一种新的流动注射在线共沉淀技术的研究及应用

建立了应用流动注射在线共沉淀分离富集火焰原子吸收法测定天然水样中痕量铬的价态分析方法。利用铬（Ⅲ）在碱性条件下与氢氧化镧形成共沉淀而与共存离子分离并得到富集，沉淀不需过滤，直接用稀盐酸从编织反应器（ＫＲ）中溶解并洗脱下来，用原子吸收测定。本体系的浓集倍率２２，检出限（３σ）０．８μｇ／Ｌ，相对标准偏差（ｎ＝１１）２．７２％，用水标样考察，分析结果与推荐值相符。该方法成功地用于天然水中铬的快速测定。     

陆地水体参数的卫星遥感反演研究进展

以江河、湖泊与湿地等形式存在的陆地水体对气候变化和人类生产生活有着重要影响,准确掌握陆地水体参数的变化对全面理解地球水循环及有效管理水资源等具有重大意义,卫星遥感技术的迅速发展为陆地水体的动态监测带来广阔前景.围绕陆地水体的重要物理参数,回顾了基于卫星遥感来提取水域面积的光学遥感法、雷达遥感法和水域面积-水位关系法,获...     

High resolution facies architecture and digital outcrop modeling of the Sandakan formation sandstone reservoir,Borneo:Implications for reservoir characterization and flow simulation

Advances in photogrammetry have eased the acquisition of high-resolution digital information from outcrops, enabling faster, non-destructive data capturing and improved reservoir modeling. Geocellular models for flow dynamics with in the virtual outcrop in siliciclastic deposits at different sets of sandstone facies architecture remain, however, a challenge. Digital maps of bedding, lithological contrast, spatial-temporal variations of bedding and permeability characteristics make it more easy to understand flow tortuosity in a particular architecture. An ability to precisely model these properties can improve reservoir characterization and flow modeling at different scales. Here we demonstrate the construction of realistic 2 D sandstone facies based models for a pragmatic simulation of flow dynamics using a combination of digital point clouds dataset acquired from LiDAR and field investigation of the Sandakan Formation, Sabah, Borneo.Additionally, we present methods for enhancing the accuracy of outcrop digital datasets for producing high resolution flow simulation. A well-exposed outcrop from the Sandakan Formation, Sabah, northwest Borneo having a lateral extent of 750 m was chosen in order to implement our research approach. Sandstone facies and its connectivity are well constrained by outcrop observations, data from air-permeability measurements, bilinear interpolation of permeability, grid construction and water vector analysis for flow dynamics.These proportions were then enumerated in terms of static digital outcrop model(DOM) and facies model based on sandstone facies bedding characteristics. Flow simulation of water vector analysis through each of the four sandstone facies types show persistent spatial correlation of permeability that align with either cross-bedded orientation or straight with more dispersion high quality sandstone(porosity 21.25%-41.2%and permeability 1265.20-5986.25 mD) and moderate quality sandstone(porosity 10.44%-28.75% and permeability 21.44-1023.33 mD). Whereas, in more heterolithic sandstone(wavy-to flaser-bedded and bioturbated sandstone), lateral variations in permeability show spatially non-correlated patterns over centimeters to tens of meters with mostly of low quality sandstone(porosity 3.4%-12.31% and permeability < 1 mD to 3.21 mD). These variations reflect the lateral juxtaposition in flow dynamics. It has also been resulted that the vertical connectivity and heterogeneities in terms of flow are mostly pragmatic due to the interconnected sandstone rather than the quality of sandstone.     

Electrical analogy for modelling thermal regime and moisture distribution in sandy soils

The soil mass is subjected to temperature variation due to several human activities (viz. tanks storing heated fluids, buried cables and pipelines, air-conditioning ducts, disposal of nuclear and thermal power plant wastes etc.), which result in heat-induced migration of the moisture in it. Though several studies have been conducted in the past to investigate the mechanism of heat migration through the soil mass, a methodology for ‘real-time measurement of the variations in temperature, flux and moving moisture front, in tandem, with respect to space' has rarely been attempted. In this context, extensive laboratory investigations were conducted to measure real-time flux and temperature variations in the sandy soils, and the validation of results has been done by employing an equivalent electrical circuit programme, LTspice. Subsequently, a mathematical model PHITMDS (i.e. Prediction of Heat-Induced Temperature and Moisture Distribution in Soil) has been developed and its utility and efficacy, for predicting the depth-wise temperature and heat-induced moisture migration, due to evaporation, in terms of position of moving moisture front in the sandy soil has been critically discussed and demonstrated.     

大地热流对中国西部环境与生态演变的影响及其研究意义

中国西部地区生态环境的优劣与大地热流的高低有良好的对应关系。大地热流较高的西南地区生态环境优良,孕育了我国最好的生物多样性;而大地热流较低的西北地区环境恶劣,生态脆弱,荒漠化严重。大地热流的脉动影响区域大气系统下垫面的热力背景和气流运动,从而影响降水的分布和区域气候的干湿程度;大地热流的高低决定了一个地区地表生态系统能量供给的下限,是生态系统演变过程中一个重要的物种限制因子,制约了一些地区生态系统物种的多样性,进而影响到区域生态系统的稳健性。对大地热流影响生态系统发育和演变机理的研究将为人类科学干预地表生态系统的演化、恢复与重建退化生态系统提供科学依据与技术方案。提出了西部生态环境整治的一些新的思路。     

云南地热资源及其开发前景

云南地热异常多且显著。滇西高温水热活动区是藏滇水热带的南延，滇东断陷盆地中低温水热活动区的形成得益于独特的地质结构，滇西、滇南花岗岩地热系统则主要吸收地层中K^40同位索放射热而成。开发前景极为广阔。     

A hybrid discrete-continuum approach to model hydro-mechanical behaviour of jointed rocks

A hybrid discrete-continuum approach has been presented in this paper to simulate water flow in the near and far fields of deformable fractured rocks. In the near field, the discrete model is used; while in the far field, the equivalent continuum model is employed. The discrete element method (with the static relaxation algorithm) is used in the near field and the boundary integral equation method in the far field. Along the interface of these two domains, both mechanical and hydraulic compatibility conditions are satisfied. Fully coupled hydro-mechanical analysis can be conducted in the combined near and far fields. Application to a dam foundation problem has demonstrated the capability of the developed approach.     

江西省大地热流与铀矿关系的初步研究

本文根据江西省大地构造、铀矿分布和大地热流实测资料,证明大地热流异常和铀矿均受深大断裂和深部构造变异带的控制,铀矿化能在一定程度上引起热流异常,并据此初步探讨了根据大地热流异常寻找铀矿床的可能性。     

北京平原区水源热泵应用适宜区划分

北京市水源热泵的应用,宏观上未充分考虑地下水水源地的分布,微观上未注重应用场地的水文地质条件,地下水回灌率低造成了水资源浪费。本文针对北京平原区的水文地质条件,以浅层含水层导水系数、有效导水系数、地下水中的铁和总硬度为评价因子,以水源地保护区及补给区、地面沉降中心区为约束因子,利用叠加分析技术,将平原区分为适宜发展区、较适宜发展区、限制发展区和禁止发展区,为水源热泵的理性推广提供了技术参考。     

酉阳河流域典型年汛期的基流分割研究

基流分割是水文学研究中的重难点问题之一,目前基流分割也存在许多方法.基于酉阳河典型年汛期实测日平均流量资料,分别采用Chapman-Maxwell改进方程数字滤波法一次滤波(参数N=1)以及二次滤波(参数N=2)、BFI(f)法、HYSEP固定步长法、HYSEP滑动步长法、HYSEP局部最小值法进行基流分割并对其结果进...