阿尔泰喀纳斯早泥盆纪钾质富镁英安岩：俯冲沉积物熔体交代

阿尔泰造山带喀纳斯地区出露一套钾质富镁英安岩,锆石U Pb定年显示其形成于早泥盆世（411±4 Ma）。该套英安岩富SiO2（6471～6777 wt％）,MgO（328～353 wt％）和K2O（212～275 wt％）,贫Na2O（170～185 wt％）,K2O/Na2O比值介于（120～153）,具较高的Al2O3（1412～1533 wt％）和较低的CaO（112～128 wt％）,ASI指数>18,显示过铝质钙碱性岩浆系列特征,明显不同于初始的高镁安山质岩浆。样品具有中等的Cr（134×10-6～153×10-6）、Co（1747×10-6～1865×10-6）、Ni（71.64×10-6～80.76×10-6）含量,富集大离子亲石元素Rb、K和高场强元素U、Th、Pb及LREE,发育Sr、Ba及“TNT”（Ta、Nb、Ti）负异常,显示俯冲带岩浆岩地球化学特征。其高的Mg#（5171～5247）和低的εNd(t)值（-46～-42）说明该套火山岩可能来自遭受强烈交代作用的地幔楔部分熔融。样品具有较高的Ba/La、Pb/La比值和较低的Th/Yb、Nb/Y比值,显示地幔交代作用以俯冲沉积物熔体的交代作用为主。以上地球化学特征说明,喀纳斯钾质富镁英安岩可能主要是受俯冲沉积物熔体交代的上覆地幔橄榄岩部分熔融的产物,阿尔泰泥盆纪处于俯冲作用相关的活动大陆边缘构造环境。此外,该套火山岩的形成时代制约了其下覆的哈巴河群沉积上限,显示哈巴河群沉积于早泥盆世之前。     

西天山玉希莫勒盖达坂石英闪长岩的微量元素地球化学及同位素年代学研究

玉希莫勒盖达坂石英闪长岩的主量元素组成相对稳定,SiO2、TiO2、Al2O3、Fe2O3T、MgO、CaO、Na2O和K2O的含量分别为57.08%～59.95%、0.70%～0.85%、16.34%～16.81%、6.73%～8.51%、2.82%～3.55%、5.72%～6.91%、3.22%～3.90%和1.44%～1.96%。该类岩的CA/TH指数在1.2左右变化,应属钙碱性系列岩石。主量元素和微量元素地球化学特征显示,玉希莫勒盖达坂石英闪长岩与区域内的大哈拉军山组钙碱性玄武安山岩为同源岩浆岩,它们是富集的尖晶石二辉橄榄岩部分熔融的产物,原始地幔楔的富集受俯冲板块脱水形成流体控制,这种源区富集交代过程导致玉希莫勒盖石英闪长岩具有明显的陆壳混染特征。玉希莫勒盖石英闪长岩明显亏损Nb-Ta、Zr-Hf、Ti等高场强元素,同时富集Pb,显示出与板块俯冲作用有关造山带岩浆岩的特征,形成于活动陆缘岛弧。与大哈拉军山组高钾系列火山熔岩形成于板片撕裂诱发的伸展构造环境不同,石英闪长岩形成于挤压的构造环境。单颗粒锆石U-Pb定年结果显示,石英闪长岩的形成年龄为309.9±2.7Ma,暗示阿吾拉勒东段大哈拉军山组火山岩的形成时代为晚石炭世。     

Geochemical and geochronological constraints on the origin and emplacement of the Shimo-ondori diorites in Shikoku,Southwest Japan

In this study, the LA-ICP-MS zircon U–Pb dating of the Shimo-ondori diorites in the Shimanto accretionary complex of SW Japan provides ~130 Ma, representing the timing of their crystallization ages. Combined with the geological occurrence, that age clearly indicates that the diorites occur as blocks, not as intrusive rocks as suggested by previous studies. Moreover, the ages of the Shimo-ondori diorites are suggesstive that they could be influential for the estimate of the early-Cretaceous tectonic evolution for the eastern Asian margin. Their whole-rock chemical compositions show high MgO, Ni and Cr contents, and low total FeO/MgO ratios, indicating that they were crystallized from high magnesian andesite (HMA) magmas. Moreover, their TiO₂ and REE compositions suggest that they were formed by the same processes as the sanukites. And, the zircon Hf isotopic ratios (ε_Hf [~130 Ma] = +9.9 − +17.5), which is close to or slightly lower than that of the ~130 Ma depleted mantle, suggest that the wedge-mantle materials were predominantly involved in the formation of the dioritic magmas. Their geochronological and geochemical similarities of the Shimo-ondori diorites with the early Cretaceous adakites and HMAs in the eastern Asian margin suggest that they might have been formed possibly by the same slab rollback of the Izanagi plate at the early Cretaceous. After the crystallization of the Shimo-ondori diorites, they were delivered and deposited as blocks in a trench site with the surrounding sedimentary rocks of the Shimanto accretionary complex.     

青海玉树赵卡隆铁铜多金属矿床地质特征及成因探讨

赵卡隆铁铜多金属矿床产于三叠纪末期江达弧后裂谷热水沉积盆地中,具有铁、铜、金、铅锌等多金属矿化.矿体赋存于三叠系巴塘群上部碎屑岩组上岩性段地层中,严格受地层和岩性控制.各矿(体)群根据矿体分布部位不同划分为若干条矿体.火山喷发活动(安山岩)为成矿提供了物质来源和热源,同期火山岩具有富铝钠质低钾质特征,属安山岩类-拉斑玄...     

Eclogite-melt/peridotite reaction: Experimental constrains on the destruction mechanism of the North China Craton

To study the mechanism of melt-peridotite reaction pertinent to the destruction of the North China Craton (NCC) lithosphere, a series of experiments were performed at a pressure of 2.0 GPa and temperatures from 1250 to 1400°C using Bixiling eclogite and Damaping peridotite as starting materials. The experimental results show that the reaction between eclogite melt and peridotite causes dissolution of olivine and orthopyroxene and precipitation of clinopyroxene in the melt. The experimental run products, cha...     

埃达克岩的原义、特征与成因

论述了埃达克岩的原义与综合特征 ,并针对其与太古宙TTG之间的区别和联系及今后研究埃达克岩的建议提出了自己的见解。埃达克岩 (adakite)的原义是指一类具有镁铁质斑晶的隐晶质火山岩 ,属于岛弧型岩浆钙碱性岩系 ,一般形成于年轻的 (<2 5Ma)、地热高的岛弧环境 ,是俯冲板块和上覆地幔相互作用产生的杂化熔液通过结晶分异形成的。综合总结埃达克岩 (原义 )的地球化学特征如下 :(1)原生标志 ,高Mg# 、低FeO /MgO、高Cr及Ni;(2 )微量元素标志 ,高LILE、高LREE、低HREE、低HFSE以及高分异的REE型式等。对实验岩石学研究资料的总结可知杂化 (hybridized)熔液是由小数量的板块熔液与地幔楔反应经交代作用、同化作用形成的 ,可分异直至出现酸性岩浆 ,这一过程称为“地幔同化及分离结晶作用 (mantle AFC)”。在橄榄岩的同化作用中 ,原有熔液Mg# 迅速上升 ,并在熔液成分加多后 ,向高Mg# 区迅速发展。在近代一些埃达克岩及相关岩石研究中 ,部分学者认为太古宙TTG与新生代板块 (榴辉岩 )重熔的TTD岩系类似。同时 ,亦有学者认为太古宙“绿岩带”中与TTG有关的深成岩系是一类Mg质花岗闪长岩Mg质二长闪长岩 ,成因与Sanukite相似 (太古宙sanuk itoid岩系 ) ,相当于富集橄榄岩重熔形成的岩系。这些研究重新引发了太古宙     

内蒙古林西早中生代O型高镁埃达克质安山岩的发现及其意义

对内蒙古林西地区火山岩样品的地球化学研究表明,其具有大洋型(O型)高镁埃达克质安山岩的地球化学特征[w(SiO2)=57.89%～63.97%、w(Al2O3)=15.39%～16.17%、w(Na2O)/w(K2O)=1.5～2.2(除一个为0.9)、A/CNK=0.83～0.97、Mg#=49～64、w(Cr)=91～209μg/g、w(Ni)=52.2～111.4μg/g、w(Sr)=551～1018μg/g、w(Yb)=1.18～1.71μg/g、w(Y)=12.6～17.7μg/g、δ(Eu)=0.86～0.94]。利用LA-ICP-MS对其锆石进行了U-Pb定年,得到206Pb/238U加权平均年龄为(244±2)Ma(MSWD=0.36)。此时,区域内古亚洲洋已闭合,综合地球化学特征和区域地质环境说明,林西高镁埃达克质安山岩是由残余洋壳部分熔融并随后与地幔橄榄岩相互作用形成的。内蒙古林西早中生代高镁埃达克质安山岩的产出表明,洋壳来源的埃达克岩(O型埃达克岩)不仅可以随俯冲同时产生,而且也可以在非俯冲环境下由保存在古俯冲带地幔中的残余洋壳部分熔融产生。     

辽西黄半吉沟早白垩世义县组高镁安山岩的成因

利用橄榄石和熔体包裹体,结合全岩的方法对辽西地区早白垩世义县组黄半吉沟火山岩的成因进行了研究。黄半吉沟火山岩SiO_2=53.41%~53.74%,MgO=8.15%~8.23%,Mg#=~70(Mg#=mol Mg/(Mg+Fe2+)),为高镁安山岩;全岩在TAS图解上,落在玄武安山岩范围内,属于亚碱性系列;它们具有较高Ni(119×10-6~125×10-6)和高Cr(467×10-6~521×10-6),显示幔源岩浆特征;在微量元素组成上,黄半吉沟高镁安山岩Sr=920×10-6~930×10-6,Y=16.1×10-6~16.4×10-6,Sr/Y=57~58;在微量元素原始地幔标准化蛛网图上,黄半吉沟高镁安山岩显示轻重稀土分异,明显的Nb-Ta-Ti和弱的Zr-Hf负异常,Ba、Sr和Pb正异常,这些特征与大陆下地壳非常相似。熔体包裹体MgO为6.5%~9.7%,SiO_2为51%~53%,不符合典型高镁安山岩的定义;在TAS图解上它们落在玄武粗安岩内,属于碱性系列;MgO与其它主量元素成分呈明显或者弱的负相关关系,说明它们的成分主要受控于橄榄石结晶分离过程。黄半吉沟高镁安山岩的橄榄石Fo值为75~91;CaO含量为0.10%~0.18%,NiO为0.05%~0.41%,Fe/Mn比值为60~80。黄半吉沟高镁安山岩的全岩和熔体包裹体成分存在显著差异,如熔体包裹体具有更高的Al2O3和更低的SiO_2。结合全岩微量元素特征,我们认为黄半吉沟高镁安山岩在地壳深度的岩浆演化过程中加入了来自下地壳的酸性熔体,是壳幔相互作用的结果。全岩较低Ni高Mg#,熔体包裹体低CaO并落在CATS-Olivine-Quartz相图的热障碍边界线富硅一侧,以及橄榄石低Ca和陡倾的Fo-Ni关系,指示黄半吉沟高镁安山岩的幔源岩浆是来自以斜方辉石为主辉石岩的源区。我们认为广泛发育于辽西地区的早白垩世义县组高镁安山岩可能经历了壳幔相互作用,因而不能作为拆沉作用导致岩石圈大规模减薄的重要证据。     

松潘-甘孜地体中部晚三叠世安山质增生弧的确定及其意义

本文研究揭示,巴颜喀拉-松潘甘孜地体(简称松潘-甘孜地体)中部三叠系复理杂岩中的安山岩块是增生弧岩浆活动的产物,具有高度不均一均匀的岩石组构、地球化学与同位素组成。特别是这些安山岩显示了与松潘-甘孜三叠系海相浊积岩具有高度的Sr-Nd同位素亲缘性,沿亏损地幔和三叠系海相浊积岩混熔曲线分布,且主要分布于三叠系海相浊积岩端元区。这表明该增生弧安山质岩浆主要由增生楔中的海相浊积岩基质部分熔融形成,并受到了增生楔中大洋岩石圈残片等超镁铁/铁镁质组分的不同程度混染。安山岩时代(226.8±1.9Ma~213.7±0.9Ma)以及同时期广泛的S型花岗岩侵入活动(228±2Ma~204±7Ma)揭示增生弧形成于晚三叠世Norian期。前人工作表明,位于松潘-甘孜地体东北隅的诺尔盖-松潘盆地是一个周缘前陆盆地。因此,松潘-甘孜地体并非单一构造成因的地质体,至少由二叠纪-三叠纪演化的古特提斯大洋和中三叠世拉丁期-晚三叠世诺列期周缘前陆盆地两部分构成。前者是松潘-甘孜地体的主体部分,由松潘-甘孜古特提斯洋在三叠纪时期快速收缩形成的增生楔杂岩组成,其上发育增生弧,局部残存古特提斯大洋盆地及被构造移置的洋壳残片;后者为西秦岭弧(248~234Ma)与扬子地块碰撞的产物。     

The onset of post-collisional magmatism in the Macururé Domain,Sergipano Orogenic System: The Glória Norte Stock

In the northern-central portion of the Sergipano Orogenic System there is an expressive Neoproterozoic granitic magmatism with high-K calc-alkaline and shoshonitic affinities. The Glória Norte Stock (GNS, 45 km²) is the most important representative of the shoshonitic magmatism in one the domains of the Sergipano System, the Macururé. The contacts of the stock with the host metasedimentary rocks are discordant and steep, with generation of amphibolite facies hornfels. The GNS is made up of predominantly porphyritic quartz-monzonite and monzogranite. It shows a magmatic flow foliation defined by oriented mafic enclaves and feldspar phenocrysts, without evidence for solid state regional deformation. Mafic microgranular enclaves (MME) are abundant and present different sizes and shapes. Minette and biotite diopside cumulate enclaves are also present. Coexistence between two different magmas is indicated by crystal corrosion and dissolution textures, compositional zoning of feldspar and presence of clusters of mafic minerals. Grain size decrease towards the rims of the MME indicates fast cooling of small drops of mafic magma, due to temperature contrast with the felsic magma. The monzonites and granites of the GNS have shoshonitic affinity, and the enclaves are related to ultrapotassic suites (MgO > 3%, K₂O > 3%). LREE are enriched as compared to HREE, and there are remarkable negative anomalies of Ta, Nb, Ti, P, Sr and Eu, mostly in the enclaves. The MME have been probably formed from a mantellic magma with shoshonitic affinity. The observed evolution from MME to quartz-monzonites and monzogranites is essentially linked to a process of fractional crystallization. The relations between Ta/Yb and Th/Yb ratios suggest enriched mantle as a possible source of this magmatism. The relative enrichment in Rb, Th, Ce and Sm indicates that magma was generated in post-collisional events. The U-Pb_SHRIMP age of 588 ± 5 Ma in zircon crystals indicates that the emplacement of the GNS represents a post-collisional magmatism, marking the end of collisional processes in the Macururé Domain.