混合溶剂溶解磷灰石分光光度法测定全磷

试验了用柠檬酸－Ａｌ（ＮＯ３）３混合溶剂分解磷灰石,可有效地消除分光光度法测定磷灰石中全磷时干扰离子的影响,此方法测得结果与磷钼酸喹啉重量法分析结果相符;其ＲＳＤ〈５％（ｎ＝６）。     

苏北超基性岩某些超高压变质特征

苏北芝麻坊超基性岩体,位于大别—苏鲁超高压变质带东段的核心部位,与基性榴辉岩紧密伴生,是苏北最具代表性的岩体之一。根据多年来的成果资料,研究它的超高压变质特征,对研究整个苏鲁超高压变质带具有重大意义。对岩体的形态特征、岩相学特征、特别是矿物学特征,如镁铝榴石特征的研究,结合金刚石的选出,都有力的证实苏北超基性岩是在超高压变质环境下生成的,同时也反映其是由华北地块与扬子地块俯冲碰撞而从地壳深处挤压上来的幔源物质。     

Nutrient composition and distributions in coastal waters impacted by the Changjiang plume

Four cruises were conducted during 2002--2003 in the Changjiang Estuary and adjacent coastal areas. The data presented show a clear coast to open sea gradient in nutrients related to the river inputs. Maximum values of chlorophyll a were typically observed at intermediate salinities at surface water and coincided with non-conservative decreases in nutrients along the salinity gradient, indicating that removal of nutrients was related to phytoplankton uptake. The seasonal variations of nutrient concentrations were just opposite to those of chlorophyll a, indicating that the seasonal variations of nutrients were mainly controlled by phytoplankton uptake, whereas riverine inputs merely weakened or balanced its extent. During the estuarine mixing, phosphate demonstrated some remobilization during all the four cruises; whereas both conservative and non-conservative behaviors for dissolved inorganic nitrogen and silicate were observed in the study area, indicating that both biotic and abiotic events may affect their behaviors during the estuarine mixing. Under the influence of freshwater inputs with high value of ratio of nitrogen to phosphorus, the estuarine and coastal waters impacted by the Changjiang plume were high （ 〉 30） in ratio of nitrogen to phosphorus, but rates of primary production were apparently not constrained by any kind of nutrient elements. However, the low （ 〈 1 ） ratio of silicate to nitrogen in most of the study area might be linked with the rapidly increasing frequency of harmful algal bloom （HAB） incidents in recent years in the coastal waters impacted by the Changjiang plume.     

氮磷营养盐对中肋骨条藻生长及硝酸还原酶活性的影响

通过实验室培养，在不同氮磷浓度及氮磷比率的营养条件下，对中肋骨条藻（Skeletonema costatum）的生长及藻细胞硝酸还原酶的活性进行研究。实验结果表明，中肋骨条藻属于营养型藻类，氮磷营养盐的添加，极大地促进了藻细胞的增殖。在接种后的第4～5天，各培养组藻密度达到最大值并与对照组形成极显著性差异（P〈0．01）。实验进一步发现，环境中的氮、磷浓度及氮磷比率都会影响中肋骨条藻的生长及藻细胞硝酸还原酶活性（NRA）。此外，在各培养组中，中肋骨条藻硝酸还原酶活性的最大值（NRAmax）均出现在指数生长期（接藻后第1，2天），早于最大藻密度的出现时间（第4，5天），这表明藻对营养盐的同化速率与生长速率并不一致，后者存在一定的滞后效应。在本实验条件下，中肋骨条藻的硝酸还原酶活性存在一定的阈值。     

我国铝土矿资源可持续开发的对策建议

铝的用途十分广泛,铝土矿是生产金属铝的最佳原料,其价值也不同于一般的矿产.铝土矿是指工业上能利用的,以含水氧化铝(三水铝石、硬水铝石或软水铝石)为主要矿物所组成的铝矿石的统称,是目前冶炼金属铝的主要矿石原料,它应用的领域有金属和非金属两个方面.铝土矿在非金属方面的应用所占比重虽小,但是用途却十分广泛,主要是作耐火材料、研磨材料、化学制品及高铝水泥的原料.     

山东半岛北部滨浅海区表层沉积物铝物源鉴别

Surface sediment samples in the near shore area of the north Shandong Peninsula are collected for grain size and element analyses. The results indicate that the surface sediments in the study area are primarily composed of the silt-sized components similar to the Huanghe River. The total concentration of aluminum varies from 5.57% to7.37%(average(6.33 ± 0.40)%), and its spatial distribution is mainly controlled by the grain size. Correlations between the ratio of aluminum to titanium concentration and aluminum concentration, titanium concentration and the mean grain size indicate that aluminum in the near shore surface sediments is affected majorly by the terrigenous source, and partially by the anthropogenic source. The ratios of aluminum to titanium concentrations are larger than the background value of loess matter at some stations due to the existence of excess aluminum associated with human activities. Thus, the sources of aluminum should be identified firstly when aluminum is used as an index of terrigenous matter even in the near shore area dominated by terrigenous deposits.     

内蒙古中部四子王旗地区晚二叠-早三叠世过铝花岗岩定年及成因

研究区位于华北板块北缘中段,紧邻兴蒙造山带,是研究古生代—中生代地壳增生演化的重要地区。本文对区内三个花岗岩体进行了锆石LA-ICP-MSU-Pb定年及岩石地球化学研究。结果表明阿玛乌苏花岗闪长岩形成于267±9Ma(MSWD=9.7);布龙二长花岗岩和格尔图白云母正长花岗岩分别侵位于239±4Ma和238±6Ma(MSWD=0.91);而侵入格尔图白云母正长花岗岩的白云母二长花岗岩脉则获得了224±8Ma(MSWD=5.7)的侵位年龄。岩石地球化学特征显示阿玛乌苏花岗闪长岩为岩浆混合成因,暗示大规模岩浆底侵作用的存在;格尔图白云母正长花岗岩具明显的稀土元素"四分组"效应,是分异岩浆与流体作用的结果,可能经历一定程度的地壳混染,非真正意义上的S型花岗岩,属于造山后岩浆热事件,应代表造山的结束。格尔图白云母正长花岗岩及白云母二长花岗岩脉均受到热液流体作用,说明在中三叠世(224～238Ma),区内一直存在有大量的热液流体活动,且热液流体可能富含F和Cl,区内产出的大规模的萤石矿是否为该期流体活动的产物尚需进一步工作。     

A-C复合交联剂的合成及其应用

合成了3种交联剂:柠檬酸铝、柠檬酸铬、A-C复合交联剂,利用傅立叶红外光谱、紫外光谱对它们进行了表征,并将其用于清水和处理后油田采出污水配制HPAM型聚合物弱凝胶的对比实验。实验表明:A-C复合交联剂用于油田采出污水配制的聚合物弱凝胶的成胶效果最优;当pH值为6、成胶温度为60℃、成胶时间为1 d时所配制的弱凝胶黏度最大,其黏度值达到1 129 mPa.s。随后考察了A-C复合交联剂浓度、成胶温度、矿化度、pH值、S2-及Fe2+等因素对A-C复合交联剂弱凝胶体系黏度的影响效果,结果表明:A-C复合交联剂基本上可用于油田处理后污水配制弱凝胶体系,有望实现油田处理后污水的资源化利用。