东海西湖凹陷保俶斜坡下第三系储层岩石学特征

东海西湖凹陷保俶斜坡下第三系储层砂岩为长石岩屑砂岩或岩屑长石砂岩，杂基含量小于5％，矿物成分主要为伊利石和绿泥石；胶结物主要成分为高岭石、石英次生加大边、碳酸盐矿物，总含量小于10％．     

四元体系Na~ ∥Cl~-,CO_3~(2-),B_4O_7~(2-)-H_2O 273K介稳相平衡研究

采用等温蒸发法研究简单四元体系Na ∥Cl-,CO32-,B4O72--H2O273K时的介稳相平衡,并测定该体系273K平衡液相中各组分的溶解度及密度,该体系的介稳相图和密度组成图显示:该四元体系在273K时的相图由3条溶解度单变量线、3个结晶区及1个共饱和点组成。体系属简单共饱型,无复盐或固溶体形成,3个结晶区分别对应单盐Na2CO3·10H2O,NaCl和Na2B4O7·10H2O。共饱点E处于Na2CO3·10H2O,NaCl及Na2B4O7·10H2O3盐共饱和,所对应的平衡液相组成为w(Na2CO3)=6.81%,w(NaCl)=21.69%,w(Na2B4O7)=0.65%,w(H2O)=70.85%。研究体系在273K下,Na2CO3·10H2O是碳酸钠盐的唯一析出形式,且硼酸钠对碳酸钠有盐析作用。     

南黄海北部盆地东北凹陷烃源岩的早期预测

烃源岩评价是沉积盆地油气地质研究的重要组成部分,尤其对油气勘探初期的战略选区与决策至关重要.南黄海北部盆地东北凹陷的油气勘探程度极低,至今尚无探井揭示烃源岩的发育特征,因此制约了凹陷的油气勘探进程.基于地质类比原理,采用与其相邻类似凹陷--北部凹陷综合对比的方法,应用层序地层、沉积相、地震相分析及含油气盆地动态数值模拟等技术,分析了东北凹陷主要烃源岩层的空间展布和生烃演化特征,并初步形成了一套适用于勘探程度低的地区烃源岩早期预测的方法技术流程.研究表明,南黄海北部盆地东北凹陷发育上白垩统泰州组主力烃源岩系,具有广阔的油气勘探前景.     

车镇凹陷套尔河洼陷地层超压成因机理

从超压成因机理研究的各种分析方法入手,依据压实不均衡、成烃及裂解成气作用两方面对车镇凹陷套尔河洼陷地层超压成因机理进行了研究.结果表明,泥岩声波时差及其对应的泥岩密度曲线表现为两段式演化,趋势线变化点在3 250 m附近.一方面从古近系沉积速率看,沙三期沉积中心的沉积速率高达450 m/Ma,可形成高幅度的异常高压,反映了压实不均衡作用对该地区地层超压的贡献作用;另一方面,套尔河洼陷地层超压分布范围与该地区生烃中心范围一致,且沙三中下段烃源岩的镜质体反射率Ro值在0.8%～1.1%之间,说明生烃作用对套尔河洼陷地区地层超压的发育亦具有一定的贡献.由此认为,压实不均衡和生烃作用是套尔河洼陷地区地层超压发育的主要机理.     

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。     

新疆北部石炭纪地层、岩相古地理与烃源岩

依据近几年新疆区域地质调查结果,结合新疆油田与吐哈油田最新勘探成果,通过区域构造背景和沉积充填演化特征推断石炭系沉积建造样式,理顺了新疆北疆地区石炭纪地层层序,目的是推断石炭纪烃源岩发育层段与主力生烃区范围。下石炭统有效烃源岩分布较广,主要发育于北疆西准噶尔达尔布特山前、博格达山前、准噶尔东部陆东—五彩湾地区早石炭世被动陆缘海相和海陆过渡相沉积盆地;上石炭统有效烃源岩分布相对局限,主要发育于东准噶尔克拉美丽山前石钱滩区、布尔津—吉木乃区及库普—三塘湖区海陆过渡相沉积盆地内。石炭系油气成藏严格遵循"源控论",有效生烃区决定其有效成藏范围,所伴随发育的火山岩体决定其富集程度。优选西准噶尔、东准噶尔、库普—三塘湖区、博格达山前区、布尔津—吉木乃区石炭系烃源岩发育区及其相邻构造带,作为今后石炭系油气勘探战略选区的重要领域和区带。     

基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

δ^13C-δ^18O Covariance： An Effective Indicator of Hydrological Closure for Lakes？

The correlation between theδ~(13)C andδ~(18)O in primary carbonates is affected by several factors such as hydrological balance,total CO_2 concentrations,climatic condition and lake productivity. The influence of these factors on theδ~(13)C-δ~(18)O correlation may be different on different time scales.In this paper,two different-type lakes in southwestern China,Lake Erhai and Lake Chenghai,are selected to investigate the influence of climatic pattern on theδ~(13)C-δ~(18)O correlation and to evaluate the reliability of theδ~(13)C-δ~(18)O covariance as an indicator of hydrological closure.The results show that there exists good correlation between theδ~(13)C andδ~(18)O in Lake Erhai (overflowing open lake) and in Lake Chenghai (closed lake).This suggests that theδ~(13)C-δ~(18)O covariance may be not an effective indicator of hydrological closure for lakes,especially on short time scales.On the one hand,a hydrologically open lake may display covariantδ~(13)C andδ~(18)O as a result of climatic influence.The particular alternate warm-dry and cold-wet climatic pattern in southwestern China may be the principal cause of theδ~(13)C-δ~(18)O covariance in Lake Erhai and Lake Chenghai.On the other hand,a hydrologically closed lake unnecessarily displays covariant trends betweenδ~(13)C andδ~(18)O because of the buffering effect of high CO_2 concentration on theδ~(13)C shift in byper-alkaline lakes.We should be prudent when we use the covariance betweenδ~(13)C andδ~(18)O to judge the hydrological closure of lake.     

川西坳陷中段天然气碳同位素特征及其成因类型

川西坳陷中段天然气的组份以烃类气体为主,占气体总体积的98.1%～99.7%;非烃气体以CO,2和N2为主,其含量分别占气体的0.12%～1.32%和0.25%～1.54%;烃类气体中以甲烷占绝对优势,平均含量为95.83%;重烃含量较低,平均为3.21%;干燥系数(C1/C,1-5>)平均为0.97,整体上属典型的干气.川西坳陷中段的所有样品δ13C,2都大于-25.8‰,属于典型的煤型气范畴,天然气的δ13C,1δ'13C,2δ13C,3,呈明显的正序排列,显示出天然气为典型的有机成因.甲烷碳同位素组成,反映了其母质演化程度已处于成熟～高成熟阶段,且以高成熟阶段为主.