环氧树脂/金云母纳米复合材料的制备与表征

以环氧树脂为基体,二甲基苄胺为固化剂,经结构修饰和有机改性的金云母为增强相,制备了环氧树脂/金云母纳米复合材料,测试了环氧树脂/金云母纳米复合材料的结构、形貌、力学和电学性能。研究了金云母添加量、混合时间以及固化剂添加方式等因素对金云母在环氧树脂中剥离程度的影响。力学性能测试表明,当金云母含量为1%时复合材料的性能最好,与纯树脂相比,拉伸强度提高了32.33%,弯曲强度提高了53.77%,冲击强度提高了127%。电学性能测试表明,当金云母含量为1%时,复合材料体积电导率和表面电导率分别比纯树脂提高了2个和4个数量级。     

Mica Types as Indication of Magma Nature, Central Anatolia, Turkey

This study focuses on the nature of giant micas occurring at the contact between the ?zvatan (foid-bearing) syenites and the metamorphic basement in Central Anatolia. The studied micas are dark greenish-black in color and crystallized within vein shape like bodies as a narrow lens. The origin and processes responsible for the formation of these independent crystals of the giant micas were investigated by mineralogical, petrographical and geochemical analyses with the use of Confocal Raman Spectroscopy (CRS), Fourier Transform Infrared (FTIR) Spectroscopy, X-Ray Diffraction (XRD), Polarized Energy Dispersive X-Ray Fluorescence Spectrometer (PED-XRF) and Electron Probe Micro Analysis (EPMA). According to XRD, CRS, FTIR and EPMA data, the giant micas are phlogopite. EPMA results reveal that studied mica minerals represent the products of re-equilibrated primary mica characterized by high MgO and FeO and low Al2O3 and TiO2 contents. The trace element concentrations of the giant micas display similar patterns with the upper crust. The giant micas are crystallized within small cubicles from an alkaline magma and their composition is possibly modified by a mixing event between the crust- and mantle-derived magmas and contaminated at varying extent by the basement metamorphic rocks.     

新疆东天山天宇铜镍硫化物矿床金云母Ar-Ar年代学及其地质意义

查明矿床形成后的变化保存情况对提高成矿预测能力十分重要。文章通过金云母的矿物化学和ArAr年代学研究来探析天宇铜镍硫化物矿床形成后的变化保存问题。研究发现,该矿床的云母有2种产状：一种呈他形片状分布在橄榄石与辉石颗粒之间;另一种是产在块状硫化物矿体与围岩的接触面上,呈叶片状集合体。2种云母种属为铁质黑云母、镁质黑云母和金云母。前者与角闪石近同期结晶,结晶后受到了晚期硫化物熔体的影响,后者为炽热的硫化物矿浆侵位时与围岩相互作用新生成的云母。云母结晶温度为609.6~646.2℃,2个金云母样品的Ar-Ar坪年龄分别为（250.4±1.5） Ma和（247.7±1.5） Ma。该2个坪年龄比岩体的锆石U-Pb年龄晚了约30 Ma,文章推测是由于区内晚二叠世—早三叠世的走滑断裂活动使该Ar-Ar年龄发生了重置。     

Compositional variation of phlogopite in a marble sample: implications for geological thermobarometry

Abstract The textural and compositional features of phlogopites in a contact-metamorphic dolomite marble inclusion in the Bergell intrusion (central Alps) and in a metasomatic reaction vein cutting through this marble suggest different origins for vein phlogopites:
(a) High-Al vein phlogopite represents former marble phlogopite which has been compositionally modified by reaction with the vein forming fluid.
(b) Low-Al vein phlogopite represents phlogopite precipitated from the vein forming fluid.
As both types of vein phlogopite were in contact with the same vein forming fluid at the same time, low-Al phlogopite most likely represents an equilibrium phlogopite composition, whereas high-Al phlogopite does not. High-Al vein phlogopite retained its Al-content from the contact-metamorphic marble parent phlogopite and only underwent Fe-Mg exchange with the metasomatic fluid.
All the vein phlogopites studied are strongly enriched in Fe relative to marble phlogopite. The data may suggest in general that phlogopite Al/Si ratios may be retained from the conditions under which the phlogopites first formed, whereas the Mg/Fe-ratios may be substantially modified by exchange with other ferromagnesian solid phases and/or a metamorphic fluid at later stages in their metamorphic history. This may have significant effects on calculated pressures and temperatures from thermobarometers involving biotite.     

太行山中段新生代玄武岩中高镁橄榄石捕虏晶：残留古老岩石圈地幔样品

太行山中段新生代玄武岩(7.8Ma)中发现具有明显环带结构的高Mg^#橄榄石。其中心部分明显富MgO和NiO，边缘FeO、MnO、CaO和Al2O3的含量较高。高Mg^#橄榄石中心部分(Mg^#=89.892.3)与华北新生代玄武岩所携带的橄榄岩捕虏体中高Mg^#橄榄石的组成接近，中间部分(Mg^#=84.5～89.7)略高于寄主玄武岩中斑晶橄榄石中心部分的组成(Mg^#=77.1～81.7)，而高Mg^#橄榄石的边缘部分(Mg^#=55.6～73.6)和寄主玄武岩斑晶橄榄石边缘的组成(Mg^#=55.6～73.6)相一致，都接近于寄主玄武岩基质中橄榄石的组成(Mg^#=54.8～66.1)。橄榄石的化学成分环带及其所具有的熔蚀结构说明它是地幔橄榄岩的解体矿物，其大颗粒的中心部分能够代表地幔橄榄岩的组成，表明在太行山中段新生代时期仍存在古老的岩石圈地幔。对比研究发现，华北地区岩石圈减薄存在时空上的差异。     

湖南桃源理公港地区含金刚石沉凝灰岩的发现及其找矿意义

湖南桃源理公港地区白垩纪红盆内的灰绿色和紫红色沉积夹层曾选获过金刚石。以灰绿色岩石为研究对象,通过薄片鉴定和电子探针分析来确定岩石名称和岩石中石榴石和云母的属性。显微镜下,灰绿色岩石呈凝灰结构,由约45%的晶屑、35%的岩屑和20%的玻屑组成,为较典型的沉凝灰岩,并非前人所述的金伯利岩。沉凝灰岩中的石榴石和云母分别为G10型镁铝榴石和金云母,镁铝榴石和金云母的成分与辽宁、山东及南非典型岩管含金刚石金伯利岩中的镁铝榴石及金云母的成分基本一致,暗示其来源于含金刚石的金伯利岩。沉凝灰岩的特征表明,其来源地不会太远,这为在附近找寻火山机构奠定了基础; 金伯利质岩屑、G10型镁铝榴石和金云母的发现,为在周边寻找原生金伯利岩提供了重要信息。     

湖南芙蓉锡矿床40Ar/39Ar 同位素年龄及地质意义

文章以金云母、角闪石和白云母为测试对象,利用40Ar/39Ar同位素定年的方法,精确厘定了芙蓉超大型锡矿床的形成时间。研究结果表明,白腊水矿区3个金云母样品的40Ar/39Ar坪年龄分别为(150.6±1.0)Ma、(157.3±1.0)Ma和(154.7±1.1)Ma;热液成因角闪石的坪年龄为(156.9±1.1)Ma。淘锡窝矿区云英岩中2个白云母样品的40Ar/39Ar坪年龄为(159.9±0.5)Ma和(154.8±0.6)Ma;因此芙蓉矿床的形成时间为151～160Ma,这与骑田岭主体花岗岩的侵入时间(151～162Ma)相吻合。湘南地区的柿竹园超大型W-Sn-Mo-Bi-F矿床、新田岭大型W矿床、瑶岗仙W矿床和黄沙坪Pb-Zn多金属矿床的形成时间亦集中在150～160Ma之间,因此,湘南有色金属矿化集中区可能主要集中在150～160Ma发生成矿,这种大规模成矿作用可能与中生代华南岩石圈的拉张、伸展作用密切相关。     

大兴安岭北部诺敏河地幔金云母及钾质地幔熔体研究

在大兴安岭北部诺敏河第四纪钾质火山岩携带的地幔捕虏体中,发现少量金云母矿物和富钾地幔熔体。金云母颗粒大小1~5mm,呈网脉状充填在橄榄石和辉石、石榴子石等地幔矿物间隙。电子探针研究表明地幔橄榄石、单斜辉石、斜方辉石和石榴石等矿物几乎不含钾质成分(K2O0.01%),而金云母矿物成分具有高钾(K2O~10%)、高钛(Ti O25.41%~7.74%)的特点,暗示区域地幔钾的富集与金云母矿物有密切关系。地幔金云母的成因往往与富钾地幔流体/熔体的交代作用有关,在地幔捕虏体矿物反应边的硅酸盐熔体(囊体)中,发现富硅、富钾的熔体,K2O 4%~8%。结合前人地幔熔体研究,认为区域地幔经历了多期、不同成分地幔熔体的富集作用,其中富钾熔体对地幔钾质成分的富集起到重要作用。诺敏钾质火山正是富钾地幔部分熔融的产物,钾质熔体成分的来源可能与俯冲再循环的壳源物质有关。