Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

环境同位素记录中共生碳酸盐氧同位素分馏差值的影响

湖泊化学沉积碳酸盐δ18O是研究区域气候演变的重要环境指标之一。青海湖等闭流湖泊的研究结果证实,在对δ18O环境记录进行共生碳酸盐氧同位素分馏效应校正时,应依据具体情况,采用0-1‰的分馏差值。由高温实验结果推断出的常温分馏差值(4‰-7‰)不能被应用到自然条件下湖泊共生碳酸盐氧同位素分馏效应的校正。     

基于EM算法和单幅雷达图像阴影的控制点坡度校正

对在我国现有的条件下进行控制点坡度校正的必要性进行了阐述，并分析了EM算法。根据EM算法以及基于区域增长的余弦散射模型建立了控制点坡度校正模型，并用河北省张北地区的雷达影像进行了实验，取得了较高的精度初值。     

MODIS 1B影像几何纠正方法研究及软件实现

MODIS影像是一种新型和重要的数据。对MODIS 1B影像几何畸变原因进行了深入分析，选择了一种合适的纠正方法。对于1km分辨率MODIS 1B影像，直接采用1km分辨率的空间坐标进行几何纠正；对于250m和500m分辨率的MODIS 1B影像，先用三次样条曲线对坐标进行插值生成同分辨率的坐标，然后利用坐标插值结果对其进行几何纠正。由于MODIS影像在空问分布上的特殊性，采用前向和后向映射相结合的方式确定纠正后某一像素点在原始影像中的位置。根据该位置的条带重叠度，可以确定参与计算像素个数、搜索窗口的大小以及窗口的精确位置；采用归一化反距离加权插值法计算纠正后像素点的属性值。上述优化算法不仅保证了纠正后影像的质量，而且提高了数据处理速度。作者在Visual C 6．0环境下开发实现了上述算法。从坐标插值和几何纠正结果分析，无论是数据处理速度还是纠正后的影像质量和精度均达到要求。     

Correcting method of eddy covariance fluxes over non-flat surfaces and its application in ChinaFLUX

Although Eddy Covariance (EC) technique is one of the best methods for estimating the energy and mass exchanges between underlying surface and atmosphere in micrometeorology, errors and uncertainties still exist without necessary corrections. In this paper, we will focus on the effect of coordinate system on the eddy fluxes. Based on the data observed over four sites (one farmland site, one grassland site and two forest sites), the effects of three coordinate system transforming methods (Double Rotation-DR, Triple Rotation-TR and Planar Fit-PF)on the turbulent fluxes are analyzed. It shows that (i) the corrected fluxes are more or less than the uncorrected fluxes, which is related mainly to the sloping degree of surface, wind speed and wind direction; and (ii) pitch angle has a sinusoidal dependence on wind direction, especially in the regular sloping terrain; and (iii) PF method is something like the simplification of TR or DR,and there are not obvious distinctions in correction in sloping grassland and flat farmland, but PF method is not suitable for uneven and irregular forest sites.     

Fractionation mechanism of stable isotope in evaporating water body

Under Rayleigh equilibrium condition, stable isotopic ratio in residual water increases with the decrease of the residual water proportion f exponentially, and the fractionation rate of stable isotopes is inversely proportional to temperature. However, under kinetic evaporation condition, the fractionation of stable isotopes is not only related to the phase temperature but also influenced by the atmospheric humidity and the mass exchange between liquid and vapor phases. The ratio δ in residual water will not change with f after undergoing evaporation of a long time for great relative humidity. The rate that the evaporating water body reaches isotopic steady state is mainly dependent on the relative humidity in atmosphere. The analysis shows that the actual mean linear variety rates, about -30.0, of the δ18O in residual water versus the residual water proportion at Nagqu and Amdo stations are consistent with the simulated process under temperature of 20 oC and relative humidity of 50%. The distillation line simulated under Rayleigh equilibrium condition is analogous to the global meteoric water line (MWL) as the temperature is about 20 oC. Under non-equilibrium condition, the slope and constant values of distillation line are directly proportional to temperature and relative humidity. According to the basic data, the simulated distillation line is very consistent with the actual distillation line of Qinghai Lake.     

Laser Ablation ICP-MS Developments and Trends for 2003

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.     

Using raw regional climate model outputs for quantifying climate change impacts on hydrology

General circulation model outputs are rarely used directly for quantifying climate change impacts on hydrology, due to their coarse resolution and inherent bias. Bias correction methods are usually applied to correct the statistical deviations of climate model outputs from the observed data. However, the use of bias correction methods for impact studies is often disputable, due to the lack of physical basis and the bias nonstationarity of climate model outputs. With the improvement in model resolution and reliability, it is now possible to investigate the direct use of regional climate model (RCM) outputs for impact studies. This study proposes an approach to use RCM simulations directly for quantifying the hydrological impacts of climate change over North America. With this method, a hydrological model (HSAMI) is specifically calibrated using the RCM simulations at the recent past period. The change in hydrological regimes for a future period (2041–2065) over the reference (1971–1995), simulated using bias‐corrected and nonbias‐corrected simulations, is compared using mean flow, spring high flow, and summer–autumn low flow as indicators. Three RCMs driven by three different general circulation models are used to investigate the uncertainty of hydrological simulations associated with the choice of a bias‐corrected or nonbias‐corrected RCM simulation. The results indicate that the uncertainty envelope is generally watershed and indicator dependent. It is difficult to draw a firm conclusion about whether one method is better than the other. In other words, the bias correction method could bring further uncertainty to future hydrological simulations, in addition to uncertainty related to the choice of a bias correction method. This implies that the nonbias‐corrected results should be provided to end users along with the bias‐corrected ones, along with a detailed explanation of the bias correction procedure. This information would be especially helpful to assist end users in making the most informed decisions.     

基于OSM的浮动车轨迹数据校正方法

浮动车轨迹数据具有覆盖范围广、更新周期短、获取成本低等特点，对于地图的生产和更新具有重要意义，但是由于受到卫星信号被遮挡及多路径效应的影响，其精度普遍较低。本文采用一种基于OSM作为参考数据的方式对浮动车轨迹数据进行校正。首先通过一种分层时空地图匹配的方式将轨迹数据与OSM进行匹配；然后采用引力模型对数据进行校正；最后在武汉市出租车轨迹数据上进行了试验。结果表明，本文提出的数据校正方法可以有效地提高浮动车轨迹数据的精度。