安徽庐枞火山岩盆地橄榄玄粗岩系的地球化学特征及其对下扬子地区晚中生代岩石圈减薄机制的约束

庐枞盆地内的中生代火山-潜火山岩具高钾和相对富碱为特性,属典型的橄榄玄粗岩系列。它们在地球化学上表现出明显富集Rb、Th、U、K等强不相容元素和轻稀土元素,亏损高场强元素Nb和Ta的特征。Nd、Sr同位素组成总体位于富集型的扬子克拉通岩石圈地幔的范围内或其附近,显示其母岩浆主要是由富集型地幔部分熔融形成的。火山-潜火山岩的成分变异趋势显示橄榄玄粗质幔源岩浆在高压下(斜长石稳定压力之下,1.5GPa)经历过以单斜辉石和钛铁氧化物为主的矿物分离结晶作用。低压下矿物的分离结晶作用及上地壳物质的混染则不明显。这套火山-潜火山岩的部分地球化学性质(如Ce/Yb比值)类似于大洋岛弧内的橄榄玄粗岩,可能意味着区内由于岩石圈的减薄,软流圈地幔上涌到了岩石圈相对较浅的部位,控制源区部分熔融的主要是尖晶石相地幔岩。虽然局部(如靠近郯庐断裂的盆地西缘)可能存在着明显的热侵蚀,但突发性的机械拆沉是区内(乃至整个长江中下游地区)岩石圈减薄的主要机制。在整个晚中生代岩石圈减薄的过程中,这两种机制可能一直相互促进着。     

陕北能源化工基地采煤生态环境破坏及补偿机制研究

陕北能源化工基地煤炭、石油、天然气、岩盐等矿产资源储量丰富,经过近20a的开发,已初步建成为中国重要的能源接续地和大型煤化工基地。但该区又具有水资源相对短缺、生态环境脆弱的特点,加之近年来煤炭生产和转化等资源开发增长速度较快,采煤造成的区域性环境污染与生态破坏问题较为突出,严重制约着该区的可持续发展。通过探索建立陕北能源化工基地生态补偿机制,解决了煤炭资源开发与生态环境保护的矛盾,使资源得到适度、可持续的开发利用,环境生态得到持续的恢复和改善,从而使该区的经济发展与保护生态环境相协调,最大限度的实现了可持续发展的战略。     

Evolution of continental crust of the Aravalli craton,NW India,during the Neoarchaean–Palaeoproterozoic: evidence from geochemistry of granitoids

Neoarchaean–Palaeoproterozoic granitoids of the Aravalli craton, represented by four plutons with different ages, viz. Gingla (2.6–2.4 Ga), Ahar River (2562 Ma), Untala (2505 Ma), and Berach (2440 Ma) granitoids, are classified into three suites: TTG-like, Sanukitoid, and High-K Granitoid suite, all exhibiting negative Nb and Ti anomalies. The TTG-like suite is characterized by high contents of SiO₂, Na₂O, and LREEs, high (La/Yb)_N, low contents of K₂O, MgO, Cr, and Ni, and low (Dy/Yb)_N, suggesting that this suite formed by partial melting of a subducted basaltic slab without interacting with a mantle wedge. In contrast, the calc-alkaline Sanukitoid suite is marked by a high content of LILEs and mantle-compatible elements, which indicate that this suite formed by partial melting of a slab-fluid metasomatized mantle wedge in a subduction-related arc environment. On the other hand, the High-K Granitoid suite is characterized by high contents of SiO₂ and K₂O, and low contents of Na₂O, MgO, Cr, and Ni with variable Eu anomaly, along with high (La/Sm)_N and (La/Yb)_N, and low (Dy/Yb)_N and Nb/Th. Some high-K granitoids also exhibit A-type characteristics. These features indicate that the High-K Granitoid suite formed by melting of crustal rocks. Early Neoarchaean continental crust formation reflected a slab-melting-dominated magmatic process as evidenced by the TTG-like suite, whereas Palaeoproterozoic petrogenesis was governed by the interaction of slab melt with mantle wedge as demonstrated by the Sanukitoid suite. The High-K Granitoid suite formed during the waning stages of subduction. This study reveals that granitic rocks of the Aravalli craton evolved from slab melting in the Neoarchaean to melting of mantle wedge in the Palaeoproterozoic. Melting of older crust led to the formation of the High-K Granitoid suite.     

遵义黄家湾镍钼铂族元素矿床地质、地球化学和Re—Os同位素年龄测定——兼论华南寒武系底部黑色页岩多金属成矿作用

黄家湾矿是近几年在贵州遵义地区寒武系底部新发现的黑色页岩镍钼铂族元素矿床,本文介绍了矿床的基本特征和含矿地层,以及在矿层中鉴别出喷流间歇期形成的水云母黄铁矿层.利用负离子热表面电离质谱对矿石进行了Re-Os同位素年龄精测,获得541.3±16Ma(2σ)的等时线年龄.黄家湾矿是华南寒武纪黑色页岩多金属成矿带的一个组成部分.基于矿石的PGE和REE测试,结合前人的工作成果,分析区域构造演化历史和W-Sn-Mo-Sb地球化学富集区,认为区域黑色页岩由正常沉积作用形成;提出了镍钼铂族元素矿的成矿模式,认为这套矿床的形成是由海底喷流系统从海底镁铁质一超镁铁质岩中萃取物质与下伏富Mo-Re-(Cu)岩浆房提供成矿能源和部分物源共同作用的结果.     

Alteration of bottom roughness by benthic organisms in a sandy coastal environment

This work deals with the potential influence of benthic communities on the sediment dynamics of the coastal zone, and specifically with the modifications to bottom roughness caused by communities and their effects on wave propagation across the coastal profile. Time-series of video observations of the sea bottom on the Ebro delta coast were analysed in order to estimate the bottom roughness associated with physical and biological morphological components and the sediment reworking rates caused by epifaunal organisms. Biological roughness was mainly caused by ophiuroids and tanatocenosis of bivalve and gastropod shells, which changed their abundance during the study period. The total biological roughness (K_bio) ranged between 0.27 and 0.81 cm and represented a significant part (<20%) of the total form drag roughness. Flattening of ripples caused by bioturbation was observed under low-energy conditions. Surface sediment perturbation and bioturbation rates were also estimated. Based on these observations a wave propagation model was applied in order to carry out a sensitivity analysis of the significance of biological roughness on wave dissipation in the study area under different wave conditions.     

Seismic studies of the Brasília fold belt at the western border of the São Francisco Craton, Central Brazil, using receiver function, surface-wave dispersion and teleseismic tomography

The Tocantins Province in Central Brazil is composed of a series of SSW–NNE trending terranes of mainly Proterozoic ages, which stabilized in the Neoproterozoic in the final collision between the Amazon and São Francisco cratons. No previous information on crustal seismic properties was available for this region. Several broadband stations were used to study the regional patterns of crustal and upper mantle structure, extending the results of a recent E–W seismic refraction profile. Receiver functions and surface wave dispersion showed a thin crust (33–37 km) in the Neoproterozoic Magmatic Arc terrane. High average crustal Vp/Vs ratios (1.74–1.76) were consistently observed in this unit. The foreland domain of the Brasília foldbelt, on the other hand, is characterized by thicker crust (42–43 km). Low Vp/Vs ratios (1.70–1.72) were observed in the low-grade foreland fold and thrust zone of the Brasília belt adjacent to the São Francisco craton. Teleseismic P-wave tomography shows that the lithospheric upper mantle has lower velocities beneath the Magmatic Arc and Goiás Massif compared with the foreland zone of the belt and São Francisco craton. The variations in crustal thickness and upper mantle velocities observed with the broadband stations correlate well with the measurements along the seismic refraction profile. The integration of all seismic observations and gravity data indicates a strong lithospheric contrast between the Goiás Massif and the foreland domain of the Brasília belt, whereas little variation was found across the foldbelt/craton surface boundary. These results support the hypothesis that the Brasília foreland domain and the São Francisco craton were part of a larger São Francisco-Congo continental plate in the final collision with the Amazon plate.     

油气有机质与MVT铅锌矿床的成矿——以四川赤普铅锌矿为例

四川赤普MVT铅锌矿床成矿与古老油气藏关系密切。通过对矿床不同成矿阶段硫化物硫同位素和热液碳酸盐碳、氧同位素系统研究,结合沥青有机质的有机地球化学特征,探讨油气参与金属成矿的详细过程。取得主要认识如下：(1)油气系统中先存的H2S是成矿早阶段主要的硫源, TSR作用启动后还原硫酸盐,为成矿提供另一硫源。Mg2+可能是控制成矿过程中TSR作用的一个因素;(2)热液碳酸盐矿物碳(氧)同位素组成指示了 TSR 作用氧化的有机碳与流体溶解围岩碳酸盐岩中碳的不均匀混合作用;(3)矿床中与成矿作用有关的有机质(沥青)具有高-过成熟度特征和低芳烃含量,或是其参与了 TSR 作用的一个标志;(4)川滇黔地区油气成藏-破坏和赤普铅锌成矿可能是盆山演化过程中不同阶段或是同一阶段不同时代的产物,铅锌矿床形成与古老油气藏破坏密切相关。     

华北克拉通东部早白垩世伸展盆地的发育过程及其对克拉通的破坏

在晚侏罗世华北克拉通东部破坏之初出现了区域性隆起,全区缺失上侏罗统沉积。在早白垩世早期,出现了区域性的伸展活动,断陷盆地形成,克拉通南、北缘伸展活动最强,北部燕山构造带以出现变质核杂岩为特征,南部出现宽裂谷型盆地。早白垩世中期华北克拉通东部普遍出现了火山活动与岩浆侵入。早白垩世晚期克拉通上以出现窄裂谷型盆地为特征,沿北北东走向的郯庐断裂带断陷活动最强。这些断陷盆地的演化过程揭示,经历地表抬升后,克拉通破坏之初的岩石圈热而弱,从而形成变质核杂岩或宽裂谷型盆地。这期间的破坏强度在空间上具有不均匀分布的特征,受控于早期岩石圈地幔的结构。经过早白垩世中期的大量岩浆活动之后,早白垩世晚期克拉通岩石圈温度降低、强度变大,从而利用早期大型断裂构造形成窄裂谷型盆地。这现象支持华北克拉通东部晚中生代的岩石圈减薄是以逐渐拆沉机制为主。     

Geochemistry of the high-Mg andesites at Zhangwu, western Liaoning: Implication for delamination of newly formed lower crust

Ten volcanic samples at Zhangwu,western Liaoning Province,North China were selected for a sys-tematic geochemical,mineralogical and geochronological study,which provides an opportunity to ex-plore the interaction between the continental crust and mantle beneath the north margin of the North China craton.Except one basalt sample(SiO2= 50.23%),the other nine samples are andesitic with SiO2 contents ranging from 53% to 59%.They have relatively high MgO(3.4%―6.1%,Mg#=50―64) and Ni and Cr contents(Ni 27×10?6―197×10?6,Cr 51×10?6―478×10?6).Other geochemical characteristics of Zhangwu high-Mg andesites(HMAs) include strong fractionation of light rare earth elements(LREE) from heavy rare earth elements(HREE),and Sr from Y,with La/Yb greater than 15,and high Sr/Y(34― 115).Zircons of andesite YX270 yield three age groups with no Precambrian age,which precludes ori-gin of the Zhangwu HMAs from the partial melting of the Precambrian crust.The oldest age group peaking at 253 Ma is interpreted to represent the collision of the Siberia block and the North China block,resulting in formation of the Central Asian orogenic belt by closure of the Mongol-Okhotsk Ocean.The intermediate age group corresponds to the basalt underplating which caused the wide-spread coeval granitoids in the North China craton with a peak 206Pb/238U age of 172 Ma.The youngest age group gives a 206Pb/238U age of 126±2 Ma,which is interpreted as the eruption age of the Zhangwu HMAs.The high 87Sr/86Sri(126 Ma)>0.706 and low εNd(t)= ?6.36―?13.99 of the Zhangwu HMAs are distinct from slab melts.The common presence of reversely zoned clinopyroxene phenocrysts in the Zhangwu HMAs argues against the origin of the Zhangwu HMAs either from melting of the water saturated mantle or melting of the lower crust.In light of the evidence mentioned above,the envisaged scenario for the formation of the Zhangwu HMAs is related to the basaltic underplating at the base of the crust,which led to the thickening of the lower crust and formation of lower crustal eclogite,followed by foundering of the eclogitic lower crust into the asthenosphere.The foundered eclogite then melted and the resul-tant melts interacted with surrounding peridotite during their upward transport,which finally produced the high-Mg andesites.This well explains the high-Mg adakitic characters and absence of ancient in-herited zircon in the Zhangwu lavas.     

陕西小秦岭地区太华群的锆石U-Pb年龄和 Hf同位素组成

本文对陕西华山岩体南侧一个太华群黑云斜长片麻岩进行了地球化学、锆石U-Pb年龄和Hf同位素分析.地球化学分析显示其原岩为中酸性钙碱性花岗质岩石,稀土含量较低( ∑REE =83.13×10-6),但富集Pb和LILE元素(如Rb、Ba).锆石的176Hf/177Hf比值变化于0.281258～0.281404,具明显负的εHf(t)值(-6.86～- 11.23).锆石的Hf同位素模式年龄(2.96 ～3.24Ga)表明原岩是由中太古代地壳演化而来.对比显示小秦岭太华群黑云斜长片麻岩与鲁山地区的太华群具有相似的中太古代地壳源区,但它们的形成时代可能不同.锆石内部结构、Th/U比值以及定年结果显示小秦岭地区的太华群在～1.91Ga经历了一期重要的变质热事件,该事件与Columbia超大陆拼合时的全球性碰撞造山事件相关联.小秦岭太华群为华北克拉通块体南缘的地质单元,但各地区太华群在原岩组成、形成时代和变质时代上具有不同的特征,太华群应是一个杂岩体,至少可以解体为新太古代和古元古代两部分.