Composition and pre-metamorphic geodynamic setting of the ultrahigh-pressure metabasic rocks from Dabie Shan,E-China

As part of the Yangtze plate, segments of the Dabie Shan terrane of Central China underwent ultra-high pressure metamorphism during Triassic subduction. We studied the geochemistry of the abundant eclogites to evaluate the nature of the protoliths and their geodynamic setting. Although some previous geochemical work exists, the analyses and interpretation herein are based on a new subdivision of the ultra-high pressure sequence into basement and cover units (Changpu and Ganghe Unit), revealing new and important results. In addition, eclogites of the so-called HP Unit south of the UHP units were studied. Whereas the large ion lithophile elements indicate postmagmatic, metasomatic changes of some samples, the high-field strength elements and the rare earth elements display original magmatic trends. The geochemical characteristics of the eclogites of the ultra-high pressure areas display a strong dependence on their “structural” and geographic position. The eclogites of the basement and the Changpu Unit indicate melt intrusion and extrusion in a continental rift system, i.e. during extensional tectonics. In contrast, the Ganghe Unit is characterized by a pronounced chemical homogeneity. The composition of the eclogites indicates generation from a mantle source highly influenced by slab-derived fluids. Those of the HP Unit show similar characteristics. Magmatism of the Ganghe and HP Unit probably occurred in a continental arc setting. A similar age for both units, geographically and/or tectonically separated, is possible. The geodynamic interpretation based on the geochemistry of the four units points to a Neoproterozoic scenario in which the protoliths of the HP and the cover units could have been of similar age and deposited in one evolving geological system. A rift-related larger-scale basin might have formed, e.g. a continental back-arc basin behind a magmatic arc after or simultaneous to sedimentation and magmatism in the magmatic arc. Alternatively, magmatism occurred in independent geodynamic settings, distinct in time and space. The units were juxtaposed during exhumation, after subduction to varying depths.     

快速城镇化进程中珠江三角洲高铵地下水赋存环境及驱动因素

地下水中高浓度的铵态氮对生活饮用水安全及生态环境存在潜在威胁。相比较硝态氮，高浓度的铵态氮不仅有各种人为来源，天然沉积环境更是造成高铵地下水的主要成因。本文以城镇化快速发展的珠江三角洲为研究区，运用数理统计、主成分分析等方法深入探讨了研究区高铵地下水的赋存环境特征及驱动因素。结果表明，研究区地下水中NH₄⁺质量浓度介于未检出~180 mg/L。研究区1539组地下水样品中，NH₄⁺质量浓度大于10 mg/L的高铵地下水69组，其中含NH₄⁺质量浓度大于30 mg/L的高铵"肥水"23组。对比2005-2008年历史水化学数据，2009-2018年新增建设用地孔隙含水层高铵地下水样品比例增加25%。高铵地下水呈斑块状分布于三角洲平原区第四系底部低洼的基底、洼地等退积层序发育的淤泥质含水层中。淤泥层等富含有机质和总有机碳的沉积层是珠江三角洲地区的"生铵层"，有机氮的矿化是三角洲平原区城市化孔隙含水层中高铵地下水的主要驱动力。城镇化扩张引起生活污水及富铵工业废水的泄漏入渗是城乡结合部高铵地下水铵氮的重要来源。三角洲平原区中性至弱碱性富含有机质的还原环境是高铵地下水的主要成因。风化溶滤、阳离子交换吸附、海陆交互作用是珠江三角洲高铵地下水质演变的主要水文地球化学过程。     

扬子地台前寒武纪－寒武纪界线地层的微体植物化石群

前寒武纪一寒武纪界线地层在扬子地台发育良好、分布广泛,并有包括微体植物群、海藻、瓶形原生物、具硬体动物及‘澄江动物群’等化石的发现。因而,扬子地台成为研究前寒武纪－寒武纪界线生物地层的代表地区之一。基于对扬子地台前寒武纪－寒武纪界线地层已知微体植物化石记录的回顾和论定,总结概括了下寒武统微体植物化石组合：寒武系最底部硅质磷块岩中的Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合和较高层位页岩的Ｓｋｉａｇｉａ－Ａｎｎｕｌｕｍ－Ａｒｃｈａｅｏｄｉｓｃｉｎａ组合。它们分别与Ａｎａｂａｒｉｔｅｓ－Ｃｉｒｃｏｔｈｅｃａ－Ｐｒｏｔｏｈｅｒｔｚｉｎａ小壳动物化石带和Ｐａｒａｂａｄｉｅｌｌａ及Ｅｏｒｅｄｌｉｃｈｉａ三叶虫带相对应。与东欧地台疑源类生物地层相对照,扬子地台Ｍｉｃｒｈｙｓｔｒｉｄｉｕｍ－Ｐａｒａｃｙｍａｔｉｏｓｐｈａｅｒａ－Ｍｅｇａｔｈｒｉｘ组合的纵向分布大体和东欧地台Ａｓｔｅｒｉｄｉｕｍｔｏｒｎａｔｕｍ－Ｃｏｍａｓｐｈａｅｒｉｄｉｕｍｖｅｌｖｅｔｕｍ组合带相一致,而以上两地台的化石组合产出层位可能都略高于纽芬兰东部剖面,依据Ｐｈｙｃｏｄｅｓｐｅｄｕｍ所厘定的寒武系底界?     

坡地农林复合系统的结构类型与效益分析─以长江三峡库区坡地农业为例

本义认为现代术语的农林复合系统来源于生产实践,体现了农业与林业的有机结合、品种生态和经济的有机结合、产品多样化以及管理科学化4个方面相统一的特点。文章在分析三峡库区农林复合系统的类型结构基础上,提出了农林复合系统可以进行层次结构划分的观点。最后,以典型案例研究方法入手,对1种农林结构类型进行效益分析,结果表明,采用植物篱农林复合坡地系统,是现阶段生产力水平下实现坡地生态经济协调发展的有效途径,值得广泛推广。     

基于泛珠三角的广东工业旅游探讨

基于建立泛珠三角的研究背景，通过对广州发展工业旅游的条件的分析得出结论，认为由于地缘关系和历史原因，在泛珠三角的成员中，广东最早接受香港地区的经济辐射，港澳台投资者在广东大量投资建厂，工业优势也日渐凸显，这种得天独厚的优势，为广东发展工业旅游奠定了坚实的基础。并通过对广东工业旅游示范点和其他适合发展工业旅游的企业进行调查分析和实证研究，总结了广东发展工业旅游的主要客源类型，并对广东工业旅游的发展提出了几点发展思路。工业与旅游相结合，两者完全可以达到双赢，并可以得到一定的社会效益，也是结论性认识。     

实施流域生态管理的长江中下游湿地保护探讨

长江中下游地区湿地分布广泛且类型多样,是我国淡水湖泊分布最集中和最具有代表性的地区。为了从根本上解决长江中下游湿地利用面临的问题,实现湿地资源的可持续利用,保护湿地环境,解决区内上、下游用水的供需矛盾,实现水资源的优化配置,调动区域湿地保护的积极性和主动性,有必要遵循湿地流域分布规律,应用流域生态学最新理论与实践成果,进行流域生态管理。一方面,要从流域角度处理好几大江湖关系、蓄泄关系、湖垸关系和山湖(河)关系等;另一方面,在流域内建立统一协调机制,对流域湿地进行保护与合理利用、合理布局和统一规划;同时在保护的前提下,科学合理地利用长江中下游湿地资源,开拓新的生产力。     

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.     

长江口水域多光谱遥感水深反演模型研究

利用Landsat-7 ETM 遥感影像反射率和实测水深值之间的相关性可以探测水深。该文介绍单波段、双波段比值和多波段3种线性回归模型以及动量BP人工神经网络水深反演模型。选择长江口北港河道上段作为研究区,利用上述模型,分两种情况进行水深反演:一是以河道全部历史样本建模;二是将河道按自然水深划分为浅水区和深水区分别建模。结果表明:神经网络模型预测精度高于线性回归模型;水深分区后线性回归和神经网络模型预测误差均有所减小。     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.