南海海盆区莫霍面分布规律及其对深部钻探的意义

钻遇莫霍面是人类一直以来的梦想。深海海底是地球上离莫霍面最近的地方，目前有研究推测南海是世界上莫霍面深度最浅的海域之一，但缺乏足够的直接证据。深反射地震探测可以直接揭示岩石圈的构造形态，是莫霍面探测的重要手段。本文基于长达15000 km的深反射多道地震剖面的解释、处理、制图和分析，结合前人的研究，形成了南海海盆区莫霍面反射特征和空间分布的初步认识。① 南海东部次海盆南部早期经历了较快速扩张，岩浆供应充足，受扩张停止后岩浆活动影响较小，基底平坦，地质构造相对简单，同时洋壳地震速度结构不存在异常，且有较强的广角莫霍面反射波和可识别的地幔顶部折射波，具备莫霍面钻探的基本条件。② 南海海盆不同区域的莫霍面反射强度存在较大差异。其中东部次海盆莫霍面反射最为强烈且清晰，西北次海盆次之，西南次海盆仅有零星出现的清晰莫霍面反射且可信度不高。③ 识别南海海盆区莫霍面地震反射长度超过3500 km，首次形成了海盆区深度域莫霍面地震反射空间分布图。与重力反演的莫霍面深度相比，利用深反射多道地震计算的莫霍面深度细节更为丰富，并且可以在垂向上清晰刻画莫霍面的结构。整体上，南海海盆区莫霍面地震反射强烈和可信度高的区域中，深度较浅的区域之一是东部次海盆南部，最浅处仅约9. 5 km，其中水深4. 01 km，洋壳厚度仅5. 54 km。综合判断，东部次海盆南部是南海重要的莫霍面钻探备选区，这对南海莫霍面钻探选址具有重要意义。     

南极长城站地区现代环境地球化学特征

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。     

云南大地热流及地热地质问题

本文报道了云南20多个大地热流测试数据。据热流分布特点并参考前人有关资料,结合地球物理测深资料、岩石热物性与放射性生热率测试数据,对各区地壳深度范围的温度、热流配分组成作了粗略分析,划分出各有特征的若干地质-热流区。云南普遍地热偏高(滇东南小范围除外)的主要原因是新构造运动强烈;怒江以西近代岩浆活动亦强烈,具有典型的板块交汇带的基本地热特点     

Strength and stability of frictional sliding of gabbro gouge at elevated temperatures

To investigate the strength of frictional sliding and stability of mafic lower crust, we conducted experiments on oven-dried gabbro gouge of 1 mm thick sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) at slip rates of 1.22 × 10^− 3 mm/s and 1.22 × 10^− 4 mm/s and elevated temperatures up to 615 °C. Special attention has been paid to whether transition from velocity weakening to velocity strengthening occurs due to the elevation of temperature.Two series of experiments were conducted with normal stresses of 200 MPa and 300 MPa, respectively. For both normal stresses, the friction strengths are comparable at least up to 510 °C, with no significant weakening effect of increasing temperature. Comparison of our results with Byerlee's rule on a strike slip fault with a specific temperature profile in the Zhangbei region of North China shows that the strength given by experiments are around that given by Byerlee's rule and a little greater in the high temperature range.At 200 MPa normal stress, the steady-state rate dependence a − b shows only positive values, probably still in the “run-in” process where velocity strengthening is a common feature. With a normal stress of 300 MPa, the values of steady-state rate dependence decreases systematically with increasing temperature, and stick-slip occurred at 615 °C. Considering the limited displacement, limited normal stress applied and the effect of normal stress for the temperatures above 420 °C, it is inferred here that velocity weakening may be the typical behaviour at higher normal stress for temperature above 420 °C and at least up to 615 °C, which covers most of the temperature range in the lower crust of geologically stable continental interior. For a dry mafic lower crust in cool continental interiors where frictional sliding prevails over plastic flow, unstable slip nucleation may occur to generate earthquakes.     

Paleoproterozoic (2155–1970 Ma) evolution of the Guiana Shield (Transamazonian event) in the light of new paleomagnetic data from French Guiana

We present a comprehensive paleomagnetic study on Paleoproterozoic (2173–2060 Ma) plutonic and metamorphic rocks from French Guiana, representative of the full range of the main Transamazonian tectonothermal steps. Twenty-seven groups of directions and poles were obtained from combination of 102 sites (613 samples) based on age constraint, similar lithology and/or geographical proximity. Paleomagnetic results show variations between rocks of different ages which are supposed to be characteristic of magnetizations acquired during uplift and cooling of successive plutonic pulses and metamorphic phases. This is also reinforced by positive field tests (baked contact and reversal tests). Recent U/Pb and Pb/Pb on zircon and complementary ⁴⁰Ar/³⁹Ar on amphibole and biotite allow questioning the problem of magnetic ages relative to rock formation ages. Estimated magnetic ages, based on amphibole dating as a proxy, enable us to construct a Guiana Shield apparent polar wander path for the 2155–1970 Ma period. It is also possible to present paleolatidudinal evolution and continental drift rates related to specific Transamazonian tectonic regimes.French Guiana and probably the Guiana Shield were located at the Equator from ca. 2155 to 2130 Ma during the Meso-Rhyacian D1 magmatic accretion phase, related to subduction of Eorhyacian oceanic crust. After closure of the Eorhyacian Ocean and collision of West African and Amazonian plates, the Guiana Shield moved. The first evolution towards 60° latitude, occurs after 2080 Ma, during the Neorhyacian D2a post collisional sinistral transcurrent phase. During the Late Rhyacian D2b phase, up to 2050 Ma, the Guiana Shield reaches the pole and starts to move to lower latitudes on an opposite meridian. By the Orosirian D2c phase, from ca. 2050 to 1970 Ma, the Guiana Shield reaches the Equator.Based on the amphibole ⁴⁰Ar/³⁹Ar dates, we estimate the continental drift between 12 and 16 cm/y for the Meso to Late Rhyacian period followed by a lower rate between 9 and 14 cm/y up to Orosirian time. This study highlights rock ages and magnetic ages are prerequisite to any continental reconstruction especially when it is shown continental drift is important for a 100–200 Ma time period. Our results confirm the possibility of APWP construction on Paleoproterozoic plutonic rocks but suggest improvement will rely on the combination with multidisciplinary approaches such as structural geology and multi-method radiometric dating.     

Seismic lamination and anisotropy of the Lower Continental Crust

Seismic lamination in the lower crust associated with marked anisotropy has been observed at various locations. Three of these locations were investigated by specially designed experiments in the near vertical and in the wide-angle range, that is the Urach and the Black Forrest area, both belonging to the Moldanubian, a collapsed Variscan terrane in southern Germany, and in the Donbas Basin, a rift inside the East European (Ukrainian) craton. In these three cases, a firm relationship between lower crust seismic lamination and anisotropy is found. There are more cases of lower-crustal lamination and anisotropy, e.g. from the Basin and Range province (western US) and from central Tibet, not revealed by seismic wide-angle measurements, but by teleseismic receiver function studies with a P–S conversion at the Moho. Other cases of lamination and anisotropy are from exhumed lower crustal rocks in Calabria (southern Italy), and Val Sesia and Val Strona (Ivrea area, Northern Italy). We demonstrate that rocks in the lower continental crust, apart from differing in composition, differ from the upper mantle both in terms of seismic lamination (observed in the near-vertical range) and in the type of anisotropy. Compared to upper mantle rocks exhibiting mainly orthorhombic symmetry, the symmetry of the rocks constituting the lower crust is either axial or orthorhombic and basically a result of preferred crystallographic orientation of major minerals (biotite, muscovite, hornblende). We argue that the generation of seismic lamination and anisotropy in the lower crust is a consequence of the same tectonic process, that is, ductile deformation in a warm and low-viscosity lower crust. This process takes place preferably in areas of extension. Heterogeneous rock units are formed that are generally felsic in composition, but that contain intercalations of mafic intrusions. The latter have acted as heat sources and provide the necessary seismic impedance contrasts. The observed seismic anisotropy is attributed to lattice preferred orientation (LPO) of major minerals, in particular of mica and hornblende, but also of olivine. A transversely isotropic symmetry system, such as expected for sub-horizontal layering, is found in only half of the field studies. Azimuthal anisotropy is encountered in the rest of the cases. This indicates differences in the horizontal components of tectonic strain, which finally give rise to differences in the evolution of the rock fabric.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

Variscan to eo-Alpine events recorded in European lower-crust zircons sampled from the French Massif Central and Corsica, France

Ion-microprobe U–Pb zircon dating of lower-crust metasedimentary granulite are reported on samples from two localities in Europe in order to determine (a) how this environment recorded the Variscan and eo-Alpine events, and (b) whether the transition between the two orogenic cycles was continuous or separated by a gap. The samples come from enclaves hosted by Miocene volcanoes at Bournac in the French Massif Central, and from the granulitic metasedimentary basement of the Alpine Santa Lucia nappe in Corsica, on the South European paleomargin of the Ligurian branch of the Tethys Sea. The zircon ages from Bournac range between 630 and 430 Ma and between 380 and 150 Ma with a major frequency peak at 285 Ma; the zircons older than 430 Ma are interpreted as detrital, whereas those younger than 380 Ma are considered to have formed by metamorphic processes after burial in the lower crust. Zircon ages from Santa Lucia range from to 356 to 157 Ma, with exception of one inherited Archean grain, and are interpreted like the younger Bournac zircons as having been formed by metamorphic processes.

In a granulite metamorphic environment, as opposed to an anatectic environment, new zircon growth can occur in the solid state. Once Zr has been incorporated into zircon, however, it is difficult to remobilize without dissolution; thus Zr available for new zircon growth must result from the breakdown of Zr-bearing minerals during prograde and/or retrograde events. In this light, the U–Pb zircon-age probability curves are interpreted as markers for major tectonometamorphic events, as suggested by the close correspondence between peaks in the curve and geological events recorded in the upper-crust, such as magma emplacement and basin subsidence.

Evidence of a tectonometamorphic gap between the Variscan and Alpine orogeneses is provided by the Santa Lucia zircon-age probability curve, which reveals a probable interlude during the Variscan–Alpine transition between 240 and 210 Ma. Here, the peak at 240 Ma is interpreted as the very beginning of crustal extension and the low at 210 Ma as a period of quiescence prior to the formation of an active margin and oceanization.