Experimental determination of REE partition coefficients between zircon,garnet and melt: a key to understanding high‐T crustal processes

The partitioning of rare earth elements (REE) between zircon, garnet and silicate melt was determined using synthetic compositions designed to represent partial melts formed in the lower crust during anatexis. The experiments, performed using internally heated gas pressure vessels at 7 kbar and 900–1000 °C, represent equilibrium partitioning of the middle to heavy REE between zircon and garnet during high‐grade metamorphism in the mid to lower crust. The D_REE (zircon/garnet) values show a clear partitioning signature close to unity from Gd to Lu. Because the light REE have low concentrations in both minerals, values are calculated from strain modelling of the middle to heavy REE experimental data; these results show that zircon is favoured over garnet by up to two orders of magnitude. The resulting general concave‐up shape to the partitioning pattern across the REE reflects the preferential incorporation of middle REE into garnet, with D_Gd (zircon/garnet) ranging from 0.7 to 1.1, D_Ho (zircon/garnet) from 0.4 to 0.7 and D_Lu (zircon/garnet) from 0.6 to 1.3. There is no significant temperature dependence in the zircon–garnet REE partitioning at 7 kbar and 900–1000 °C, suggesting that these values can be applied to the interpretation of zircon–garnet equilibrium and timing relationships in the ultrahigh‐T metamorphism of low‐Ca pelitic and aluminous granulites.     

Low‐P and high‐T metamorphism of basalts: Insights from the Sudbury impact melt sheet aureole and thermodynamic modelling

Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K₂O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K₂O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.     

P–T–t–d evolution of orogenic middle crust of the Roc de Frausa Massif (Eastern Pyrenees): a result of horizontal crustal flow and Carboniferous doming?

Structural, petrological and textural studies are combined with phase equilibria modelling of metapelites from different structural levels of the Roc de Frausa Massif in the Eastern Pyrenees. The pre‐Variscan lithological succession is divided into the Upper, Intermediate and Lower series by two orthogneiss sheets and intruded by Variscan igneous rocks. Structural analysis reveals two phases of Variscan deformation. D1 is marked by tight to isoclinal small‐scale folds and an associated flat‐lying foliation (S1) that affects the whole crustal section. D2 structures are characterized by tight upright folds facing to the NW with steep NE–SW axial planes. D2 heterogeneously reworks the D1 fabrics, leading to an almost complete transposition into a sub‐vertical foliation (S2) in the high‐grade metamorphic domain. All structures are affected by late open to tight, steeply inclined south‐verging NW–SE folds (F3) compatible with steep greenschist facies dextral shear zones of probable Alpine age. In the micaschists of the Upper series, andalusite and sillimanite grew during the formation of the S1 foliation indicating heating from 580 to 640 °C associated with an increase in pressure. Subsequent static growth of cordierite points to post‐D1 decompression. In the Intermediate series, a sillimanite–biotite–muscovite‐bearing assemblage that is parallel to the S1 fabric is statically overgrown by cordierite and K‐feldspar. This sequence points to ~1 kbar of post‐D1 decompression at 630–650 °C. The Intermediate series is intruded by a gabbro–diorite stock that has an aureole marked by widespread migmatization. In the aureole, the migmatitic S1 foliation is defined by the assemblage biotite–sillimanite–K‐feldspar–garnet. The microstructural relationships and garnet zoning are compatible with the D1 pressure peak at ~7.5 kbar and ~750 °C. Late‐ to post‐S2 cordierite growth implies that F2 folds and the associated S2 axial planar leucosomes developed during nearly isothermal decompression to <5 kbar. The Lower series migmatites form a composite S1–S2 fabric; the garnet‐bearing assemblage suggests peak P–T conditions of >5 kbar at suprasolidus conditions. Almost complete consumption of garnet and late cordierite growth points to post‐D2 equilibration at <4 kbar and <750 °C. The early metamorphic history associated with the S1 fabric is interpreted as a result of horizontal middle crustal flow associated with progressive heating and possible burial. The upright F2 folding and S2 foliation are associated with a pressure decrease coeval with the intrusion of mafic magma at mid‐crustal levels. The D2 tectono‐metamorphic evolution may be explained by a crustal‐scale doming associated with emplacement of mafic magmas into the core of the dome.     

The tectono‐metamorphic evolution of the very low‐grade hangingwall constrains two‐stage gneiss dome formation in the Montagne Noire (Southern France)

The Montagne Noire in the southernmost French Massif Central is made of an ENE‐elongated gneiss dome flanked by Palaeozoic sedimentary rocks. The tectonic evolution of the gneiss dome has generated controversy for more than half a century. As a result, a multitude of models have been proposed that invoke various tectonic regimes and exhumation mechanisms. Most of these models are based on data from the gneiss dome itself. Here, new constraints on the dome evolution are provided based on a combination of very low‐grade petrology, K–Ar geochronology, field mapping and structural analysis of the Palaeozoic western Mont Peyroux and Faugères units, which constitute part of the southern hangingwall of the dome. It is shown that southward‐directed Variscan nappe‐thrusting (D₁) and a related medium‐P metamorphism (M₁) are only preserved in the area furthest away from the gneiss dome. The regionally dominant pervasive tectono‐metamorphic event D₂/M₂ largely transposes D₁ structures, comprises a higher metamorphic thermal gradient than M₁ (transition low‐P and medium‐P metamorphic facies series) and affected the rocks between c. 309 and 300 Ma, post‐dating D₁/M₁ by more than 20 Ma. D₂‐related fabrics are refolded by D₃, which in its turn, is followed by dextral‐normal shearing along the basal shear zone of both units at c. 297 Ma. In the western Mont Peyroux and Faugères units, D₂/M₂ is largely synchronous with shearing along the southern dome margin between c. 311 and 303 Ma, facilitating the emplacement of the gneiss dome into the upper crust. D₂/M₂ also overlaps in time with granitic magmatism and migmatization in the Zone Axiale between c. 314 and 306 Ma, and a related low‐P/high‐T metamorphism at c. 308 Ma. The shearing that accompanied the exhumation of the dome therefore was synchronous with a peak in temperature expressed by migmatization and intrusion of melts within the dome, and also with the peak of metamorphism in the hangingwall. Both, the intensity of D₂ fabrics and the M₂ metamorphic grade within the hangingwall, decrease away from the gneiss dome, with grades ranging from the anchizone–epizone boundary to the diagenetic zone. The related zonation of the pre‐D₃ metamorphic field gradients paralleled the dome. These observations indicate that D₂/M₂ is controlled by the exhumation of the Zone Axiale, and suggest a coherent kinematic between the different crustal levels at some time during D₂/M₂. Based on integration of these findings with regional geological constraints, a two‐stage exhumation of the gneiss dome is proposed: during a first stage between c. 316 and 300 Ma dome emplacement into the upper crust was controlled by dextral shear zones arranged in a pull‐apart‐like geometry. The second stage from 300 Ma onwards was characterized by northeast to northward extension, with exhumation accommodated by north‐dipping detachments and hangingwall basin formation along the northeastern dome margin.     

Significance of post‐peak metamorphic reaction microstructures in the ultrahigh temperature Eastern Ghats Province,India

Ultrahigh temperature (UHT) granulites in the Eastern Ghats Province (EGP) have a complex P–T–t history. We review the P–T histories of UHT metamorphism in the EGP and use that as a framework for investigating the P–T–t history of Mg–Al‐rich granulites from Anakapalle, with the express purpose of trying to reconcile the down‐pressure‐dominated P–T path with other UHT localities in the EGP. Mafic granulite that is host to Mg–Al‐rich metasedimentary granulites at Anakapalle has a protolith age of c. 1,580 Ma. Mg–Al‐rich metasedimentary granulites within the mafic granulite at Anakapalle were metamorphosed at UHT conditions during tectonism at 960–875 Ma, meaning that the UHT metamorphism was not the result of contact metamorphism from emplacement of the host mafic rock. Reworking occurred during the Pan‐African (c. 600–500 Ma) event, and is interpreted to have produced hydrous assemblages that overprint the post‐peak high‐T retrograde assemblages. In contrast to rocks elsewhere in the EGP that developed post‐peak cordierite, the metasedimentary granulites at Anakapalle developed post‐peak, generation ‘2’ reaction products that are cordierite‐absent and nominally anhydrous. Therefore, rocks at Anakapalle offer the unique opportunity to quantify the pressure drop that occurred during so‐called M2 that affected the EGP. We argue that M2 is either a continuation of M1 and that the overall P–T path shape is a complex counter‐clockwise loop, or that M1 is an up‐temperature counter‐clockwise deviation superimposed on the M2 path. Therefore, rather than the rocks at Anakapalle having a metamorphic history that is apparently anomalous from the rest of the EGP, we interpret that other previously studied localities in the EGP record a different part of the same P–T path history as Anakapalle, but do not preserve a significant record of pressure decrease. This is due either to the inability of refractory rocks to extensively react to produce a rich mineralogical record of pressure decrease, or because the earlier high‐P part of the rocks history was erased by the M1 loop. Irrespective of the specific scenario, models for the tectonic evolution of the EGP must take the substantial pressure decrease during M2 into account, as it is probable the P–T record at Anakapalle is a reflection of tectonics affecting the entire province.     

Geochronological and petrological constraints from the evolution in the Saxon Granulite Massif,Germany, on the Variscan continental collision orogeny

Controversy over the plate tectonic affinity and evolution of the Saxon granulites in a two‐ or multi‐plate setting during inter‐ or intracontinental collision makes the Saxon Granulite Massif a key area for the understanding of the Palaeozoic Variscan orogeny. The massif is a large dome structure in which tectonic slivers of metapelite and metaophiolite units occur along a shear zone separating a diapir‐like body of high‐P granulite below from low‐P metasedimentary rocks above. Each of the upper structural units records a different metamorphic evolution until its assembly with the exhuming granulite body. New age and petrologic data suggest that the metaophiolites developed from early Cambrian protoliths during high‐P amphibolite facies metamorphism in the mid‐ to late‐Devonian and thermal overprinting by the exhuming hot granulite body in the early Carboniferous. A correlation of new Ar–Ar biotite ages with published P–T–t data for the granulites implies that exhumation and cooling of the granulite body occurred at average rates of ~8 mm/year and ~80°C/Ma, with a drop in exhumation rate from ~20 to ~2.5 mm/year and a slight rise in cooling rate between early and late stages of exhumation. A time lag of c. 2 Ma between cooling through the closure temperatures for argon diffusion in hornblende and biotite indicates a cooling rate of 90°C/Ma when all units had assembled into the massif. A two‐plate model of the Variscan orogeny in which the above evolution is related to a short‐lived intra‐Gondwana subduction zone conflicts with the oceanic affinity of the metaophiolites and the timescale of c. 50 Ma for the metamorphism. Alternative models focusing on the internal Variscan belt assume distinctly different material paths through the lower or upper crust for strikingly similar granulite massifs. An earlier proposed model of bilateral subduction below the internal Variscan belt may solve this problem.     

Carboniferous eclogite and garnet–omphacite granulite from northeastern Hainan Island,South China: Implications for the evolution of the eastern Palaeo‐Tethys

High‐P (HP) eclogite and associated garnet–omphacite granulite have recently been discovered in the Mulantou area, northeastern Hainan Island, South China. These rocks consist mainly of garnet, omphacite, hornblende, quartz and rutile/ilmenite, with or without zoisite and plagioclase. Textural relationships, mineral compositions and thermobarometric calculations demonstrate that the eclogite and garnet–omphacite granulite share the same three‐stage metamorphic evolution, with prograde, peak and retrograde P?T conditions of 620–680°C and 8.7–11.1 kbar, 820–860°C and 17.0–18.2 kbar, and 700–730°C and 7.1–8.5 kbar respectively. Sensitive high‐resolution ion microprobe U–Pb zircon dating, coupled with the identification of mineral inclusions in zircon, reveals the formation of mafic protoliths before 355 Ma, prograde metamorphism at c. 340–330 Ma, peak to retrograde metamorphism at c. 310–300 Ma, and subsequent pegmatite intrusion at 295 Ma. Trace element geochemistry shows that most of the rocks have a MORB affinity, with initial ε_Nd values of +2.4 to +6.7. As with similar transitional eclogite–HP granulite facies rocks in the thickened root in the European Variscan orogen, the occurrence of relatively high P?T metamorphic rocks of oceanic origin in northeastern Hainan Island suggests Carboniferous oceanic subduction leading to collision of the Hainan continental block, or at least part of it, with the South China Block in the eastern Palaeo‐Tethyan tectonic domain.     

New P–T constraints on the Tamayen glaucophane‐bearing rocks,eastern Taiwan: Perple_X modelling results and geodynamic implications

New pseudosection modelling was applied to better constrain the P–T conditions and evolution of glaucophane‐bearing rocks in the Tamayen block of the Yuli belt, recognized as the world's youngest known blueschist complex. Based on the predominant clinoamphibole, textural relationships, and mineral compositions, these glaucophane‐bearing high‐P rocks can be divided into four types. We focused on the three containing garnet. The chief phase assemblages are (in decreasing mode): amphibole + quartz + epidote + garnet + chlorite + rutile/titanite (Type‐I), phengite + amphibole + quartz + garnet + chlorite + epidote + titanite + biotite + magnetite (Type‐II), and amphibole + quartz + albite + epidote + garnet + rutile + hematite + titanite (Type‐III). Amphibole exhibits compositional zoning from core to rim as follows: glaucophane → pargasitic amphibole → actinolite (Type‐I), barroisite → Mg‐katophorite/taramite → Fe‐glaucophane (Type‐II), glaucophane → winchite (Type‐III). Using petrographic data, mineral compositions and Perple_X modelling (pseudosections and superimposed isopleths), peak P–T conditions were determined as 13 ± 1 kbar and 550 ± 40 °C for Type‐I, 10.5 ± 0.5 kbar and 560 ± 30 °C for Type‐II (thermal peak) and 11 ± 1 kbar and 530 ± 30 °C for Type‐III. The calculations yield higher pressures and temperatures than previously thought; the difference is ~1–6 kbar and 50–200 °C. The three rock types record similar P–T retrograde paths with clockwise trajectories; all rocks followed trajectories with substantial pressure decrease under near‐isothermal conditions (Type‐I and Type‐III), with the probable exception of Type‐II where decompression followed colder geotherms. The P–T paths suggest a tectonic environment in which the rocks were exhumed from maximum depths of ~45 km within a subduction channel along a relative cold geothermal gradient of ~11–14 °C km^?1.     

Contrast in stress–strain history during exhumation between high- and ultrahigh-pressure metamorphic units in the Western Alps: Microboudinage analysis of piemontite in metacherts

Our analyses of microboudinage structures of piemontite grains embedded within six samples of metachert, one collected from an ultrahigh-pressure (UHP) metamorphic unit at Lago di Cignana in Italy of the Western Alps, and the other five from surrounding high-pressure (HP) metamorphic units in Italy and France, have revealed that the structures are all symmetrical in type, and were presumably produced in coaxial strain fields. Stress–strain analyses of the microboudinaged grains revealed significant contrasts in the stress and strain histories of the UHP and HP metamorphic units, with the differential stress recorded by the UHP sample being unequivocally lower than that recorded by the five HP samples. In addition, our analyses showed that the UHP sample underwent stress-relaxation during microboudinage, whereas the five HP samples did not. On the basis of these observations and analyses we discuss the mechanical decoupling of the UHP and HP units that led to different histories in differential stress between the units during exhumation of the Western Alps.     

羌塘地区榴辉岩中矿物出溶体及其成因机制探讨

西藏羌塘地区榴辉岩石榴子石和磷灰石中均发育矿物出溶体,结合电子探针和扫描电镜分析及能谱分析,确定了石榴子石中的出溶体有金红石、石英和角闪石,指示其可能经历了高压/超高压变质作用。本研究在磷灰石中发现了金红石出溶,并认为其可能是在高压/超高压条件下元素相互置换的结果,置换方式为Ti~(4+)(Fe~(2+)、Si~(4+))=2Ca~(2+),这些出溶体的形成为榴辉岩曾经历高压/超高压变质作用提供了矿物学证据。