Static Stability of the Troposphere Over the Southeastern Beaufort Sea–Amundsen Gulf Region of the Western Maritime Arctic

The characterization of the static stability of the troposphere over the western maritime Arctic remains limited in spite of its significance to both atmospheric thermodynamics and dynamics. Field observations of microwave radiometric temperature profiles from the International Polar Year, Circumpolar Flaw Lead System Study (late November 2007 to mid-July 2008) and the ArcticNet field campaign (mid-July to early November 2009) provided a unique opportunity to characterize the static stability of the troposphere over the southeastern Beaufort Sea–Amundsen Gulf region. Notably, the monthly median atmospheric boundary layer (<2000?m) static stability profile for April and the profile for May clearly revealed an inversion elevated above a thermal internal boundary layer, whereas the median summer static stability profiles had very strong surface-based inversions. These profiles have been linked to the seasonal evolution of sea-ice cover in Amundsen Gulf. The monthly static stability profiles for the free atmosphere (2000–10,000?m) revealed an annual cycle. The average static stability of the lower troposphere (2000–5000?m) had a minimum of 3.3?±?0.5?K?km^?1 in July and a maximum of 4.5?±?0.5?K?km^?1 in January and February. In the upper troposphere (>5000–8000?m), the average static stability had a minimum of 2.9?±?0.6?K?km^?1 in June and August and a maximum of 5.3?±?0.8?K?km^?1 in January. The monthly median heights of the tropopause also had an annual cycle. The maximum of 9750?m occurred in June, July, and August. The minimum tropopause height of 8000?m occurred in December, January, and March. The seasonal cycles of static stability in the free atmosphere and the seasonal cycle in the height of the tropopause can be attributed to regional as well as synoptic-scale forcing. This analysis will contribute to the understanding of the thermodynamics and dynamics of a data-sparse region of the Arctic by providing a “snapshot” of the state of the atmosphere through a composite annual cycle.     

Teleconnection of IOD signal in the upper troposphere over southern high latitudes

Evidence has been found for the teleconnection of Indian Ocean Dipole mode (IOD) events in the southern high latitude sea surface pressure field, although the mechanisms that might lead to such far-reaching links remain unresolved. Based on the teleconnection pattern between IOD and the climate anomaly in the upper troposphere, we propose one such mechanism here: the energy propagation theory of the atmospheric planetary wave. Ray traces of the atmospheric planetary waves suggest that the energy propagation of the waves could be responsible for the teleconnection between IOD and tropospheric climate anomalies in southern high latitudes.     

Monitoring Measurements from the Jason-1 Microwave Radiometer and Independent Validation with GPS

The Jason-1 Microwave Radiometer (JMR) provides measurements of the wet troposphere content to correct the altimetric range measurement for the associated path delay. Various techniques are used to monitor the JMR wet troposphere path delays, with measurements of zenith troposphere content from terrestrial GPS sites used as an independent verification technique. Results indicate that an unexpected offset of approximately +4.1 ± 1.2 mm (drier) emerged in the JMR measurements of wet path delay between cycles 28-32 of the Jason-1 mission, and that the measurements may be drifting at a rate of approximately -0.5 mm/year. These anomalies are shown to be caused by a -0.7 K offset in 23.8 GHz brightness temperatures between cycles 28-32, and a 0.16 ± 0.04 and -0.45 ± 0.08 K/year drift in the 18.7 and 34.0 GHz brightness temperatures, respectively. Intercomparison of the 3-Hz JMR brightness temperature measurements show that they have been drifting with respect to each other, and that a dependence on yaw-steering regime is present in these measurements. An offset of 0.5 m/s between cycles 28-32 and a drift of approximately 0.5 m/s/year in the JMR wind speed measurements is also associated with these anomalies in the 1-Hz brightness temperatures. These errors in JMR wind speeds presently have a negligible impact on the retrieved JMR path delays.     

卫星资料揭示的青藏高原对流层上层温度气候演变趋势特征

利用1982—2016年MSU/AMSU-A亮温资料,分析了青藏高原地区对流层上层温度的气候趋势及其演变特征,并利用ERA-Interim和NCEP-R2再分析资料的相应高度大气温度资料进行了对比分析。结果表明,青藏高原地区对流层高层卫星亮温资料总体表现为逐渐增暖现象,这与再分析资料的对应层次大气温度变化有很好的相似性。基于集合经验模式分解方法 EEMD的非线性趋势分析表明,青藏高原地区对流层上层亮温的增温首先出现在青藏高原中部,随着时间演变,增温现象逐渐向青藏高原四周扩散,最后在整个青藏高原地区都出现了一致增温现象。相比于NCEP-R2再分析资料而言,ERA-Interim再分析资料300 h Pa大气温度的演变趋势与观测亮温有很好的相似性,只是增温现象是首先在青藏高原附近,随着时间推移,增温现象逐步向周边地区扩张,最终整个青藏高原地区出现了整体升温现象。但是NCEP-R2再分析资料则是与上述两种资料的温度演变特征有很大的差异,其300 h Pa高度大气温度在前20年表现为明显的降温特征,在最近10年才出现了增温,并逐步向周边地区扩张的现象。     

Reduction of a Model Describing Ozone Oscillations in the Troposphere: Example of an Algorithmic Approach to Model Reduction in Atmospheric Chemistry

We consider a simplified reaction mechanism from tropospheric chemistryconsisting ofsix chemical species involved in ten dynamic processes. The concentrations of all six speciesundergo temporal oscillation for some parameter values. An asymptoticapproach to reduction of the original six-variable model to a four-variable version is considered together with detailed explanation of the procedure as well as discussion of conditions under whichthe reduction is possible. The reduced system nearly quantitatively represents the oscillating behavior of thefull model and allows elucidation of its basic dynamical features. This approach also can be used to compare various small models of atmospheric chemistry, and to determine their underlying dynamic structure. The method can be systematically appliedto larger atmospheric models.     

大涡模拟模式研究对流层湍流

利用三维大涡模拟模式研究不同地面热力状况和风切变对湍流产生的影响，在对流层湍流发展过程中，这两种作用是同时存在的、同时起作用，水平风速的瞬时垂直切变可以在自由大气中激发湍流，但它不能维持很长时间，对流热泡也可以在自由大气中激发湍流，其湍流强度与地面的热量强度有关。     

The distribution of acetaldehyde in the lower troposphere during TROPOZ II

A series of 72 measurements of the acetaldehyde (CH₃CHO) mixing ratio were made in the lower troposphere during TROPOZ II. These measurements are the first ever made of the background level of this trace gas in the free troposphere. The data show a vertical decrease of the CH₃CHO mixing ratio with increasing altitude and indicate higher CH₃CHO concentrations in the Northern Hemisphere — in general agreement with a model-derived average CH₃CHO distribution. Deviations of the observed CH₃CHO mixing ratios from the modelled mean distribution are correlated with similar deviations in the corresponding HCHO mixing ratios.     

Atmospheric concentrations and deposition of heavy metals over the North Sea: A literature review

A literature review of the atmospheric concentration rates and dry and wet deposition fluxes of particulate Cd, Cr, Cu, Pb and Zn to the North Sea and adjacent areas is given. The results of direct measurements of dry and wet deposition fluxes are compared to indirect estimates and to modelling values. This work points out the large uncertainties in results of different studies on atmospheric input of trace elements into the North Sea. The current knowledge about the dependence of the deposition velocity upon the particle size and about the processes controlling wet deposition fluxes, and the quality and completeness of the emission data are still inadequate for describing the environmental cycle and impact of heavy metals in the North Sea.     

Hydroperoxides in the marine troposphere over the Atlantic Ocean

Hydrogen peroxide (H₂O₂) and organic hydroperoxides (ROOH) were measured on board of theRV Polarstern during its cruise across the Atlantic Ocean from 20 October to 12 November 1990 (54° N to 51° S latitude) by the enzyme fluorometric method. The H₂O₂ mixing ratio varied from below the detection limit of about 0.12 ppbv up to 3.89 ppbv, showing a latitudinal dependence with generally higher values around the equator and decreasing values poleward. The shape of the latitudinal H₂O₂ distribution agrees well with an analytical steady state expression for H₂O₂ using the measured H₂O and O₃ distribution and a wind dependent H₂O₂ deposition rate. The ROOH mixing ratio varied from below the detection limit of about 0.08 ppbv up to 1.25 ppbv with qualitatively the same latitudinal dependence as H₂O₂. The observed ratio ROOH/(ROOH + H₂O₂) varied between 0.17 and 0.98 showing higher values at the lowest H₂O₂ mixing ratios at high latitudes. The measured H₂O₂ mixing ratio shows a significant diurnal variation with a maximum around 14:00 local time, explicable by a superposition of the photochemical H₂O₂ production with a constant H₂O₂ deposition rate. Four independent estimations of the average effective H₂O₂ deposition rate inferred from the H₂O₂ decrease in the night, from the midday H₂O₂ production deficit (as derived from comparison with a photochemical model and from the daily ozone loss), and from the offset in the latitudinal H₂O₂ distribution, were consistent. An episode of maximum H₂O₂ concentration suggests the possibility of its formation in clouds.     

Size-Resolved Characterisation of Soluble Ions in the Particles in the Tropospheric Plume of Masaya Volcano, Nicaragua: Origins and Plume Processing

We present the first application of a multi-stage impactor to study volcanic particle emissions to the troposphere from Masaya volcano, Nicaragua. Concentrations of soluble SO₄ ^2–,Cl^–, F^–, NO₃ ^–, K⁺, Na⁺,NH₄ ⁺, Ca²⁺ and Mg²⁺ were determined in 11 size bins from 0.07 m to >25.5 m. The near-source size distributions showed major modes at 0.5m (SO₄ ^2–, H⁺,NH₄ ⁺); 0.2 m and 5.0 m (Cl^–) and 2.0–5.0 m(F^–). K⁺ and Na⁺ mirrored the SO₄ ^2– size-resolvedconcentrations closely, suggesting that these were transported primarily asK₂SO₄ and Na₂SO₄ in acidic solution, while Mg²⁺ andCa²⁺ presented modes in both <1 m and >1 m particles. Changes in relative humidity were studied by comparing daytime (transparent plume) and night-time (condensed plume) results. Enhanced particle growth rates were observed in the night-time plume as well as preferential scavenging of soluble gases, such as HCl, by condensed water. Neutralisation of the acidic aerosol by background ammonia was observed at the crater rim and to a greater extent approximately 15 km downwind of the active crater. We report measurements of re-suspended near-source volcanic dust, which may form a component of the plume downwind. Elevated levels ofSO₄ ^2–, Cl^–, F^–,H⁺, Na⁺, K⁺ and Mg²⁺ were observed around the 10 m particle diameter in this dust. The volcanic SO₄ ^2– flux leaving the craterwas 0.07 kg s^–1.