成一个双峰式火山岩套,另外包含少量的年龄约为2.15Ga的陆壳。初始Hf同位素组成可分成两组:第一组具有正的ε_(Hf)(t)值,为5.9±0.9～12.9±0.7;第二组ε_(Hf)(t)值在零左右,为-4.3±0.5-2.3±0.3。正的ε_(Hf)(t)值与较年轻的模式年龄相对应,负的ε_(Hf)(t)值与古元古代模式年龄相对应。前者表明,在扬子陆块北缘裂谷岩浆作用将亏损地幔物质加入到大陆地壳中,同时在新元古代中期的裂谷构造带中存在同时期的壳-幔相互作用。因此,在扬子陆块北缘新元古代中期裂谷岩浆活动中,既有新生地壳生长和即时再造,也有古老地壳再造。     

闽西南古田-小陶花岗质杂岩体的形成时代和成因

古田-小陶花岗质杂岩体是由小陶、古田、华家、蛟洋和姑田等单元组成。小陶、古田和华家单元为含黑云母二长花岗岩,蛟洋和姑田单元是含角闪石黑云母石英二长岩。小陶和古田花岗岩以高 SiO_2(>71.77%)、K_2O(>4.67%)和低 CaO(<1.71%)为特征,属于弱过铝-强过铝花岗岩;它们含高的 Rb、Nh、Ta、Th、U 和低的 Sr、Ba 含量;稀土(REE)含量和轻重稀土分异((La/Yb)_N)变化大,分别变化于143×10~(-6)～548×10~(-6),和3.3～26.5,Eu 亏损中等到强。姑田和蛟洋单元都以低SiO_2(62.88%～66.38%)和高 Al_2O_3(15.44%～16.51%)为特征。姑田单元的 REE 总量低而蛟洋单元的 REE 总量高,但两者的 Eu 负异常都不明显。华家单元花岗岩的地球化学特征介于上述两组花岗岩之间。LA-ICPMS 锆石 U-Pb 定年显示小陶花岗岩形成于222±3Ma,而古田花岗岩形成于161±1Ma。小陶、古田和姑田花岗岩具有相似的~(87)Sr/~(86)Sr 初始比值(0.7089～0.7099)和ε_(Nd)(t)值(-11.1～-11.5),而且古田和小陶花岗岩的锆石 Hf 同位素组成也相似,表明它们起源于相同的源区。地球化学和 Sr-Nd-Hf 同位素指示它们的源区物质是具有1.73～1.5Ga 平均地壳存留年龄的变质沉积岩。而位于杂岩体南部的华家花岗岩显示明显高的~(87)Sr/~(86)Sr 初始比值(0.7310)和更低的ε_(Nd)(t)值(-16.4),指示它的母岩浆起源于古元古代壳源物质,暗示杂岩体南北基底组成可能不同。古田花岗岩形成于燕山早期的板内伸展构造背景,而小陶花岗岩形成于印支晚期,地球化学特征以及同时代岩石组合以及构造应力场分析表明其最可能形成于后造山构造背景。     

个旧老卡岩体接触-凹陷带构造控矿特征研究

个旧老卡岩体接触-凹陷带是个旧矿集区最重要的锡铜多金属成矿构造带,带内锡铜矿体的成生与凹陷带构造密切相关,受构造、岩性和岩浆活动联合控制,凹陷带的形态、产状、规模的变化直接影响矿体的形态、产状、规模.凹陷带构造是一个有利成矿的构造部位,并配之有其他控矿因素,最终在燕山晚期含矿岩浆气液作用下形成富厚矿体.     

Mineral oxygen isotope and hydroxyl content changes in ultrahigh-pressure eclogite–gneiss contacts from Chinese Continental Scientific Drilling Project cores

A combined study of mineral O isotopes and hydroxyl contents was carried out for the contacts between ultrahigh‐pressure eclogite and gneiss from main hole of the Chinese Continental Scientific Drilling Project in the Sulu orogen. While there is a large δ¹⁸O variation from ?8.3 to 7.3‰ for all minerals, different styles of mineral‐pair fractionation occur at the boundaries of different lithologies. Both equilibrium and disequilibrium O isotope fractionations are observed between quartz and the other minerals, with reversed fractionations between omphacite and garnet in some samples of eclogite. This suggests that both eclogite and gneiss acquired their negative δ¹⁸O values by meteoric‐hydrothermal alteration of their protoliths at high temperatures before subduction, and that fluid‐assisted O isotope exchange did take place across the boundary of different lithologies at local scales during amphibolite‐facies retrogression. Fourier Transform Infrared Spectroscopy analysis yielded H₂O concentrations of 50 to 1144 p.p.m. (by weight) for garnet and 139 to 751 p.p.m. for omphacite. The state of equilibrium or disequilibrium O isotope fractionations between omphacite and garnet are correlated with variations in their water content at local scales, indicating that the internally derived fluid plays a critical role in retrograde metamorphism during exhumation. The retrograde metamorphism results in mineral reactions and O isotope disequilibria between some of the minerals, but the fluid for retrogression was derived from the decompression exsolution of structural hydroxyl and thus internally buffered in the O isotope composition. A quantitative estimate suggests that a hand specimen (3 × 6 × 9 cm) of eclogite composed of 70% garnet and 30% omphacite can release 0.316 g water by the decompression exsolution of structural hydroxyl, which can form 14.4 g amphibole during exhumation. This provides sufficient amounts of water for the amphibolite‐facies retrogression.     

Late Cambrian to Early Silurian Granitic Rocks of the Gemuri Area, Central Qiangtang, North Tibet: New Constraints on the Tectonic Evolution of the Northern Margin of Gondwana

The Paleozoic tectonic framework and paleo–plate configuration of the northern margin of Gondwana remain controversial. The South Qiangtang terrane is located along the northern margin of Gondwana and records key processes in the formation and evolution of this supercontinent. Here, we present new field, petrological, zircon U-Pb geochronological, and Lu-Hf isotopic data for granitic rocks of the Gemuri pluton, all of which provide new insights into the evolution of the northern margin of Gondwana. Zircon U-Pb dating of the Gemuri pluton yielded three concordant ages of 488.5 ± 2.1, 479.9 ± 8.9, and 438.5 ± 3.5 Ma. Combining these ages with the results of previous research indicates that the South Qiangtang terrane records two magmatic episodes at 502–471 and 453–439 Ma. These two episodes are associated with enriched zircon Hf isotopic compositions(εHf(t) =-10.1 to-3.9 and-16.6 to-6.5, respectively), suggesting the granites were formed by the partial melting of Paleoproterozoic–Mesoproterozoic metasedimentary rocks(Two–stage Hf model ages(TCDM) = 2094–1704 and 2466–1827 Ma, respectively). Combining these data with the presence of linearly distributed, contemporaneous Paleozoic igneous rocks along the northern margin of Gondwana, we suggest that all of these rocks were formed in an active continental margin setting. This manifests that the two magmatic episodes within the Gemuri area were associated with southward subduction in the Proto-(Paleo-) Tethys Ocean.