铝硅酸盐矿物和玻璃中Al的配位与局部结构

利用同步辐射的AlK边X射线吸收近进结构（XANES）谱研究了刚玉和铝硅酸盐矿物（蓝晶石,红柱石,夕线石和钠长石）中Al的配位与局部结构,证明该方法可以作为新的结构探针研究结构未知体系中Al的配位与局部结构。例如,Al的K边XANES谱证明在室温压条件,钠长石玻璃中的Al保持为四面体配位（AlIV）,局部结构与钠长石晶体中的Al相似;尽管硬玉晶体中的Al为八面体配位,但硬玉玻璃中的Al变为四面体配位（AlIV）。而在相同的高温压条件（4．4GPa,1575C）下制备的硬玉-钠长石玻璃系列中,压力引起四面体配位的Al变成五次（Alv）和六次配位（AlVl）,且五次和六次配位Al的比例随玻璃中硬玉含量的增加而增大。     

Upper Limit of Iodine Oxide in the Lower Stratosphere

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.     

Intercomparison of Tropospheric OH Measurements by Different Laser Techniques during the POPCORN Campaign 1994

In-situ OH measurements by laser-induced fluorescence (LIF) spectroscopy and folded long-path differential optical absorption spectroscopy (DOAS) were carried out in a rural environment in North-East Germany as part of the field experiment POPCORN in August 1994. The large set of OH data obtained allowed an intercomparison of both techniques based on relative diurnal profiles and simultaneously measured absolute concentrations. Most of the time the two OH instruments encountered the same air and agreed well in the measured relative diurnal variations. Only on a few occasions the measurements significantly disagreed due to a perturbation of the DOAS measurements by a local OH source in the north-western wind sector. Excluding data from this wind direction, the statistical analysis of 137 data pairs yields a correlation coefficient of r = 0.90 and a weighted linear fit with a slope of 1.09 ± 0.12. The correlations are carefully analyzed. The comparison of both instruments is discussed in the light of newly published effective absorption cross-sections for H2O and O2 that affect the calibration of LIF.     

基于阈值光电子-光离子符合技术的分子离子光谱和解离动力学研究

对电子和离子同时采用速度聚焦电场收集的阈值光电子-光离子符合成像谱仪能够有效提高电子的收集效率和能量分辨率.利用该符合成像谱仪,开展了Xe/Ar/Ne 惰性混合气体及NO 分子的阈值光电子谱、阈值光电子-光离子符合质谱和质量选择的符合光谱等实验研究,精确测量了NO 分子的电离势,并且获得了NO⁺离子振动态分辨的X¹Σ⁺,c³Π和B¹Π态光谱.还进一步研究了NO^{+ 相似文献}   

Evolution of three unconformity‐bounded sandy carbonate successions in the McArthur River region of northern Australia: The Lawn,Wide and Doom Supersequences in a proximal part of the Isa Superbasin

Gamma‐ray curves from surface outcrops together with U–Pb SHRIMP zircon dating are used to redefine the evolution of a Palaeoproterozoic sandy dolostone succession from northern Australia. This case history indicates that gamma‐ray logging of surface sections should accompany lithostratigraphic logging or an inadequate interpretation of stratigraphic evolution is a likely outcome. The 1200 m‐thick Nathan Group from the McArthur River area had previously been interpreted as a more‐or‐less continuous package of carbonates deposited in lacustrine and associated shallow‐water environments. Now it is seen to comprise the preserved remnants of three truncated, second‐order supersequences—the Lawn, Wide and Doom Supersequences—each a few hundred metres thick and each deposited over a time period of a few million years. These supersequences are separated by major stratigraphic breaks each approaching probably 10 million years duration. Each supersequence comprises several third‐order sequences which themselves contain higher‐order cycles. These were deposited in a series of continental, shoreline, and inner to outer carbonate platform environments. Transgressive, high‐energy, fluvial to marginal marine, mixed clastic‐carbonate facies dominate most of the sequences. The middle, Wide Supersequence, however, preserves deeper water (mostly sub‐storm‐wave‐base) stromatolitic facies in one sequence, and storm‐reworked clastics in another. These are interpreted as condensed intervals deposited around their respective maximum flooding surfaces and are succeeded by regressive facies that probably represent highstand systems tracts. New correlations between these 1615–1575 Ma sandy carbonate successions of the McArthur Basin (Amos, Balbirini and Dungaminnie Formations) and time‐equivalent largely clastic successions in the Lawn Hill area (Lawn Hill and Doomadgee Formations), some 400 km to the southeast, are proposed.     

Multivariate analysis of fluorescence and source identification of dissolved organic matter in Jiaozhou Bay, China

Hierarchical clustering analysis and principal component analysis (PCA) methods were used to assess the similarities and dissimilarities of the entire Excitation-emission matrix spectroscopy (EEMs) data sets of samples collected from Jiaozhou Bay, China. The results demonstrate that multivariate analysis facilitates the complex data treatment and spectral sorting processes, and also enhances the probability to reveal otherwise hidden information concerning the chemical characteristics of the dissolved organic matter (DOM). The distribution of different water samples as revealed by multivariate results has been used to track the movement of DOM material in the study area, and the interpretation is supported by the results obtained from the numerical simulation model of substance tracing technique, which show that the substance discharged by Haibo River can be distributed in Jiaozhou Bay.     

Intrinsic spectra of the AXPs

Using direct measurements of photo-electric absorption edges, I derive the intrinsic spectra for the Anomalous X-ray Pulsars. In the past, the hydrogen column density, N _H had been found by fitting the X-ray spectra with a variety of simple continuum models. Since different models fit equally well, with different values of N _H, little is learned about the true column density or intrinsic spectra. Here, I measure the column densities in a model-independent way, and thus derive intrinsic spectra without first assuming what those spectra ought to look like. Particularly for the brightest source, 4U 0142+61, the column density can be determined accurately, and is a factor of 1.4 smaller that the typically N _H quoted. With this new value, the new intrinsic spectrum can be investigated anew, and shows a slight hint of a feature around 13 Å. To be emphasised, this is an empirical method with the minimum of assumptions, as is appropriate for these beguiling sources, the behaviour of which has mystifies astronomers for over a decade. This paper summarises the methods and conclusions to be published in the Astrophysical Journal by Durant and Van Kerkwijk (2006; see astro-ph/0606604).     

A possible explanation of photon emission from supernova remnants by jitter radiation

We investigate a possibility that non-thermal X-ray emission in a supernova remnant(SNR) is produced by jitter radiation, which is the analogue of synchrotron radiation in small-scale random magnetic fields. We can fit the multi-wavelength data of SNRs RX J1713.7-3946 (G347.3-0.5) and RX J0852.0-4622 (G266.6-1.2) by constructing pure jitter and inverse Compton (IC) emission models. We find that the physical fit parameters of random magnetic fields take values of several tens of μG strength and of the order of ∼10⁷ cm correlation length. These properties of random magnetic fields in collisionless shock of SNRs are discussed.      

The drift model of “magnetars”

It is shown that the drift waves near the light cylinder can cause the modulation of emission with periods of order several seconds. These periods explain the intervals between successive pulses observed in AXPs, SGRs and radio pulsars with long periods. The model under consideration gives the possibility to calculate real rotation periods P of host neutron stars. It is shown that P≤1 s for the investigated objects. The magnetic fields at the surface of the neutron star are of order 10¹¹–10¹³ G and equal to the fields usual for the known radio pulsars.      

兴凯湖沉积物磁化率和色度反映的28kaBP以来区域古气候环境演化

对兴凯湖长269 cm的沉积岩心的研究结果显示:沉积物的色度和磁化率特征可以较好地反映区域气候环境变化。沉积物明度分别与红度、磁化率、黏土和有机质含量之间及磁化率与黏土之间有很好的相关性;红度高值与明度低值对应暖湿气候环境,磁化率低值反映沉积物较粗的较低湖面,对应冷干气候。28480~26160 cal.aBP,湖区处于温湿气候时期;22880~18170 cal.aBP,岩心孢粉浓度很低,流域处于末次盛冰期疏桦林草原环境;18170~12650 cal.aBP处于Bφlling/Older Dryas/Allerφd暖期。岩心深度90~78 cm段,对应于新仙女木期;11500~4570 cal.aBP,进入全新世暖期,其中8000~5000 cal.aBP,本区处于全新世大暖期(气候适宜期);4570~1470 cal.aBP气候变为凉干;1470 cal.aBP以来,流域又变为暖湿气候环境,同时,人类活动逐渐增强造成水土流失加剧。