辉石巨晶中的硫化物及其成因

我国一些地区玄武岩辉石巨晶中的硫化物球泡(0.02-0.05mm)呈点阵式、散布式、定向带状或微裂隙羽状分布。硫化矿物组合是磁黄铁矿-镍黄铁矿-黄铜矿,其中以磁黄铁矿为主(～90％)。根据硫化物的规则排布以及高温矿物组合推测点阵式、散布式硫化物形成于地幔。是由溶解了～1％S的硅酸盐熔体在减压上升过程中析出过饱和的硫所致。     

Oxidation Experiment of Natural Megacrystal Clinopyroxene: Implications for Assignment of Mössbauer Spectra

The Mössbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A‐A', B‐B', C‐C' and D‐D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D‐D' doublet assigned to Fe³⁺at the lattice site M***1 in previous papers. Particularly, the assignment and interpretation of the C‐C' doublet are diverse. The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000°C and oxygen fugacity of FMQ buffer in 1, 2, ***3 and 5 days respectively. The oxidized samples were then measured by X‐ray diffraction spectrometry and Mössbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe²⁺ → Fe³⁺at M1 under the subsolidus conditions, which is consistent with the increase of the area of the D‐D' doublet when the heating time increases. Accordingly, the area of the A‐A' and B‐B' doublets decreases with the increasing heating time. However, the area of C‐C' keeps almost constant. Therefore, the 4 sets of doublets can be assigned correctly as follows: A‐A' doublet to Fe⁺²at M1, B‐B' Fe²⁺at M1, C‐C' Fe²⁺at M2, and D‐D' Fe³⁺at M1. The M1 site splitting is due to the NNN (Next Nearest Neighbour) effect of the M2 site. The amount of Fe³⁺at the tetrohedral site of megacrystal clinopyroxene is negligible according to this study.     

Clinopyroxene REE Geochemistry of the Red Hills Peridotite, New Zealand: Interpretation of Magmatic Processes in the Upper Mantle and in the Moho Transition Zone

The Red Hills peridotite in the Dun Mountain ophiolite of SouthIsland, New Zealand, is assumed to have been produced in a paleo-mid-oceanridge tectonic setting. The peridotite is composed mostly ofharzburgite and dunite, which represent residual mantle andthe Moho transition zone (MTZ), respectively. Dunite channelswithin harzburgite blocks of various scales represent the MTZcomponent. Plagioclase- and clinopyroxene-bearing dunites occursporadically within common dunites. These dunites representproducts of melt–wall-rock interaction. Chondrite-normalizedrare earth element (REE) patterns of MTZ clinopyroxenes showa wide compositional range. Clinopyroxenes in plagioclase dunitesare extremely depleted in light REE (LREE) ([Lu/La]_N >100),and are comparable with clinopyroxenes in abyssal peridotitesfrom normal mid-ocean ridges. Interstitial clinopyroxenes inthe common dunite have flatter patterns ([Lu/La]_N 2) comparablewith those for dunite in the Oman ophiolite. Clinopyroxenesin the lower part of the residual mantle harzburgites are evenmore strongly depleted in LREE ([Lu/La]_N = 100–1000) thanare mid-ocean ridge peridotites, and rival the most depletedabyssal clinopyroxenes reported from the Bouvet hotspot. Incontrast, those in the uppermost residual mantle harzburgiteand harzburgite blocks in the MTZ are less LREE depleted ([Lu/La]_N= 10–100), and are similar to those in plagioclase dunite.Clinopyroxenes in the clinopyroxene dunite in the MTZ are similarto those reported from mid-ocean ridge basalt (MORB) cumulates,and clinopyroxenes in the gabbroic rocks have compositions similarto those reported from MORB. Strong LREE and middle REE (MREE)depletion in clinopyroxenes in the harzburgite suggests thatthe harzburgites are residues of two-stage fractional melting,which operated initially in the garnet field, and subsequentlycontinued in the spinel lherzolite field. The early stage meltingproduced the depleted harzburgite. The later stage melting wasresponsible for the gabbroic rocks and dunite. Strongly LREE–MREE-depletedclinopyroxene in the lower harzburgite and HREE-enriched clinopyroxenein the upper harzburgite and plagioclase dunite were formedby later reactive melt migration occurring in the harzburgite. KEY WORDS: clinopyroxene REE geochemistry; Dun Mountain ophiolite; Moho transition zone; orogenic peridotite; Red Hills     

藏北羌塘戈木错渐新世碱性钾质火山岩中绿核辉石的成因:岩浆补给—混合过程

藏北戈木错渐新世碱性钾质火山岩中单斜辉石斑晶普遍出现正环带、反环带和韵律环带结构,多具有"绿核辉石"的结构特征。通过矿物电子探针测得"绿核辉石"的核部有高Mg#和低Mg#两种不同成分,两者都不同程度发育有筛孔状熔蚀结构,环带结构主要发育在辉石的幔部到边部,与绿色核部存在明显的成分间断,幔部环带结构的成分变化范围相对较窄。"绿核辉石"的成分和结构特征反映了同源碱性钾质岩浆在壳内岩浆房中发生了岩浆补给-混合作用,复杂的环带结构记录了混合岩浆的结晶过程。     

雅鲁藏布江缝合带西段错不扎铬铁矿特征及形成环境

雅鲁藏布江蛇绿岩带是国内铬铁矿床出露点最多,且铬铁矿石储量、产量最大的一个蛇绿岩带。根据空间展布规律,该岩带被划分为东段(曲水—墨脱)、中段(昂仁—仁布)和西段(萨嘎至中印边境)3部分。其中,西段自萨嘎以西分为南、北两支亚带。长期以来的研究工作主要集中在东段和中段,西段的研究程度非常薄弱,尤其是北亚带。不同区段研究程度的不平衡十分不利于雅鲁藏布江蛇绿岩带内铬铁矿找矿工作的开展。错不扎蛇绿岩体位于雅鲁藏布江缝合带西段的北亚带,呈北西-南东向带状产出,主要由方辉橄榄岩组成,并普遍发育基性岩脉。野外地质调查在该蛇绿岩体中发现了多个铬铁矿化点,矿化体呈透镜状产于方辉橄榄岩中,出露地表的长度为0.5～1m,厚为0.2～0.5 m,矿石均为致密块状。电子探针分析结果表明,错不扎铬铁矿属于高铬型铬铁矿,铬尖晶石的Cr#[=100×Cr/(Cr+Al)]为75～78,Mg#[=100×Mg/(Mg+Fe2+)]为66～69。计算结果表明,母岩浆的FeO/MgO比值为0.51～0.65,Al2O3和Ti O2含量分别为11.27%～12.1%和0.19%～0.4%,与玻安质岩浆的化学成分相当。然而,针状单斜辉石出溶体的发现指示错不扎铬铁矿可能还经历了一个深部作用过程。     

基于镁铁-超镁铁岩中单斜辉石主量元素含量的决策树集成算法对比

依靠岩浆构造环境的地球化学成分认识岩浆形成过程是岩石地球化学中的重要应用。当前利用岩石地球化学成分判别构造环境的工作还不够深入。用4种基于决策树的机器学习方法对来自全球新生代洋岛玄武岩(OIB)、岛弧玄武岩(IAB)及大洋中脊玄武岩(MORB)等镁铁-超镁铁岩中单斜辉石的13种主量元素构成数据集进行了岩浆构造环境判别和主要特征排序。通过对比4种基于决策树的机器学习方法,验证了树类算法对于地球化学成分识别问题的有效性,并总结出4种方法在处理岩浆构造环境判别问题时的优劣:决策树算法判别过程更易于理解,但是其准确率欠佳;boosting算法中的AdaBoost和GBDT对于岩浆构造环境的鉴别准确度较高,但构造过程复杂;bagging集成算法随机森林在权衡性能和模型可理解性时不失为一个良好的选择。此外,还通过4种算法的特征重要性排序得出Cr_2O_3,TFeO,TiO_2,FeO和Al_2O_3是进行岩浆构造环境判别的重要成分。     

西藏雅鲁藏布江缝合带中段仁布豆荚状铬铁矿成因及构造意义

藏南雅鲁藏布江缝合带为目前国内铬铁矿储量最大的缝合带.本文报道了缝合带中段仁布蛇绿岩的豆荚状铬铁矿床,围绕矿床特征开展成因探讨,对缝合带的形成演化和成矿作用提供新制约.仁布蛇绿岩呈近东西走向带状产出,主要由近30个大小不等的地幔橄榄岩体组成.地幔橄榄岩体主要为经历不同程度蛇纹石化的方辉橄榄岩和少量纯橄岩.在纯橄岩和方辉...     

山东刚玉巨晶中包裹体研究Ⅱ：氯化物与地幔液相的物质组成

利用电子探针,扫描电镜在山东碱性玄武岩中产出的刚玉巨晶中发现了许多氯化物包裹体,这些氯化物可能以石盐为主,它的发现表明在较浅深度的地幔液相中也存在较多的氯。     

Genesis of the Kamioka Skarn Deposits: An Important Role of Clinopyroxene Skarn and Graphite-bearing Limestone in Precipitating Sulfide Ore

Abstract: A genetical relationship between skarn formation and mineralization is investigated for the Kamioka skarn deposits which are the largest Zn-Pb producer in Japan. In the Mozumi deposit, one of main deposits in the Kamioka mining area as well as Tochibora and Maruyama, clinopyroxene skarn was generally subjected to later replacement by garnet or magnetite–calcite–quartz during the Zn-Pb mineralization. The replacement of hedenbergitic clinopyroxene by andraditic garnet resulted in the formation of diopsidic clinopyroxene relicts. With the progress of replacement, the S/So value (So: an estimated area occupied by an original clinopyroxene grain in a thin section, S: a total area of relict clinopyroxene fragments) which is an index of the degree of replacement decreases from 0. 7 to 0. 1, and the hedenbergite mole percent of relict clinopyroxene decreases drastically from about 65 to less than 40. A close association of andraditic garnet and sphalerite suggests that heden-bergitic clinopyroxene skarn played an important role to reduce the relatively oxic ore-forming fluid enriched in Zn²⁺ and SO4^2– and to precipitate sphalerite from the fluid. Ferrous iron in the hedenbergitic clinopyroxene skarn was oxidized to form andraditic garnet. Besides this garnet formation, the mineral assemblage of magnetite–calcite–quartz replaced the clinopyroxene skarn at the time of mineralization. In both cases, the reduction of relatively oxic ore-forming fluid by hedenbergitic clinopy-roxene skarn at the later stage brought about the precipitation of sulfide minerals. In contrast, these types of later replacement are not found in the Tochibora deposit. Instead, graphite-bearing crystalline limestone and relatively fresh clinopyroxene skarn are common. Mineralized clinopyroxene skarn has high graphite carbon contents relative to barren one, suggesting that the amount of graphite in the skarn was an important controlling factor for mineralization. It is very likely that the graphite played a role of reducing agent during the mineralization in the Tochibora deposit.     

Progressive changes in lithological association of the Sanbagawa metamorphic complex,Southwest Japan: Relict clinopyroxene and detrital zircon perspectives

The main tectono‐stratigraphic unit (Shirataki unit) of the Sanbagawa metamorphic complex in central Shikoku is characterized by abundant mafic schist layers that show the mid‐ocean ridge basalt (MORB) affinity. These MORB‐derived schist layers are absent in a southern (structurally lower) domain within the unit. Instead, sporadic occurrences of small metabasite lenses that contain relict igneous minerals (Ti‐rich augite and kaersutite) indicative of alkali basalt magmatism are newly recognized in the southern domain. Compositions of relict clinopyroxene in metabasalt are useful to identify the tectonic setting and origin of the protolith basalt, and those in each unit of the Sanbagawa metamorphic complex are presented. The metamorphic grade of the Shirataki unit generally increases structurally upwards in the southern side of the highest‐grade zone, and metamorphic zonation is subparallel to lithostratigraphic succession. The protolith assemblage of the Shirataki unit shows a distinct change from the southern low‐grade domain (lower Shirataki subunit) composed of terrigenous sedimentary rocks (mudstone and sandstone) with minor alkali basalt to the northern higher‐grade domain (upper Shirataki subunit) consisting of terrigenous and pelagic sedimentary rocks with abundant MORB. The youngest detrital zircon U–Pb ages (ca 95–90 Ma) suggest that both domains have Late Cretaceous depositional ages at the trench. Progressive peeling of oceanic plate stratigraphy during subduction can account for the observed change of lithological association in the Shirataki unit.