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61.
Mohamed M. Hantush Rao. S. Govindaraju Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74
This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills. 相似文献
62.
Pierre Hudon In-Ho Jung Don R. Baker 《Physics of the Earth and Planetary Interiors》2002,130(3-4):159-174
Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively. 相似文献
63.
64.
The effect of scattering in surface wave tomography 总被引:6,自引:1,他引:6
Jesper Spetzler Jeannot Trampert Roel Snieder 《Geophysical Journal International》2002,149(3):755-767
65.
大洋多金属结核中1nm锰矿相的相变及其主要控制因素研究 总被引:1,自引:3,他引:1
多金属结核样品在室温中放置或加热干燥后 ,其中的 1nm锰矿相会部分或全部地相变为 0 7nm锰矿相 ,这说明 0 7nm锰矿相可能不是多金属结核的原生锰矿相 ,而仅仅是 1nm锰矿相的相变产物。研究结果表明 :1nm锰矿相结构中的Cu2 + 、Co2 + 、Ni2 + 等金属阳离子的含量与其结构稳定性有正相关关系 ,即金属离子含量越高 ,其结构越稳定 ,1nm锰矿相越不易相变为 0 7nm锰矿相 ,反之亦然 ;另外 ,不同金属阳离子稳定 1nm锰矿相结构的能力也不同 ,结核中几种主要金属阳离子对 1nm锰矿相结构的稳定能力从大到小为 :Ni2 + >Cu2 + >Co2 + >Zn2 + >Ca2 + =Mg2 + 。 相似文献
66.
湖北省南漳县震旦系沉积型红星磷矿矿体P_2O_5平均含量23.91%,矿石自然类型主要为角砾状磷块岩,其次为白云质磷块岩、泥质纹层状和条带状致密块状磷块岩。工业类型主要为钙(镁)质和硅钙(镁)质磷矿,其次为硅质磷矿。矿石矿物为胶状磷灰石和微晶磷灰石,经x-射线衍射物相分析,其种属为含碳氟磷灰石。嵌布粒度以细-中粒为主。脉石矿物主要为白云石、伊利石、高岭石、铁质。经测定当磷块岩磨矿粒度小于0.1mm,其磷酸盐矿物单体解离率可达92.53%,这为确定合理的选矿流程具有实际意义。 相似文献
67.
68.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established. 相似文献
69.
Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions. 相似文献
70.
Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence. 相似文献