酸溶-电感耦合等离子发射光谱法测定密西西比型铅锌矿床矿石中的铅

密西西比型(MVT)铅锌矿床的主要矿物有方铅石、闪锌矿,常伴生有重晶石、萤石等矿物,使得MVT型矿石在酸处理过程中易生成不溶于水和酸的硫酸铅钡复盐,故而检测矿样中铅的含量偏低。本文建立了采用盐酸-硝酸-氢氟酸体系酸溶分解MVT型矿石,电感耦合等离子体发射光谱法(ICP-OES)测定铅含量的分析方法。实验比较了盐酸-硝酸-氢氟酸、盐酸-硝酸-氢氟酸-高氯酸、盐酸-硝酸-硫酸三种酸溶体系的溶样效果,并通过X射线衍射论证了方法的可行性。结果表明,盐酸-硝酸-氢氟酸体系克服了复盐硫酸铅钡和硫酸铅沉淀的生成,适量的氢氟酸促进了Pb SO4的溶解,X射线衍射表征也表明此种酸溶体系的沉淀中不含有Pb SO4,可更彻底地分解MVT型矿石。本方法精密度(RSD)为0.3%~0.6%,实际样品的加标回收率为96.0%~99.2%,铅的最佳检测范围为0.01%~20.0%。     

Characterization of Galena and Vein Paragenesis in the Penjom Gold Mine, Malaysia: Trace Elements, Lead Isotope Study and Relationship to Gold Mineralization Episodes

The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsenopyrite, and minor base metals including galena. Trace element and lead isotope analysis was undertaken on nine samples that represent two stages of galena formed during two tectonic events. Both the Pb isotopes and the trace elements show that the first stage galena within the mineralized areas at the footwall has different geochemical characteristics compared with galena in non mineralized areas in the hanging wall, suggesting that galena crystallized from two different ore fluids and probably at two different times. Higher Te, Se and Bi in the galena from the mineralized area may indicate hydrothermal fluids that migrate through the structural conduit and leached out the metal along the pathway that consist of dominant carbonaceous unit. The Pb isotopic ratio composition are transitional between the bulk crustal growth and an upper crustal growth curve, indicating that derivation was from arc rocks associated with continental crust or a crustal source that includes arc volcanic and old continental sedimentary rocks.     

改性氢氧化镁对地下水中铅镉的稳定化性能研究

为研究OH-缓释剂对铅、镉污染地下水修复的可行性,通过室内实验制备改性氢氧化镁,并对其去除地下水中Pb和Cd的性能进行研究。实验结果表明,重金属的稳定化机理主要为沉淀反应。在去除单一重金属(Pb或Cd)实验中,Pb和Cd的去除率都可达到99%以上,反应符合一级反应动力学,反应速率常数分别为0.173 7 min-1和0.003 7 min-1。改性氢氧化镁在处理Pb和Cd的复合污染时Pb优先于Cd反应,Pb的存在会对Cd的沉淀起到抑制作用。     

引发强降水的一次东移高原云团的能量演变特征研究

利用日本气象厅葵花-8卫星亮温资料、欧洲中心ERA5（the fifth generation of European Centre for Medium-Range Weather Forecasts Reanalysis）再分析资料,根据时间尺度分解的局地能量诊断方法,本文从能量学多个角度研究了2016年6月5日00时（协调世界时,下同）至6日15时（持续40小时）一次东移并引发强降水的高原对流云团,得到了以下主要结论。本次事件中,高原东移对流云团在不同阶段的主要影响系统有所不同。移出高原前,其主要受高原涡和高原短波槽的共同影响,随着云团移出高原,高原涡消亡,而高原短波槽则随时间发展加强,成为东移云团的最主要影响系统。高原东移对流云团具有显著的深对流特征,自西向东引发了一系列的降水,移出高原后,其对流重心显著降低,降水达到最强。不同阶段高原东移对流云团的能量转换特征显著不同。云团位于高原上时（第一阶段）,背景场通过动能的降尺度能量级串为造成强降水的扰动流直接提供能量,这是此阶段扰动流动能维持的主要方式;云团移出高原过程中（第二阶段）,降水凝结潜热明显增强,由此制造的扰动有效位能也显著增强。在垂直运动配合下,扰动有效位能斜压释放所制造的动能是本阶段造成强降水扰动流动能维持的最主要能量来源;云团移出高原后（第三阶段）,背景场对造成强降水扰动流的影响再次增强,但是不同于第一阶段的直接影响方式,该阶段背景场的作用是以一种间接的影响方式出现。其首先通过有效位能的降尺度级串将背景场的有效位能转换为扰动流的有效位能,然后通过扰动有效位能的斜压能量释放为扰动流的动能维持不断地提供能量。此外,本阶段内还出现了扰动流向背景场动能的升尺度级串供给（即扰动流的反馈）,但其强度不足以对背景场的演变产生显著影响。     

Mired in the past — looking to the future: Geochemistry of peat and the analysis of past environmental changes

Peat cores from ombrotrophic bogs have been used as a valuable archive to study environmental change for over a century. Much of this focus on the peat record has been on biological proxies of environmental change, such as pollen and peat-forming macrofossils, but there is growing interest in the geochemical record to study environmental changes. Several studies of long-term peat records in Europe have reconstructed past changes in atmospheric lead pollution, for example, and the general cohesiveness of the results and their agreement with known historical trends in metal production exemplify the best potential of peat geochemistry as an environmental archive. Based on the success with lead, a current emphasis in peat reconstructions is to assess the record of past mercury deposition and results thus far show generally consistent trends, e.g., a pre-anthropogenic mercury accumulation rate of about 0.5–1.5 μg Hg m^− 2 year^− 1. Despite this general consistency there is increasing concern that there may be diagenetic effects on the quantitative record of some metals, which can be inferred based on a strong relationship between mercury and other organically bound elements and proxies for peat decomposition (C/N ratio). However, it is possible that changes in decomposition and the alteration of some metal records could provide climatic information. A few recent studies show that closer examination of the geochemical matrix, in some cases along with biological proxies, can provide valuable information on landscape changes and climate; for example, partitioning metals into different weight fractions and source regions can be applied to climate studies. The best interpretations of the peat geochemical record in the context of environmental and climate change will likely come when geochemical and biological records are considered simultaneously.     

Physico-chemical Speciation of Lead in South San Francisco Bay

The speciation of lead at a site in the South San Francisco Bay was determined using a combination of physical size fractionation and electrochemical analyses. The ‘ total dissolvable ’ Pb was 8·1 nM from analysis of an acidified unfiltered sample. The ‘ dissolved ’ Pb was equal to 0·20 nM (41 ng l⁻¹), only 2·5% of the ‘ total dissolvable ’ Pb. The difference yielded the ‘ particulate ’ Pb equal to 7·9 nM (1·6 μg l⁻¹). Results from crossflow ultrafiltration indicated that almost all (0·19 nM) of the dissolved Pb was ‘ in solution ’ [<10K nominal molecular weight (MW)] and that colloidal Pb (10K MW to 0·2 μm)accounted for onlyc. 1% of the dissolved Pb at this station. This small concentration (0·01 nM) of colloidal Pb may be attributed to the low amount of organic carbon associated with colloid size fraction as determined by dissolved organic carbon analyses.The chemical speciation of lead was determined in the dissolved sample and ultrafiltered sub-sample. Differential pulse anodic stripping voltammetry (DPASV) on a thin mercury film (TMF) rotating glassy carbon disk electrode (RGCDE) was used to distinguish the kinetically labile inorganic species (Pb′) from the Pb-chelated by organic ligands (PbL_i). Lead titration results were similar for both samples revealing that Pb′, PbL_iand excess unbound ligands were present primarily in the ultrafiltrate, rather than in the colloidal phase. The titration data can be interpreted as dissolved Pb being influenced by two classes of Pb-binding ligands. In the dissolved sample, the concentration of the stronger class of ligands was [L₁]=0·89±0·35 nM, with a conditional stability constant ofK^cond_L1,Pb′=3±1×10¹⁰M⁻¹. The weaker class was [L₂]=12·8±1·9 nM, withK^cond_L1,Pb′=4±1×10⁸ M⁻¹. The presence of these ligands, in excess of the dissolved Pb, resulted in [Pb′]=7±2 pM and [Pb²⁺]=0·3 pM (62 pg l⁻¹). While less than 2·4% of the ambient Pb was ‘ in solution ’, it existed chiefly in the form of organic complexes with [PbL₁]=0·15 nM and [PbL₂]=0·03 nM. More significantly, there were large concentrations of unchelated Pb-binding ligands, (L_i′), available to buffer the free Pb²⁺concentration in the event of perturbations in dissolved Pb.     

Effects of metals and sediment particle size on the species composition of the epifauna of Pinna bicolor near a lead smelter,Spencer Gulf,South Australia

Pinna bicolor (Mollusca: Pelecypoda) were transplanted between four sites near a lead smelter. The species composition of their epifauna (sessile and mobile) was examined in relation to characteristics of both sediments and seston at the sites. Seventy-two taxa were distinguished in the epifaunal community. Substantial differences were found in the short-term sensitivity of some of the species to concentrations of Cd, Pb and Zn in sediments and to sediment particle size. The short-term sensitivity of many species to metals or sediment particle size explained their long-term distribution pattern. Twenty-three taxa were identified as significantly characterizing the faunal differences. Of these, eleven (four molluscs, four bryozoans, two barnacles and one ascidian) were affected by both sediment metal concentration and particle size, and eight (four molluscs, one bryozoan, one polychaete, one hydroid and one barnacle) were affected by metal contamination but not particle size. Of all fauna examined, the Bryozoa were the most metal-sensitive. Four species, Smittina raigii (Bryozoa), Galeolaria sp. 1 (Polychaeta), Epopella simplex (Cirripedia) and Monia ione (Pelecypoda) were identified by their short- and long-term sensitivity to metal contamination, and absence of sensitivity to sediment particle size, as suitable species for monitoring the effects of metal contamination on the epifauna. The implications of the results for toxicity-testing are discussed.     

氢化物原子荧光光度法测定地球化学样品中的微量铅

拟定了用铅空心阴极灯为激发光源,氢化物原子荧光光度法测定地球化学样品中微量铅的方法。在2％HCl-0.08％K_3[Fe(CN)_6]-2％KBH_4体系中,铅的测定灵敏度有明显地提高。该方法操作简便、快速、准确,检出限为8.89×10~(-9)g/ml,精密度为4.12％(n=11)。     

Zinc, Lead and Cadmium Content in Meadow Plants and Mosses Along the M3 Motorway (Hungary)

The heavy metal content was investigated in meadow plants located in a cultivated area and situated along the M3 motorway (Hungary). In addition to the meadow plants used as passive bioindicators, active bioindicators were also exposed to examine the accumulation rate of air pollutants. Tortula ruralis (Hedw.) Geartn. ssp. ruralis was applied to monitor the status of the environment. Meadow plant samples were collected at distances of 5, 10, 25, 50 and 100 m from the motorway and moss samples were exposed at the same distances. The zinc, lead and cadmium content of meadow plants and moss samples were analysed by ICP spectrophotometry. It was found that the zinc, lead and cadmium contents of the meadow plants decreased as the distance increased from the motorway. There was a significant difference even between values measured at the distances of 5 m and 10 m. The heavy metal contents in the moss samples exceeded those of the meadow plants. The heavy metal content in moss samples decreased with distance from the motorway. On comparing the data with Hungarian standards, it was found that measured values did not exceed the maximum allowed concentration levels.     

副高断裂前后四川盆地一次暴雨过程的比较分析

利用NCEP1°×1°6 h再分析资料,对副热带高压与西风槽典型环流形势配合下发生的一次四川区域性暴雨过程的不同阶段进行对比分析。结果表明,前期暴雨天气过程,其动力条件占到了主导地位,具有明显的经向垂直环流圈和垂直上升运动支,而在副高断裂后较强冷空气作用下,在副高边缘发生的区域性暴雨过程受西风带槽前的能量锋区影响,动力强迫作用和热力强迫作用激发的次级环流,进一步加强了四川盆地垂直运动的发展;冷空气作用前期的暴雨过程和冷空气进入后副高边缘发生的区域性暴雨过程中暴雨区域内的假相当位温均强于高层,大气处于对流性不稳定层结状态,对四川盆地暴雨的增强也起了不可忽视的作用,但由副高控制到副高逐渐断裂,湿位涡的斜压扰动是逐渐增强的过程,导致倾斜垂直涡度发展,激发更为强烈的上升运动;副高与西风槽环流形势相配合的暖区暴雨过程水汽主要来自中低层孟加拉湾;而副高断裂后发生在副高边缘的区域性暴雨过程,水汽主要来自850hPa层南海和孟加拉湾,从对流层中到低层,四川盆地东部恰恰是冷暖气流的交汇处,偏南气流将海上充沛的水汽输送到盆地东部,为暴雨的发生提供充足的水汽条件,并与对流层低层秦岭附近的东北冷气流交汇。