Cretaceous isochron ages from K–Ar and Ar / Ar dating of eclogitic rocks in the Tso Morari Complex, western Himalaya, India

The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (X_Jd = 0.48).

Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial ⁴⁰Ar / ³⁶Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic ⁴⁰Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions.     

Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.     

Elastic properties of granulite facies rocks of Mahabalipuram, Tamil Nadu, India

Compressional and shear wave velocities and attenuation measurements have been carried out in some of the borehole samples of acidic, basic and intermediate granulites of Mahabalipuram, Tamil Nadu, India. The results have been obtained at ambient conditions using ‘time-of-flight’ pulse transmission technique at 1.0 MHz frequency. The results show linear relationships between velocity and density, and velocity and attenuation properties of the rocks. The acidic granulites show lower velocities and higher attenuation than the intermediate and basic granulites. The average values of the Poisson’s ratio of acidic, intermediate and basic granulites have been found to be 0.210, 0.241 and 0.279 respectively. The variations in velocities and attenuation in these low porosity crystalline rocks are found to be strongly influenced by their mineral composition. The laboratory velocity data (extrapolated to high pressure) of the present study and the published field velocity data from deep seismic sounding studies indicate that these granulite facies rocks may belong to mid-crustal depths only.     

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.     

Effects of fracture lineaments and in-situ rock stresses on groundwater flow in hard rocks: a case study from Sunnfjord, western Norway

Systematic field mapping of fracture lineaments observed on aerial photographs shows that almost all of these structures are positively correlated with zones of high macroscopic and mesoscopic fracture frequencies compared with the surroundings. The lineaments are subdivided into zones with different characteristics: (1) a central zone with fault rocks, high fracture frequency and connectivity but commonly with mineral sealed fractures, and (2) a damage zone divided into a proximal zone with a high fracture frequency of lineament parallel, non-mineralized and interconnected fractures, grading into a distal zone with lower fracture frequencies and which is transitional to the surrounding areas with general background fracturing. To examine the possible relations between lineament architecture and in-situ rock stress on groundwater flow, the geological fieldwork was followed up by in-situ stress measurements and test boreholes at selected sites. Geophysical well logging added valuable information about fracture distribution and fracture flow at depths. Based on the studies of in-situ stresses as well as the lineaments and associated fracture systems presented above, two working hypotheses for groundwater flow were formulated: (i) In areas with a general background fracturing and in the distal zone of lineaments, groundwater flow will mainly occur along fractures parallel with the largest in-situ rock stress, unless fractures are critically loaded or reactivated as shear fractures at angles around 30° to σ_H; (ii) In the influence area of lineaments, the largest potential for groundwater abstraction is in the proximal zone, where there is a high fracture frequency and connectivity with negligible fracture fillings. The testing of the two hypotheses does not give a clear and unequivocal answer in support of the two assumptions about groundwater flow in the study area. But most of the observed data are in agreement with the predictions from the models, and can be explained by the action of the present stress field on pre-existing fractures.     

Petrogenesis and tectonic setting of Cadomian felsic igneous rocks, Sandıklı area of the western Taurides, Turkey

In the Sandıklı (Afyon) region, western Taurides, the Late Proterozoic rocks of the Sandıklı basement complex are composed of low-grade meta-sedimentary rocks (Güvercinoluk Formation) intruded by felsic rocks (Kestel Cayı Porphyroid Suite, KCPS). The KCPS is a deformed and highly sheared, dome-shaped rhyolitic body with a granitic core. Quartz porphyry dikes intrude both the slightly metamorphic igneous and the sedimentary rocks of the basement complex. Both the quartz porphyries and rhyolites were converted into mylonites with relict igneous textures. Geochemical data show that these felsic igneous rocks are subalkaline and mainly granitic in composition with SiO₂ >72 wt% and Al₂O₃ >11.5 wt%. The chondrite-normalized incompatible trace element patterns are characterized by distinct negative Rb, Nb, Sr, P, Ti, and Eu with enrichment in Th, U, La, Ce, Nd, Sm, and Zr. The REE patterns of the felsic rocks indicate a strong enrichment in LREE but display slightly flat HREE patterns. According to geochemical characteristics and petrogenetic modeling, extrusive and intrusive rocks of the KCPS were probably derived from an upper continental crustal source (partial melting of granites/felsic rocks) by 18–20% fractional melting plus 18–20% Rayleigh fractional crystallization, which seems to be the most effective igneous process during the crystallization of the KCPS. Single zircon age data from the granitoids and fossils from the disconformably overlying sedimentary successions indicate that the metamorphism and the igneous event in the Taurides are related to the Cadomian orogeny. Based on the geological, geochemical and petrogenetic correlation of the post-collisional granitoids it is further suggested that the Tauride belt in western central Turkey was in a similar tectonic setting to the Gondwanan terranes in North Africa (Younger Granitoids) and southern Europe (Spain, France, Bohemia, Brno Massifs) during the Late Cadomian period.     

Investigating the scale of structural controls on chlorinated hydrocarbon distributions in the fractured-porous unsaturated zone of a sandstone aquifer in the UK

Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL).