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41.
42.
吹扫-捕集气相色谱法测定海水中挥发性卤代烃 总被引:6,自引:0,他引:6
挥发性卤代烃(VHC)是大气中的痕量气体,对臭氧层损耗和温室效应有重要作用。海洋是大气中VHC的主要自然排放源,开展海洋VHC的研究有助于了解海洋对大气VHC和全球变暖的贡献。本文建立了吹扫-捕集与气相色谱-微池电子捕获检测器联用技术(P-T-GC-(ECD)分析海水中6种VHC的方法,确定了吹扫-捕集条件和气相色谱分离条件。该方法的检测限在0.003~0.369 ng.L-1之间;相对标准偏差是1.83~3.97;加标回收率为98.1%~110.2%;相关系数在0.997 3~0.999 8之间。可准确地测定海水中6种VHC。 相似文献
43.
A Reconstruction of Observed Profiles in the Sea East of Japan Using Vertical Coupled Temperature-Salinity EOF Modes 总被引:4,自引:0,他引:4
It is important to estimate hard-to-observe parameters in the ocean interior from easy-to-observe parameters. This study therefore
demostrates a reconstruction of observed temperature and salinity profiles of the sea east of Japan (30°≈40°N, 140°≈150°E).
The reconstruction was done by estimating suboptimal state from several values of the observed profiles and/or sea surface
dynamic height (SDH) calculated from the profiles. The estimation used a variational method with vertical coupled temperature-salinity
empirical orthogonal function (EOF) modes. Profiles of temperature and salinity in the subtropical region are effectively
reconstructed from in situ temperature profile data, or sea surface temperature (SST) and SDH. For example, the analyzed temperature field from SST
and SDH has an accuracy to within 1°C in the subtropical region. Salinity in the sea north of Kuroshio, however, is difficult
to estimate because of its complex variability which is less correlated with temperature than in the subtropical region. Sea
surface salinity is useful to estimate the subsurface structure. We also show the possibility that the estimation is improved
by considering nonlinearity in the equation calculating SDH from temperature and salinity analysis values in order to examine
the misfit between analysis and observation. Analysis using TOPEX/POSEIDON altimetry data instead of SDH was also performed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
44.
Yosuke Fujii 《Journal of Oceanography》2005,61(1):167-181
I present the derivation of the Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar), which is developed for adopting a non-diagonal background error covariance matrix in nonlinear variational analyses (i.e., analyses employing a non-quadratic cost function). POpULar is based on the idea of a linear preconditioned conjugate gradient method widely adopted in ocean data assimilation systems. POpULar uses the background error covariance matrix as a preconditioner without any decomposition of the matrix. This preconditioning accelerates the convergence. Moreover, the inverse of the matrix is not required. POpULar therefore allows us easily to handle the correlations among deviations of control variables (i.e., the variables which will be analyzed) from their background in nonlinear problems. In order to demonstrate the usefulness of POpULar, we illustrate two effects which are often neglected in studies of ocean data assimilation before. One is the effect of correlations among the deviations of control variables in an adjoint analysis. The other is the nonlinear effect of sea surface dynamic height calculation required when sea surface height observation is employed in a three-dimensional ocean analysis. As the results, these effects are not so small to neglect. 相似文献
45.
State Estimation of the North Pacific Ocean by a Four-Dimensional Variational Data Assimilation Experiment 总被引:1,自引:0,他引:1
Toshiyuki Awaji Shuhei Masuda Yoichi Ishikawa Nozomi Sugiura Takahiro Toyoda Tomohiro Nakamura 《Journal of Oceanography》2003,59(6):931-943
A four-dimensional variational data assimilation system has been applied to an experiment to describe the dynamic state of
the North Pacific Ocean. A synthesis of available observational records and a sophisticated ocean general circulation model
produces a dynamically consistent dataset, which, in contrast to the nudging approach, provides realistic features of the
seasonally-varying ocean circulation with no artificial sources/sinks for temperature and salinity fields. This new dataset
enables us to estimate heat and water mass transports in addition to the qualification of water mass formation and movement
processes. A sensitivity experiment on our assimilation system reveals that the origin of the North Pacific Intermediate Water
can be traced back to the Sea of Okhotsk and the Bering Sea in the subarctic region and to the subtropical Kuroshio region
further south. These results demonstrate that our data assimilation system is a very powerful tool for the identification
and characterization of ocean variabilities and for our understanding of the dynamic state of ocean circulation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
46.
The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems. 相似文献
47.
48.
厦门文昌鱼人工繁育批量生产技术研究 总被引:3,自引:0,他引:3
2005年5月21日至7月6日从厦门市翔安区欧厝附近海域采集文昌鱼亲体6批共计550余尾,移入室内进行强化培育.7月16日和17日夜间,培育的亲体自然排放精卵并受精,共获得受精卵125万粒.受精卵孵化获得浮游幼体115万尾,孵化率达92.0%.孵化的幼体经25d较高密度人工培育,获得99.2万尾体长0.31~0.72cm的文昌鱼苗及未成苗浮游幼体;分苗疏养后,又经28d继续培育,存活的幼体几乎全部潜入沙层中,最终获得体长0.55~1.30cm的厦门文昌鱼潜沙苗23.2万尾,其53d育苗成活率达20.7%.这是国内外首次人工培育获得成批量的文昌鱼增养殖苗种.进而于2005年11月6日向厦门文昌鱼自然保护区实施了国内外首次的文昌鱼资源人工增殖放流. 相似文献
49.
Alessandro Buccolieri Giovanni Buccolieri Nicola Cardellicchio Angelo Dell'Atti Antonella Di Leo Antonella Maci 《Marine Chemistry》2006,99(1-4):227
Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments. 相似文献
50.