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81.
IwrincrIONOn the evolution of palcoenvironment, salt-water encroachmnt and the distributionof subsurface brine in the LaizhOu Bay area, many researches had been carried out, and muchknowledge abeut the gcolOgical features in this area since Late QUaternary was aCquired' ) (H8nand Wu, l992; Han and Meng, l994; Wen et al. l989). However there was IittIe studyon the sediment geOChemical characteristics since Quaternary. In this Paper, the element strati-graphic characteristics and evolut… 相似文献
82.
Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia 总被引:1,自引:0,他引:1
Christophe Migon Sylvain Ouillon Xavier Mari Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756
Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L−1), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L−1 near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources. 相似文献
83.
研究取自于东太平洋CC48柱状样的钙质超微化石和底栖有孔虫的氧同位素成分变化的结果表明,该区下中新统至少可分出九个氧同位素地层(期),反映该区在早中新世期间至少经历了4次气温上升和5次下降的古气候变化。南极大陆冰川应是形成于早中新世而不是前人认为的中中新世。在早中新世,南极冰体体积有较大的变化。受古气候变化的影响,在早中新世期间东太平洋水柱热结构或温度梯度有比较大的变化,海平面出现多次上升与下降。 相似文献
84.
Serena M. Moseman Lisa A. Levin Carolyn Currin Charlotte Forder 《Estuarine, Coastal and Shelf Science》2004,60(4):755-770
Modes of colonization, the successional trajectory, and trophic recovery of a macrofaunal community were analyzed over 19 months in the Friendship marsh, a 20-acre restored wetland in Tijuana Estuary, California. Traditional techniques for quantifying macrofaunal communities were combined with emerging stable isotopic approaches for evaluation of trophic recovery, making comparisons with a nearby natural Spartina foliosa habitat. Life history-based predictions successfully identified major colonization modes, although most taxa employed a variety of tactics for colonizing the restored marsh. The presence of S. foliosa did not seem to affect macrofaunal colonization or succession at the scale of this study. However, soil organic matter content in the restored marsh was positively correlated with insect densities, and high initial salinities may have limited the success of early colonists. Total macrofaunal densities recovered to natural marsh levels after 14 months and diversity, measured as species richness and the Shannon index (H′), was comparable to the natural marsh by 19 months. Some compositional disparities between the natural and created communities persisted after 19 months, including lower percentages of surface-feeding polychaetes (Polydora spp.) and higher percentages of dipteran insects and turbellarians in the Friendship marsh. As surficial structural similarity of infaunal communities between the Friendship and natural habitat was achieved, isotopic analyses revealed a simultaneous trajectory towards recovery of trophic structure. Enriched δ13C signatures of benthic microalgae and infauna, observed in the restored marsh shortly after establishment compared to natural Spartina habitat, recovered after 19 months. However, the depletion in δ15N signatures of macrofauna in the Friendship marsh indicated consumption of microalgae, particularly nitrogen-fixing cyanobacteria, while macroalgae and Spartina made a larger contribution to macrofaunal diets in the natural habitat. Future successional studies must continue to develop and employ novel combinations of techniques for evaluating structural and functional recovery of disturbed and created habitats. 相似文献
85.
Julian Augley Mark Huxham Teresa F. Fernandes Alastair R. Lyndon Sarah Bury 《Estuarine, Coastal and Shelf Science》2007,72(4):648-656
The stable carbon isotope ratios (δ13C) of the organic fraction of intertidal sediments in the Forth Estuary and the Firth of Forth, Scotland, were measured to determine if terrestrially derived carbon was present in the estuarine sediments. It was hypothesised that differences in the inputs from marine vs. terrestrial sources to the organic carbon of estuarine and marine sediments, as well as differences in ambient seawater stable oxygen isotope (δ18O) ratios between the estuary and the Outer Firth, would allow the use of these two stable isotopes as habitat markers for juvenile plaice (Pleuronectes platessa), to allow determination of nursery habitats. Muddy and sandy sediments from the estuary and sandy sediments from the Outer Firth were sampled and δ13C measured. Juvenile plaice were caught at two estuarine sites and at two Outer Firth sites and otoliths were removed for δ13C and δ18O analysis. The sandy sediments in the estuary showed a strong gradient of δ13C enrichment with distance down the estuary, while the muddy sediments showed a much shallower gradient. δ13C and δ18O measured in the carbonate of juvenile plaice otoliths showed no clear difference between otoliths of fish caught at one of the estuarine sites and at the two Outer Firth sites. However, the isotope ratios of both carbon and oxygen in plaice otoliths from the other estuarine site showed the expected trend of depletion in the heavier isotopes. While the measurements recorded here did not conclusively distinguish between otoliths from juveniles caught in the estuarine site and those caught in the other three sites, they show that stable isotopes have potential to distinguish between estuarine habitats with terrestrial carbon inputs, and coastal marine habitats with predominantly marine carbon inputs. 相似文献
86.
稳定同位素在天然气水合物地球化学勘查中的应用简介--以"布莱克海隆"海区为例 总被引:2,自引:0,他引:2
介绍了国外在布莱克海隆(包括ODP164航次994、995、997站位)进行天然气水合物勘查过程中应用稳定同位素的研究实例;通过对这3个站位样品的甲烷、CO2、DIC(dissolved inorganic carbon)、有机碳以及自生碳酸盐的δ^13C分析,指出浅部(0-30m)甲烷和DIC的δ^13C值随深度迅速降低又迅速升高的变化可以作为天然气水合物存在的地球化学指标。994站位孔隙水δ^18O值深度从0.30‰下降到-0.37‰;氢同位素δD随深度略有下降(从11‰到-12‰),这与水合物形成时氢氧重同位素相对富集于固相有关,表明天然气水合物的存在。997站位δ^37Cl从海底沉积物表层以下30m处为接近海水的最大值0,至钻孔底746.85m处降为-3.68‰,可能也与天然气水合物的形成有关。 相似文献
87.
88.
西菲律宾海沉积物铁族元素地球化学 总被引:5,自引:1,他引:5
本文对取自西菲律宾海区的三个柱状沉积物岩芯的铁族元素地球化学行为进行了系统的研究。从元素的含量及剖面变化、元素的相关性及组合特征,铁族元素与主元素的关系以及元素的赋存状态等方面探讨了物质来源、沉积作用和古气候,并据此进行了地层划分。沉积物有4种来源:海底火山源、生物源、自生源和陆源。海底火山物质提供了较多的铁族元素,相形之下,自生沉积作用较弱。元素地层学研究表明,在全新世温暖期和晚更新世寒冷期铁族元素表现出不同的地球化学行为,尤以Mn和亲生物(Ca)元素对气候的反映灵敏。WP_2孔和WP_(40)孔铁族元素特征相似,与WP_1孔差别较大。 相似文献
89.
Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O2 takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O2 and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g−1 and 3.1 μmol g−1, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g−1), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g−1 and 1.6 mmol g−1, respectively) and of cracks (5.1 μmol g−1 and 0.47 mmol g−1). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases. 相似文献
90.
珠江口河流输沙、河口沉积与粒度信息之间的联系 总被引:2,自引:0,他引:2
河口三角洲地区泥沙供应充分,是现代沉积速率较高的区域。快速沉积的泥沙包含高分辨率的环境信息。采用放射性同位素测年方法研究了珠江口伶仃洋大铲湾海域6个柱样的现代沉积速率,以2mm的间隔分析了其中2个柱样上部的粒度,并对其平均粒径和珠江流域的年输沙量进行了快速傅里叶变换,以期获取河流泥沙供应、河口沉积速率和沉积物垂向粒度变化的对应关系。结果表明,大铲湾海域的沉积速率为1~3cm/a,受动力条件和泥沙供应条件的影响显著。2个柱样的平均粒径的最显著重现周期与珠江年输沙量的周期性有较好的对应关系,并可能反映了季节的、年的和多年的沉积速率信息。对于每年沉积厚度在厘米级的环境,以毫米级的高分辨率进行粒度分析,有可能揭示出沉积物供应的季节变化和年际变化。本研究亦可为其他河口的相关工作提供借鉴。 相似文献