陆丰南地区断拗转换界面厘定及其地质意义

珠江口盆地经历裂陷阶段向拗陷阶段的转变，同期沉积地层记录了该构造变革和沉积演化过程，为厘定断拗转换界面提供了可能。基于地震反射、沉积旋回特征，识别出陆丰南地区恩平组内部存在全区可追踪对比的构造沉积转换面——T72界面，也是区分上下恩平组界面。对陆丰13洼洼间隆钻井LFA开展上下恩平组碎屑锆石U- Pb 定年、重矿物组分、元素分析，提出恩平组T72界面上下地层物源体系发生转变。结合区域沉积充填特征，表明陆丰南地区T72界面为断- 拗转换界面。具体表现为：下恩平组沉积期湖盆继承文昌期裂陷盆地特征，湖盆水体较深，物源主要为盆地内部的中生代基底凸起，沉积层序明显受盆内低凸起控制，在盆内低凸起四周发育一系列近源的辫状河三角洲，井区主要接受来自惠陆低凸起物源;上恩平组沉积期间，湖盆进入断拗过渡期，湖盆扩大、水体变浅，盆内低凸起四周的断裂活动减弱，沉积层序逐渐向盆内低凸起超覆，盆外太古宙—古生代物源组分供给不断加强，近源的三角洲砂体逐渐向远源的浅水三角洲砂体转化，同时发育宽广的滨浅湖环境，原供给物源的惠陆低凸起为水体淹没，井区接受了北部隆起外的物源。     

张广才岭南部杨木岗组的厘定及物源分析

本文通过岩石组合特征和区域对比，将张广才岭南部西蛤拉河子—大锅盔一带分布的浅变质地层重新厘定为杨木岗组。为了确定杨木岗组的形成时代和沉积物源，进行了碎屑锆石U- Pb年代学和微体古生物地层学研究。锆石大多数呈自形—半自形晶，显示典型振荡岩浆生长环带，暗示其岩浆成因。该地层中测得的两组碎屑锆石U- Pb产生多组谐和年龄，其中PM010- TW样品56个测点最小峰值(谐和)年龄为307 Ma，DB02- TW样品51个测点最小峰值(谐和)年龄为275 Ma；覆盖在杨木岗组之上的中生代二浪河组安山岩的定年结果为181. 1±0. 9 Ma，表明杨木岗组形成于早二叠世晚期。杨木岗组中获取疑源类化石组合出现了新元古代晚期—早寒武世和奥陶纪地层常见分子，结合碎屑锆石年龄结果，反映杨木岗组沉积时周围存在早古生代和中—新元古代地质体。碎屑沉积岩Al2O3/TiO2平均值为24. 44，稀土元素球粒陨石标准化曲线具有轻稀土富集、重稀土稳定和负Eu异常特征，结合碎屑锆石的年龄频数可以看出，确定杨木岗组的沉积物主要来源于沉积盆地周围的晚古生代早期中酸性火成岩，次要物源由沉积盆地周边的早古生代地质体和近地表的中—新元古代地质体提供。佳木斯地块为松嫩- 张广才岭地块上晚古生代地层的形成提供了部分物源，暗示佳木斯地块与松嫩- 张广才岭地块于早二叠世之前已完成拼合。     

甘孜- 理塘洋可能存在北向俯冲：来自松潘- 甘孜道孚- 炉霍岩浆岩的证据

松潘- 甘孜造山带巨厚的三叠系复理石沉积盖层给探讨其基底性质、俯冲- 碰撞过程和深部岩浆作用增添了难度，使得带内广泛出露的花岗质岩体和少量镁铁质岩体成为解开松潘- 甘孜造山带构造演化谜团的重要研究对象。锆石U- Pb定年结果表明道孚花岗闪长岩形成于223. 5~217. 4 Ma，炉霍二长岩结晶年龄为219. 4 Ma，辉长岩为218. 9 Ma，均属于晚三叠世岩浆活动的产物。化学成分研究结果表明，花岗质岩石都表现出I型花岗岩特征，其中炉霍二长岩具有较高的Ba、Sr含量，相对较高且均一的εHf(t)值（-3. 69~-1. 65），表明其可能来源于富集玄武质新生下地壳的熔融。道孚花岗闪长岩具有分散的εHf(t)值（-13. 51~0. 41），野外和地球化学特征指示其形成于幔源熔体与古老壳源熔体的混合。辉长岩在微量元素蜘蛛图上具有类似的模式，不同程度富集Ba、Sr、Pb、Th和U元素，出现Nb、Ta、Ti元素亏损，具有岛弧玄武岩的特征，来源于流/熔体交代的地幔楔部分熔融。综合区域已有资料，我们对甘孜- 理塘洋的演化历史提出新的认识，认为甘孜- 理塘洋不仅仅存在向南俯冲的可能性，同时也具有北向俯冲的历史，晚三叠世道孚- 炉霍岩浆岩的形成受控于甘孜- 理塘洋向北边松潘- 甘孜地块俯冲的背景之下。     

北大别饶拔寨石榴辉石岩P-T-t轨迹及其构造意义

P-T-t轨迹作为变质岩的重要研究方法之一，对揭示岩石的构造演化过程具有重要意义。北大别饶拔寨镁铁-超镁铁岩形成的构造环境和就位过程长期以来尚存争议。本文通过岩相学观察、矿物化学研究和温压计计算，揭示出饶拔寨石榴辉石岩经历了四个变质演化阶段：1）超高压变质阶段（M1）：主要根据石榴子石中金红石的出溶，单斜辉石中石英的出溶和磷灰石中不透明矿物的出溶，结合前人研究，认为饶拔寨石榴辉石岩经历过超高压变质阶段（≥2.5GPa）；2）高压麻粒岩相阶段（M2）：矿物组合为石榴子石（变斑晶）和单斜辉石（基质）+斜长石（基质），记录的温压条件为T=648~700℃，P=1.47~1.94GPa；3）中压麻粒岩相阶段（M3）：以石榴子石外围发育的主要由斜方辉石+斜长石组成的内圈"白眼圈"为特征，形成的温压条件为T=781~796℃，P=0.92~0.98GPa；4）角闪岩相阶段（M4）：以石榴子石变斑晶周围发育的外圈"白眼圈"为特征，其矿物组合为角闪石+斜长石的后成合晶，形成的温压条件为T=663~685℃，P=0.50~0.58GPa。石榴辉石岩的锆石SIMS U-Pb定年得到了3组不同的交点年龄，分别为208.1~202.1Ma、227.6Ma和817.7Ma。根据锆石包裹体中角闪石+斜长石的组合，推断208.1~202.1Ma代表了角闪岩相变质年龄的下限，227.6Ma则是高压麻粒岩相的下限年龄，而新元古代年龄（817.7Ma）与区域上的变质岩原岩年龄一致，可能代表了其原岩年龄。结合前人研究，饶拔寨石榴辉石岩记录了顺时针的P-T-t轨迹，揭示了板片俯冲（超高压变质）-碰撞-折返（降压升温过程，~227Ma）-抬升（降压降温过程，208~202Ma）的完整过程。     

秦岭南缘勉略带构造属性及晚古生代地质背景:来自碎屑锆石U-Pb年代学的制约

勉略构造带作为秦岭造山带内重要的构造边界,关于其构造属性及晚古生代以来的地质背景,一直是学术界争论的焦点。碎屑锆石U-Pb年代学在限定地层单元的最大沉积年龄、研究区域构造岩浆事件及约束构造地质背景等方面行之有效。基于此,通过对勉略带内五郎坪北侧两河口变沉积地层和侵入其中的变形花岗岩脉体进行LA-ICP-MS锆石U-Pb年代学研究。获得2件变形花岗岩脉的结晶年龄均为406±1Ma。碎屑锆石主年龄谱分别为422～456Ma和558～826Ma,峰值年龄为441Ma和771Ma、813Ma,次级年龄谱分别为942～1495Ma和1658～2981Ma,峰值年龄不明显。依据最小一组碎屑锆石的峰值年龄(441Ma),和侵入其中的变形花岗岩脉(406±0.6Ma),限定该变沉积地层形成时代为406～441Ma(S_1-D_1)。碎屑锆石年龄谱显示该套变沉积地层物质来源较为复杂,其中秦岭造山带及扬子板块北缘早古生代、新元古代岩浆岩为其提供了74%±的物源,古老变质基底为其提供了26%±的物源。通过与区域上已有资料对比,认为勉略构造带内晚古生代沉积地层形成环境与邻区大致相同,且本次所获得的变沉积岩碎屑锆石年龄谱也与邻区泥盆系相似。综合认为,勉略构造带与邻区在晚古生代应属同一构造环境,晚古生代"勉略海盆"应当包括整个南秦岭。     

Detrital zircon reference for the North China block

U–Pb analyses of 250 single detrital zircons from Upper Proterozoic to Ordovician strata collected from the Zhuozi Shan in north-central China provide a detrital zircon reference for the North China block, a major crustal entity in the Asian tectonic collage. The results, which range in age from 1.72 to 2.97 Ga, shed new light on the age of the crystalline basement in North China, much of which is covered by younger sedimentary units. In addition, this detrital zircon reference can be used to help determine the provenance of clastic sedimentary units and for assessing validity of paleogeographic and regional tectonic models that include the complex history of Asian continental amalgamation, terrane accretion, and subsequent translation that is ongoing today.     

From source terrains of the Eastern Alps to the Molasse Basin: Detrital record of non-steady-state exhumation

Fission-track cooling ages of detrital apatite (AFT) in the East Alpine Molasse Basin display age groups corresponding to geodynamic events in the orogen since Jurassic times. These age groups are typical of certain thermotectonic units, which formed a patchwork in the Swiss and Eastern Alps. By a combination of petrographic and thermochronologic data, progressive erosion of source terrains is monitored in different catchments since the Oligocene. The AFT cooling ages show a decrease in lag time until when rapidly cooled debris derived from tectonically exhumed core complexes became exposed. After termination of tectonic exhumation, lag times of debris derived from the core complexes increased. Neither on the scale of the entire Eastern Alps, or on the scale of individual catchments, steady-state exhumation is observed, due to the highly dynamic changes of exhumation rates since Late Eocene collision.     

Up-temperature flow of surface-derived fluids in the mid-crust: the role of pre-orogenic burial of hydrated fault rocks

The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ¹⁸O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ¹⁸O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD_(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ¹⁸O fluid that is channelled through shear zones related to Delamerian Orogenic activity.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.