Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

新技术在北极星天文方位角测量中的应用

使用GPS接收机的UTC作为北极星天文方位角测量的时间比对的标准时间，利用推估UTl与UTC的差值，将时间归算到UTl的方法，可满足各等级天文方位角测量的要求，现场计算零点恒星时和北极星坐标的精度满足北极星天文方位角测量的要求，实现了现场评估测量精度。     

自适应GM(1,1)模型进行地表沉降预报

提出采用自适应GM( 1 ,1 )模型进行地表沉降预报 ,并用于兖州某矿形变控制点的沉降预报 ,效果令人满意。说明此模型具有实用价值。     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

青藏高原1∶25万区域地质调查地貌年代学研究

高原隆升及剥蚀作用的复杂性与区域差异性以及高原恶劣的气候、地理条件,使得在青藏高原空白区1∶25万区域地质调查中进行地貌年代学研究具有很大的现实意义.由于地貌是高原隆升、环境演化、新构造运动等的信息载体,地貌年代有助于重塑这些地质作用的发生时间及发展过程,因此地貌年代学研究具有重要的技术意义.1∶25万银石山幅的工作表明,地貌年代学调查对高原隆升及环境演化过程研究具有良好效果.     

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.     

Early Cretaceous planktonic foraminifera from the Tethys: the large, many-chambered representatives of the genus Globigerinelloides

This paper deals with the taxonomic revision of the Early Cretaceous large, many-chambered planispiral planktonic foraminifera, historically assigned to the genus Globigerinelloides or alternatively assigned in the 1990s to the genera Globigerinelloides Cushman and ten Dam, Biglobigerinella Lalicker, Blowiella Krechmar and Gorbachik and Alanlordella BouDagher-Fadel. In a previous paper we demonstrated that the morphological and microstructural features used in the literature for distinguishing Blowiella from Globigerinelloides have value only at species level, and the former genus was thus invalidated (being the junior synonym). Moreover, the Late Aptian specimens assigned to Biglobigerinella by some authors, based on the presence of twin last chamber(s), are also included in Globigerinelloides because individuals sharing the same features (number of chambers, growth rate, size of umbilicus, and a finely perforate wall) may or may not possess twin last chamber(s). Meanwhile, Moullade et al. questioned the taxonomic value of Alanlordella, erected by BouDagher-Fadel to accommodate planispiral taxa possessing a macroperforate wall. All the species analysed here possess a finely perforate wall and consequently cannot be assigned to this taxon.The large species of Globigerinelloides retained here, with six or more chambers in the outer whorl, are G. algerianus Cushman and ten Dam, G. aptiensis Longoria, G. barri (Bolli, Loeblich and Tappan) and G. ferreolensis (Moullade).In the sections studied, Globigerinelloides aptiensis was first found close to the Barremian/Aptian boundary, even though this species was recorded in Spain (Rio Argos) in the mid Upper Barremian; very rare, small, seven-chambered individuals here assigned to Globigerinelloides ferreolensis are recorded in the Lower Aptian (just below and within the Selli Level, OAE1a), while a few specimens belonging to Globigerinelloides barri occur in the Globigerinelloides ferreolensis Zone (Upper Aptian). Globigerinelloides aptiensis and G. ferreolensis range up to the Ticinella bejaouaensis Zone while Globigerinelloides barri disappears at the top of the Globigerinelloides algerianus Zone; finally, Globigerinelloides algerianus obviously spans the eponymous total range zone.From an evolutionary point of view, two lineages within the many-chambered Globigerinelloides have been recognized. In the first, already known in the literature, Globigerinelloides aptiensis gave rise to G. ferreolensis, which evolved into G. algerianus; the latter in turn gave rise to Pseudoplanomalina cheniourensis as the final evolutionary member. In the second lineage Globigerinelloides barri originated from G. blowi.     

从冷科1井下部地层的归属探讨柴达木盆地成盆时间

冷科1井是近年来柴达木盆地北缘最重要的一口科学探索井。因该井首次发现了巨厚的新地层，所以对该井的4666－5200m地层划分存在较大争议。前人主要依据孢粉资料把冷科1井4666－5200m层段归属为下侏罗统，也有人依据从该段发现的海相化石碎片认为该段为石炭系。本文从岩性组合、古生物特征、地震剖面、测井电性及水介质特征等多方面对该层段进行了分析，否定了该段为下侏罗统和石炭系的可能，认为该段为上三叠统。该研究改变了过去柴达木盆地始于早侏罗世的观点，指出柴达木盆地起始于晚三叠世零星分布的断陷沉积。     

昆仑山口西8.1级地震前青藏块体边界断层异常活动

系统分析了青藏块体边界断层的形变资料，研究了断层活动的动态过程及空间分布。结果表明，昆仑山口西8．1级地震前孕震影响范围达到青藏块体的周边地区；发震断层所在的构造带震前断层活动最为剧烈；加强对构造块体断层整体活动的宏观动态比较和分析，有助于判定未来强震发生的危险地段；震后应力将转移并集中到西秦岭构造带及其邻近地区。