溶解气运移特征砂槽模型实验研究

借助于砂槽承压含水层模型 ,以氩溶解气为研究对象 ,模拟气体聚集或稀释的异常源产生后 ,其在含水层中的运移过程。实验包括三组 ,分别模拟在不同的气源气体流量、水头压力和承压荷载条件下氩溶解气的运移过程。在实验的基础上 ,分析研究氩溶解气的运移特征 (主要包括运移模式、运移速率和溶解气峰值含量 )与气源气体流量、水位和承压荷载压力的关系。结果表明氩溶解气在低流量的范围内呈现出与离子类似的弥散特征 ,与离子不同的是氩溶解气的运移明显地受到气源气体流量的影响。     

White mica 40Ar/39Ar age spectra and the timing of multiple episodes of high‐P metamorphic mineral growth in the Cycladic eclogite–blueschist belt,Syros, Aegean Sea,Greece

New geochronology from Syros in the Cycladic eclogite–blueschist belt, Aegean Sea, Greece, shows that ⁴⁰Ar/³⁹Ar geochronology consistently dates microstructural events in metamorphic rocks. We demonstrate that the age spectra depend on microstructure in a predictable and systematic way. Ages can be inferred by applying the method of asymptotes and limits to data from the step ‐ heating experiments. The results are consistent with previously published estimates for the timing of a sequence of distinct and discrete episodes of high ‐ P metamorphic mineral growth observed regionally across this belt. Arrhenius plots from these experiments imply that phengitic white mica is highly retentive of argon, and therefore (if these data can be extrapolated to the natural environment) the ages can be interpreted as recording the timing of episodic deformation and metamorphism. Porphyroblastic growth begins: (i) for omphacite – jadeite–eclogite facies parageneses at c. 53 Ma; and (ii) for garnet – glaucophane facies parageneses at c. 47 Ma. The Kini Shear Zone started as an extensional post ‐ epidote–albite‐transitional–blueschist facies shear zone that had completed operation by c. 31 Ma. The scatter in ages is due to the effect of deformation, recrystallization and multiple growth events in shear zones that continued operating for 3 – 6 million years from the start of each episode.     

A 40Ar/39Ar laser probe study of micas from the Sesia Zone, Italian Alps: implications for metamorphic and deformation histories

Two samples from the Eclogite Micaschist Complex (EMC) and the Seconda Zona Diorito–Kinzigitica (IIDK) of the Sesia Zone have been studied using a high-spatial resolution laser probe ⁴⁰Ar/³⁹Ar technique with the aim of investigating the complexities of argon behaviour in metamorphic rocks and comparing their thermal histories. Data from a single large phengite grain from the EMC show a range of ages from mid-Jurassic to Upper Cretaceous. These ‘apparent age’ variations are spatially related to both location within the grain and to intragrain microstructure. Modelling of the data shows that the profile formed by the diffusion of an excess argon component into the grain, parallel to the mica cleavage. Profile asymmetry is explained by temporal variations in microstructural development enabling excess argon to enter the grain at different times in different places. The temperatures of the initiation of deformation and the possible time-scales for the deformation can be calculated as a function of cooling rate. All estimates suggest deformation at greenschist facies, in accord with the observed retrograde mineral assemblage. Absolute temperature estimates for deformation vary by less than 22 °C for different cooling rates of 10 and 30 °C Ma^?1 but vary by 80 °C with different estimates of diffusion parameters. The duration of deformation was for at least 2 Ma at 10 °C Ma^?1 or 0.7 Ma at 30 °C Ma^?1. Biotites from the IIDK sample record a Permian to Upper Cretaceous age range that correlates with grain size, the smallest grain sizes yielding the youngest ages. This relationship is best explained by a partial resetting of biotites during an Alpine thermal event initiated not more than 70 Ma ago. Modelling of these data suggest that the sample never exceeded 300 °C during the Alpine. The profoundly different thermal histories of the two units—the EMC recrystallized at 550 °C whilst the IIDK remained below 300 °C—suggests that they may not have been juxtaposed until much later than the eclogite facies metamorphism.     

Occurrence and significance of blueschist in the southern Lachlan Orogen

Serpentinite/talc‐matrix mélanges, bearing blocks of blueschist metavolcanics, occur within the Heathcote and Governor Fault Zones of the southern Lachlan Orogen. In the Heathcote Fault Zone, serpentinite‐matrix mélange consists of blocks or small pods of boninite, andesite, ultramafic rocks, chert and volcanogenic sandstone variably metamorphosed to prehnite‐pumpellyite, greenschist, or greenschist to blueschist facies. In the Governor Fault Zone, blueschist metavolcanics occur as blocks within serpentinite/talc matrix that is interleaved with prehnite‐pumpellyite to greenschist facies, intermediate pressure slate and phyllite. Ar/Ar dating of white mica from slaty mud‐matrix (broken formation) indicates that the main fabric development occurred at 446 ± 2 Ma. U–Pb (SHRIMP) dating of titanite from blueschists in the Governor Fault Zone indicates that metamorphism occurred at approximately 450 Ma, close to the time of mélange formation. Previously published, Ar/Ar dating of white mica from phyllite and biotite from metadiorite in the Heathcote Fault Zone suggest that blueschist metamorphism occurred at a similar time. These ages are supported by field relationships. Illite crystallinity and b₀ data from white mica, and the preservation of blueschist blocks indicate that these fault zones maintained low temperatures both during and after intermediate‐ to high‐pressure metamorphism. Occurrences of blueschists in the Arthur Lineament of the Tyennan (Delamerian) Orogen in Tasmania, and in the New England Orogen, have different ages, and in conjunction with the occurrences described here, suggest that subduction‐accretion processes contributed significantly to the development of the Tasmanides from Cambrian through to Carboniferous times.     

Alice Springs age shear zones from the southeastern Reynolds Range,central Australia

The southeast Reynolds Range, central Australia, is cut by steep northwest‐trending shear zones that are up to hundreds of metres wide and several kilometres long. Amphibolite‐facies shear zones cut metapelites, while greenschist‐facies shear zones cut metagranites. Rb–Sr and ⁴⁰Ar–³⁹Ar data suggest that both sets of shear zones formed in the 400–300 Ma Alice Springs Orogeny, with the sheared granites yielding well‐constrained ⁴⁰Ar–³⁹Ar ages of ca 334 Ma. These data imply that the shear zones represent a distinct tectonic episode in this terrain, and were not formed during cooling from the ca 1.6 Ga regional metamorphism. A general correlation between regional metamorphic grade and the grade of Alice Springs structures implies a similar distribution of heat sources for the two events. This may be most consistent with both phases of metamorphism being caused by the burial of anomalously radiogenic heat‐producing granites. The sheared rocks commonly have undergone metasomatism implying that the shear zones were conduits of fluid flow during Alice Springs times.     

Lake Boga Granite,northwestern Victoria: mineralogy,geochemistry and geochronology

The Devonian Lake Boga Granite in northern Victoria, while almost entirely under thin Murray Basin cover, is one of the largest plutons in the western Lachlan Fold Belt. Its only exposure is a quarry penetrating the Cenozoic sediments. In the quarry, prominent pod pegmatites and miarolitic cavities suggest a high level of emplacement. The granite, a non-magnetic, fractionated S-type, contains a large range of accessory minerals, including primary uranium- and REE-bearing phosphates and oxides, and primary copper sulfides. Monazite-series minerals show an exceptionally wide range of compositions, from normal monazite-(Ce) through cheralite (Ca – Th-rich) to rare huttonitic monazite (Th-rich) and brabantite; U contents in monazite also vary widely (0 – 7.9 wt%). Primary low-Ca uraninites are well preserved and are unusual in having low Th/U and LREE. Late-stage cavity fluorapatite crystals up to several centimetres across show intricate elemental zoning patterns with extreme U gradients (<10 – 6900 ppm) in some crystals. New ⁴⁰Ar – ³⁹Ar ages for magmatic biotite, muscovite and K-rich feldspar average 365 ± 3 Ma, which approximates the emplacement age of the granite. This is supported by a 377 ± 12 Ma U – Th – Pb (CHIME) age for primary uraninite. New whole-rock geochemical data support earlier observations: the granite is strongly fractionated (SiO₂ 70.7 – 76.0 wt%; 4.2 – 0.6 wt% FeO_t) and peraluminous (ASI = 1.23 – 1.45), and has slightly elevated Na₂O and P₂O₅ (0.30 wt%) contents compared with other fractionated S-type granites from the Lachlan Fold Belt. Trace-element abundances are typical of fractionated granites, although U and Cu concentrations vary strongly and reach >60 and ≈1400 ppm, respectively. REE patterns also vary strongly, from LREE-enriched with moderate Eu depletion, to flat with strong Eu depletion. The flattest of the REE patterns, in samples with FeO_total < 1%, are characterised by M-type tetrad effects. These and other samples also show low (subcrustal average) and variable Zr/Hf (35 – 16) and Nb/Ta (8 – 4) ratios; these and other unusual elemental fractionations are related to changes in elemental partitioning during the late magmatic stage, when felsic peraluminous magma and high-temperature magmatic fluid coexisted.     

中印度洋脊Edmond热液区成矿流体属性与来源:来自流体包裹体和He-Ar同位素的证据

To understand the source and nature of the ore-forming fluids of the Edmond hydrothermal field on the Central Indian Ridge, we studied the He-Ar isotope composition and fluid inclusions of the hydrothermal precipitates.Our results show that the sulfide samples contain noble gases He, Ne, Kr, and Xe with their abundances in between those of air-saturated water(ASW) and mid-ocean ridge basalt(MORB). The ~3He/~4He ratio varies from1.3 to 8.7 R_a(n=10, average: 5.1 R_a), whereas the ~(40)Ar/~(36) Ar ratio is from 285.3 to 314.7(n=10, average: 294.8). These results suggest that the He was derived from a mixture of MORB with variable amounts of seawater, but the Ar in the ore-forming fluids trapped in the sulfides is predominantly derived from seawater. The fluid inclusions of barite have a wide range of homogenization temperatures and salinities varying from 163°C to 260°C and 2.6 wt%to 8.5 wt% Na Cl equiv., respectively. It is suggested that the ore-forming fluids were produced by phase separation, which agreed with the present-day vent fluid study.     

A 3100-year history of argon isotopic and compositional variation at El Chichón volcano

El Chichón volcano has produced at least 11 eruptive events in the past 8000 years, all of which display a relatively constant trachyandesitic composition. The constancy of the eruptive products attests to the tapping of a long-lived magma chamber and suggests a system held in steady state between the influx of basaltic magma and differentiation of resident magma. We have sampled eruptive products from eight of these events, subjecting their dominant phenocryst phases (plagioclase and hornblende) to argon isotopic analysis in order to investigate the dynamics of a steady state magmatic system. Plagioclase from the older eruptions, 1500 yr BP, 1600 yr BP, 2000 yr BP and 3100 yr BP, display variable enrichment of ⁴⁰Ar (excess argon), whereas hornblende from the same eruptions shows little or no enrichment. In contrast, both plagioclase and hornblende phenocrysts from the younger eruptions in 1982, 550 yr BP, 900 yr BP and 1250 yr BP have argon isotopic ratios near-atmospheric values. Isochron analysis of these mineral phases rules out xenocrystic contamination as the source of excess argon, while mafic enclaves and isotopic and compositional zoning evidence frequent recharge events, suggesting the source of this argon is most likely the same as the source of this basaltic magma; correlation with Cl points to melt/vapor inclusions as the primary host for Ar within the phenocrysts. Argon isotopic variations point to a disturbance of the system between 1500 yr BP and 1250 yr BP, while compositional evidence for a major mafic input is present in the 900 yr BP eruption, indicating a complex relationship between recharge and isotopic signature of eruptive products. The amount of excess argon within a plagioclase phenocryst are a function of variations in melt and vapor inclusion abundance, time elapsed between melt/vapor inclusion entrapment and eruption, variations in Ar abundance in melt (itself a function of vapor exsolution timing) and time variations in Ar isotopic composition of the melt; subdued behavior of hornblende is due to slower diffusion and minimal inclusions.     

Timing of gold mineralisation in the Ballarat goldfields,central Victoria: Constraints from 40Ar/39Ar results

⁴⁰Ar/³⁹Ar data for muscovite separates and hydrothermally altered whole‐rock samples from the Ballarat West and the Ballarat East goldfields indicate that mesothermal gold mineralisation at Ballarat occurred during several episodic pulses, ranging in age from the Late Ordovician to the Early Devonian. Initial formation of auriferous structures in the Ballarat goldfields coincided with folding and thrusting associated with the development of the western Lachlan Fold Belt between 460 and 440 Ma. Subsequent fault reactivation and magmatism resulted in remobilisation and additional mineralisation between 410 and 380 Ma, and around 370 Ma. The results presented herein are in agreement with findings for other major gold deposits in central Victoria and further constrain the history of deformation, metamorphism and mineralisation in the western subprovince of the Lachlan Fold Belt.