Crystal chemistry of tremolite–tschermakite solid solutions

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.     

Statistical Properties of the Highest Pulses in Gamma-Ray Bursts

We study the statistical properties of the highest pulses within individual gamma-ray bursts (GRBs). A wavelet package analysis technique and a developed pulse-finding algorithm have been applied to identify the highest pulses from burst profiles observed by BATSE on board CGRO from 1991 April 21 to 1999 January 26. The statistical light curves of the highest pulses in four energy channels have been derived by an aligning method, which illustrate the temporal evolution of the pulse emission. Our result that narrower pulses go with higher energies is consistent with previous findings. By normalizing both the pulse durations and counts to unity, “characteristic” profiles of the highest pulses in the four channels are also derived. The four characteristic profiles are turned out to be almost the same, thus strongly support the previous conclusion that the temporal profiles in different energy channels are self-similar and the previous conjecture on GRB pulses, implying that the emission process is similar at different energies. The cosmological time dilation effect is examined by investigating the relationship between the pulse flux and pulse duration. An anti-correlation between the two was found, which agrees with the expectation of the cosmological time dilation effect. Also, the evolution of the pulse duration with the observational epoch is studied. The result shows that the pulse duration tends to be shorter in later epochs. This trend cannot be explained by the present theoretical models, and may represent a great challenge to current theories.     

成像光谱技术在典型蚀变矿物识别和填图中的应用

成像光谱矿物识别和填图技术是中国国土资源调查和监测重点发展的高新技术之一。笔者以国土资源调查应用为主要目标,研究了成像光谱矿物识别和矿物填图技术实用化中的一些关键技术问题。分析了白云母和绿泥石两种重要蚀变矿物的光谱特征及光谱变异特征;以新疆东天山黄山地区的HyMap数据为例,对目前已较为系统化的成像光谱识别技术(如MNF变换、像元纯度指数PPI和N维可视化端元识别NDVI)在典型蚀变矿物识别和填图中的应用进行介绍。     

西天山卡拉达湾地区铀及多金属综合找矿方向研究

卡拉达湾地区位于新疆北天山西段,属于中亚造山区,是在前寒武纪基底陆壳裂解的基础上发展起来的陆间型造山带,是铀及多金属成矿的重要区域。本文在前人工作的基础上,依据地面磁测、地面伽玛总量测量结果,总结分析了卡拉达湾地区磁场、放射性场、构造、矿化蚀变特征与铀及多金属成矿的关系,并圈定了铀及多金属找矿有利地段各2处,为西天山卡拉达湾地区的铀及多金属矿找矿工作提供方向。     

傅立叶变换红外光谱联用技术在化石燃料分析中的应用

对傅立叶变换红外光谱联用技术在化石燃料分析中的应用进行了较全面的总结评述,重点介绍了气相色谱／红外光谱联机、高压液相色谱／红外光谱联机、薄层色谱／红外光谱联机、超临界流体色谱／红外光谱联机、裂解色谱／红外光谱联机、热重分析／红外光谱联机、气相色谱／红外光谱／质谱三机联用技术等在化石燃料的结构组分分析、成因机理研究及其勘探等诸方面的重要应用,尤其是在芳香族化合物和几何异构体的分离鉴定方面发挥出的突出功效。引用文献５９篇。     

铝硅酸盐矿物和玻璃中Al的配位与局部结构

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。     

Upper Limit of Iodine Oxide in the Lower Stratosphere

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.     

Intercomparison of Tropospheric OH Measurements by Different Laser Techniques during the POPCORN Campaign 1994

In-situ OH measurements by laser-induced fluorescence (LIF) spectroscopy and folded long-path differential optical absorption spectroscopy (DOAS) were carried out in a rural environment in North-East Germany as part of the field experiment POPCORN in August 1994. The large set of OH data obtained allowed an intercomparison of both techniques based on relative diurnal profiles and simultaneously measured absolute concentrations. Most of the time the two OH instruments encountered the same air and agreed well in the measured relative diurnal variations. Only on a few occasions the measurements significantly disagreed due to a perturbation of the DOAS measurements by a local OH source in the north-western wind sector. Excluding data from this wind direction, the statistical analysis of 137 data pairs yields a correlation coefficient of r = 0.90 and a weighted linear fit with a slope of 1.09 ± 0.12. The correlations are carefully analyzed. The comparison of both instruments is discussed in the light of newly published effective absorption cross-sections for H2O and O2 that affect the calibration of LIF.     

Evolution of three unconformity‐bounded sandy carbonate successions in the McArthur River region of northern Australia: The Lawn,Wide and Doom Supersequences in a proximal part of the Isa Superbasin

Gamma‐ray curves from surface outcrops together with U–Pb SHRIMP zircon dating are used to redefine the evolution of a Palaeoproterozoic sandy dolostone succession from northern Australia. This case history indicates that gamma‐ray logging of surface sections should accompany lithostratigraphic logging or an inadequate interpretation of stratigraphic evolution is a likely outcome. The 1200 m‐thick Nathan Group from the McArthur River area had previously been interpreted as a more‐or‐less continuous package of carbonates deposited in lacustrine and associated shallow‐water environments. Now it is seen to comprise the preserved remnants of three truncated, second‐order supersequences—the Lawn, Wide and Doom Supersequences—each a few hundred metres thick and each deposited over a time period of a few million years. These supersequences are separated by major stratigraphic breaks each approaching probably 10 million years duration. Each supersequence comprises several third‐order sequences which themselves contain higher‐order cycles. These were deposited in a series of continental, shoreline, and inner to outer carbonate platform environments. Transgressive, high‐energy, fluvial to marginal marine, mixed clastic‐carbonate facies dominate most of the sequences. The middle, Wide Supersequence, however, preserves deeper water (mostly sub‐storm‐wave‐base) stromatolitic facies in one sequence, and storm‐reworked clastics in another. These are interpreted as condensed intervals deposited around their respective maximum flooding surfaces and are succeeded by regressive facies that probably represent highstand systems tracts. New correlations between these 1615–1575 Ma sandy carbonate successions of the McArthur Basin (Amos, Balbirini and Dungaminnie Formations) and time‐equivalent largely clastic successions in the Lawn Hill area (Lawn Hill and Doomadgee Formations), some 400 km to the southeast, are proposed.     

Intrinsic spectra of the AXPs

Using direct measurements of photo-electric absorption edges, I derive the intrinsic spectra for the Anomalous X-ray Pulsars. In the past, the hydrogen column density, N _H had been found by fitting the X-ray spectra with a variety of simple continuum models. Since different models fit equally well, with different values of N _H, little is learned about the true column density or intrinsic spectra. Here, I measure the column densities in a model-independent way, and thus derive intrinsic spectra without first assuming what those spectra ought to look like. Particularly for the brightest source, 4U 0142+61, the column density can be determined accurately, and is a factor of 1.4 smaller that the typically N _H quoted. With this new value, the new intrinsic spectrum can be investigated anew, and shows a slight hint of a feature around 13 Å. To be emphasised, this is an empirical method with the minimum of assumptions, as is appropriate for these beguiling sources, the behaviour of which has mystifies astronomers for over a decade. This paper summarises the methods and conclusions to be published in the Astrophysical Journal by Durant and Van Kerkwijk (2006; see astro-ph/0606604).