地幔平衡部分熔融和岩浆分离结晶成因岩浆岩的判别

本文在讨论Ⅰ型（地幔平衡部分熔融成因）和Ⅱ型（岩浆分离结晶成因）岩浆岩元素丰度关系公式的基础上，建立了Ⅰ型和Ⅱ型岩浆岩系成因判别公式及判别法则。     

FACTORS CONTROLLING DIFFERENTIATION OF SELENIUM ECONVIRONMENT IN THE LOESS PLATEAU

ItisataskofNationaScienceandTechnologyProjectNo.75-62-03-05and06forthe7thFive-YearPlanperiod.InvestigationsinGansuandShanxiwereundertakenbyInstituteofGeography,CAS,whiiethatinShaanxiwascarriedoutbyNortllwestInstitllteofWaterandSoilConservation,CAS.**OthermembersintheGroupofEndemicDiseaseandEnvironment,InstituteofGeograpl1y,CASare:YangLinsheng,ZhaoYuanwei,ZhaoNaiqin,LiDezhu,WangLizhenandTanJianan.I.IntrodIlcti01llthasbeenreported[21thattwoendemics,KeshanandKaschin-Beck,arecl…     

辉碲铋矿单矿物的化学分析

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。     

The influence of aerosol particle composition on cloud droplet formation

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.     

Contact-metamorphic effect on parameters for kerogen maturation

This study examines the effect of contact metamorphism by an igneous dyke on parameters for kerogen maturation, such as elemental composition (H/C, O/C, N/C), ¹H-NMR T₁, vitrinite reflectance and infrared spectra. Although elemental composition and ¹H-NMR T₁ of the kerogen changed only within 1.5 and 5.0 m from the dyke respectively, vitrinite reflectance of the kerogen was thermally affected beyond 10.0 m from the intrusion. It is concluded that vitrinite reflectance is the most sensitive of the parameters evaluated to assess thermal stress of kerogens.     

氢化物发生—原子荧光光谱法测定煤样中的硒

采用氢化物发生原子荧光光谱法测定了煤样中的总Se。煤样选用高压闷罐强酸消解的方法进行处理，所得消解液经6mol/L HCl将Se（Ⅵ）还原为Se（Ⅳ），然后进行测定。标准工作曲线的线性范围为0－400μg/L Se，检测限为0.4μg/L Se。用标准参考物质煤飞灰对方法进行了验证，所得总Se含量与标准值相符，对ω为10^-6级Se的4次测定，RSD≤4.5％。     

电感耦合等离子体质谱法同时测定地质样品中痕量碘溴硒砷的研究：Ⅱ.土壤及沉积物标准物质分析

样品用碳酸钠和氧化锌混合熔剂半熔，热水提取，然后用强酸性阳离子交换树脂将阴离子形式存在的分析元素与溶液中大量钠、锌等阳离子分离，采用电感耦合等离子体质谱法直接同时测定溶液中的碘、溴、硒、砷。用0.07mol/L的氨水溶液清洗进样系统，有效减少了碘等元素的记忆效应和清洗时间。方法检出限（10σ，DF=100）溴、碘分别为0.15和0.028μg/g，砷、硒分别为0.04和0.004μg/g。用土壤和沉积物等地质标准物质分析验证了方法的准确度和精密度，绝大多数分析结果在标准值的允许误差范围之内。样品10次测定的RSD为0.8%～2.8%。     

成矿过程流体地球化学模拟及其矿床学意义：以江西银山矿床为例

本文将银山成矿体系为富含Ｈ２Ｓ，ＣＯ２的ＮａＣｌ体系，对Ｃｕ，Ｐｂ，Ｚｎ，Ａｇ和Ａｕ等金属元素在该体系降温过程中的地球化学行为和银山矿床的成矿过程进行计算机数字模拟，并与沸腾降温体系进行对比，证明了成矿体系地球化学演化对金属元素的迁移与沉淀具有得要影响。成矿硫体地球化学模拟在矿床成因，深部成矿预测和区域成矿规律研究中具有重要意义。     

对壤中钒、硒、钼测量方法的观察与思考

本文简要介绍了钒、硒、钼的地球化学性质。根据我国西北业已查实的3个层间氧化带砂岩型铀矿床中钒、硒、钼与铀的展布特征,认为,按已知铀矿床中铀与钒、硒、钼的存在及相互关系,试图用壤中钒、硒、钼测量对层间氧化带砂岩型铀矿实施伴生元素找矿或进行“空间定位”的依据尚不足。     

环境硒污染的植物修复研究进展

硒污染已成为全球性的环境问题,严重威胁人类健康和环境安全。本文概述了环境硒污染植物修复技术的研究进展,包括硒富集植物的应用、富集硒的机理及生物技术对它们的改造。指出了当前研究在硒富集植物富集机理及田间应用时的不足;并展望了今后如何进一步寻找和使用生物技术培育硒超富集植物、探求富集机理和田间试验。