Neuzeitlicher Schadstofftrend: Polycylische aromatische Kohlenwasserstoffe (PAK) in aquatischen und terrestrischen Sedimenten

A Recent Contamination Trend: Polycylic Aromatic Hydrocarbons (PAHs) in Aquatic and Terrestrial Sediments Concentrations of polycylic aromatic hydrocarbons (PAHs) measured in aquatic sediments of small, medium‐sized or very large inland lakes, of estuaries as well as in terrestrial sediments from Germany, the UK, Finland, and the USA were plotted in 10 trend curves over the period from 1800 to 1990. The segments of the bore cores were dated for their deposition age. For comparability of the results, the trend is preferentially shown by the guide parameter fluoranthene. Until the 19th century, a constant background value of C_Fluo = 10…50 μg/kg was observed in all regions. Then a steep increase in concentration followed, reaching in the aquatic sediments a maximum in the period 1940 to 1965, while the individual fluoranthene values ranged widely from 90 to 2400 μg/kg. In several regions, a more or less distinct decrease superseded this maximum, although this development did not appear in terrestrial sediments, in one estuary, and in remote forest lakes in Finland. The trend curves reflect the atmospheric deposition of PAHs in airborne dust and in some cases the import through runoff via rivers. Thus, the sediment profiles depict the development of air pollution by pyrogenic contaminants over more than a century. Sediment profiles from rivers can be used only with a high degree of reservation, because of the irregularity and low representativity of the sedimentation.     

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.     

中国北方两种现代草地动物牙齿珐琅质δ~(13)C值与植被类型的关系初探

在简单了解研究区的植被、气候状况的基础上 ,分析了内蒙古锡林郭勒和青海海北两种典型草地食草动物牙齿的δ1 3C值 ,测定了采样点表土有机质的δ1 3C值。锡林郭勒的表土有机质碳同位素组成略分散 ,且与植被和微环境密切相关。海北的表层土壤有机质碳同位素组成比较集中。两地的碳同位素组成都偏轻 ,是植被中C4植物含量少的反映。两地放牧动物的珐琅质δ1 3C值分别比当地植物偏重 12 .9‰和 13.5‰ ,或 14 .1‰和 14 .7‰。火灾等高温过程对动物牙齿的碳同位素组成可能没有显著影响     

使用Intel编译器优化中尺度模式MM5在奔腾4上的运行

本文介绍了一种在奔腾4处理器微机上Linux操作系统下的优化编译方法。作者通过查询、试验发现：使用Intel编译器优化中尺度模式MM5，能够使得MM5在奔腾4上的运行速度提高1．4～1．5倍。利用Intel编译器优化后的MM5模式，进行了三个月资料的计算，模式运行稳定。给出了一个使用Intel编译器和通常使用的PGI编译器分别编译的计算实例，对比表明：使用Intel编译器明显提高了运算速度，两种编译方法预报的降水场和形势场没有太大差异。     

震级加权四指标Blade算法及在地震带识别中的应用

Blade算法的产生是根据地震点的分布寻找地震断层，其优势在于能从较稀疏的点分布中找出线型条带模式，但不足的是完全不考虑地震的震级屑性。针对Blade算法的几个不足之处逐步改进，提出了震级加权四指标Blade算法。算法主要的改进体现在：①引入以震级为变量的权重函数，体现了高震级地震的控制作用，通过模拟与实例比较了三种权重函数的效果；②改进原方法中所挑出的Blade中心必须有地震点，引入四指标评价体系代替原方法的二指标评价体系，同时还根据指标值将挑选出的线型条带修正到更淮确的位置。将原算法与改进算法应用于华北地区4级以上的地震数据集以按寻地震带，结果表明，震级加权四指标Blade算法较Blade算法有显改进，取得了较好的应用效果。     

Photochemistry of N2O4 Adsorbed on Ice Surfaces at 193 nm

A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO₂ was adsorbed as N₂O₄ approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO₂, NO, O₂ and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO₂, NO and O₂ were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO₂ was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N₂O₄. NO was supposed to be a predissociation product from the electronically excited NO₂ prepared through the photodissociation of N₂O₄.     

二维波动方程约束反演的大范围收敛广义脉冲谱方法

针对二维波动方程，将大范围收敛的同伦 方法引入算子参数识别反演的过程，并结合求解不适定问题的Tikhonov正则化方法，设计了二维波动方程反演的大范围收敛广义脉冲谱方法，并利用测井资料进行了约束反演. 大量 的数值模拟结果以及抗噪实验均表明了方法的有效性.     

地震勘探中的炸药震源药量理论与实验分析

炸药由于具有良好的脉冲特性及高能量的特点而作为地震勘探中的主要震源，就炸药本身来说，在地震勘探中药量、井深等参数的选取对激发能量和激发频率有很大的影响。为此，本文运用炸药爆炸理论，从炸药作功角度来加以论述，并通过理论和实验分析得出选取一个最佳的药量和井深激发，既能提高炸药作功能力，又能增强激发能量，从而激发强能量的高频震源子波，达到指导野外地震采集和节约经济成本的目的。     

禾青井动水位对断层蠕动与慢地震过程的响应初析

以湖南禾青井深井水位观测的异常图象为例进行定性分析，发现动水位观测有可能直接反映出断层的滑动或断层的慢地震过程，前者可能为地下水物理参量的观测与研究提供亲折思路，后者则可能对震源物理学的发展和地震预报水平的提高具有特殊的意义。     

北京顺义4.0级地震板桥井水位异常特征

着重介绍了北京顺义４．０级地震前后板桥井水位的异常特征，并通过对板桥井二次异常的对比分析研究，提出井水位异常时间尺度与震级之间的可能关系。