水化学指标表示裘布依公式的应用

从多矿物溶解化学动力学方程出发,推演并建立了由水化学指标表示的承压二维井流裘布依公式。结合水文地质、水文地球化学特征,列举了水文地质单元内不同区带、各种代表性矿物及相应组分化学指标的基本表达式。以山西省太原西峪煤矿所需解决的水文地质问题为例进行了定量研究与评价,其结果与已有的抽水试验资料接近,为矿井涌水量的评价开辟了一条新的道路。从事实上进一步论证了水化学指标表示裘布依公式的理论概括是正确的。     

电子探针化学测年方法

介绍含Th U Pb矿物电子探针化学测年方法的基本原理 ,并利用应用实例说明该方法在研究岩石形成年龄、构造热事件年代等方面的重要作用 ,最后简要评价该方法的优、缺点 ,并指出它的应用前景 ,认为电子探针化学测年方法将有可能在深源岩石包体年龄研究、含放射性元素矿床形成年代研究等方面大有作为 ,并使地质年代学研究更加精细化 ,有助于深入探讨复杂地质事件及其演化历程。     

大兴安岭阿龙山地区流纹岩风化的地球化学特征

通过大兴安岭地区两个流纹岩风化剖面的研究发现，大兴安岭地区的岩石风化过程具有特殊性。风化过程分为两个阶段，即以化学风化为主导的基质风化阶段和以机械风化为主导的斑晶风化阶段，第二阶段显示出与正常风化剖面相反的风化趋势。低温和长冬使第二风化阶段延长，并呈现逆风化趋势。风化过程中Fe和Al始终处于流失状态。上述特征的产生是由原岩的结构及成分、气候因素和生态系统等多种因素作用的结果。     

煤岩显微组分热解气相色谱特征与化学结构剖析

煤结构是目前地球化学研究领域中的一个难点，但却具有极其重要的理论及实际意义，本文采用分步热解气相色谱技术将树皮体，镜质体和丝质体分解为分子量较小的可测定的有机化合物，在此基础上，据不同温度下热解产物的组成特征来还原显微组分的化学结构，实验结果表明，煤显微组分主要由四大类官能团组成，一是热稳定性较低的NOS杂原子官能团；二是脂族（脂链、脂环）结构；三是苯、烷基苯（甲苯、二甲苯）、萘等芳香族化合物，四是热稳定性很高的难以分解的稠环芳烃。上述四类化合物集中于显微组分的不同结构简单中，树皮体和镜质体结构单元外侧主要由热稳定性较低的杂原子化合物以及分子量较小的苯和烷基苯组成，而丝质体结构单元外侧则主要以短链脂族结构为主，三组分结构核部由热稳定性很高的难以分解的稠环芳烃组成。连结核部稠环芳烃与结构单元外侧杂原子等官能团的主要是热稳定性较高的脂链结构，煤显微组分热成烃主要按结构中各官能团键的强弱随热演化程度的加深依次脱除，生成油气，基本上属平行独立依次反应机制，亦“官能团脱除型”，此外，还包括少量的长链脂族结构裂解为短链脂肪烃的“解聚”过程。     

A Linear Programming Approach to Determine the Normative Composition of Sedimentary Rocks

The analysis of modal and normative composition of sedimentary rocks is widely used for studying their sources and tectonic settings. The normative calculation of the mineral composition of rocks in this study is formulated as a linear programming problem and is solved by means of the simplex method. This enables both simultaneous and successive subtraction of a set of basic minerals from a rock sample represented by its chemical composition {SiO₂...LOI}. Such an approach provides a more exact calculation of the contribution of basic minerals in the rock. This mathematical approach is used to study two representative sets of sandstones and fine-grained rocks from a Meso- to Neoproterozoic marginal basin of southeastern Siberia (Uchur–Maya region, Yakutia) and a Pennsylvanian-Lower Permian uplifted continental block in Colorado, USA. The calculated normative mineral compositions of the Siberian sandstones are consistent with the observed modal compositions. These sandstones vary from K- Feldspar rich arkoses at the base of the sequence (the Uchur Group, lower Riphean) to quartz arenites or lithic sandstones and wacke in transgressive successions of the middle-upper Riphean. Arkoses and quartz arenites are dominant in Meso- to Neoproterozoic Siberia. These samples represent craton interior uplifted basement and quartzose, recycled orogen provenance of a stable craton in Rodinia. There are higher but consistent discrepancies between the calculated and observed compositions for the Pennsylvanian to Lower-Permian arkoses and quartz arenites (Sangre de Cristo, Belden, and Maroon Formations). The differences between the predicted and observed mineralogy may be due to uncertainties in the modes in the matrix and cement of the sandstones. This normative program should supplement modal calculations and provide better genetic constructions, especially in case of matrix-rich sandstones.     

止水帷幕在高层建筑深基坑中的应用

某高层建筑基坑西侧紧邻一道河沟,水量较大,采取三重管高压摆喷帷幕止水[1～4],施工完成后通过监测,未发现渗漏、地下水位明显下降和周围建筑物沉降现象。     

Rivers, chemical weathering and Earth's climate

We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO₂ and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO₂ through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO₂ as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).     

杭州市化工园区选址的气象环境与评估的数值模拟研究

城市化是国家社会发展的必然趋势，为了在新一轮城市总体规划中能保证杭州市的大气环境质量，优化不同空间尺度的城市规划，协调城市发展与保护环境的关系，本文利用一个三维非静力区域边界层数值模式，对一些典型天气条件下杭州地区的风场和气温的空间分布特征进行模拟分析，并以此为依据，给出选取化工园区的位置的评估意见。模拟结果表明，化工园区的选址宜考虑在杭州市的西南方向。     

地下气体运移变化的物理化学机制研究

在河北省怀来县后郝窑地区，对地下气体运移变化的影响因素进行了野外模拟实验研究。选择３个试验点，对地下气体的扩散作用，物理化学影响因素及水压效应等进行了模拟实验，主要研究Ｈ２，ＣＯ２气体运移变化机制。实验研究表明，Ｈ２，ＣＯ２气体运移变化机制不尽相同，水压效应对Ｈ２，ＣＯ２等地下气体运移影响相当明显     

Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.