Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.     

塔里木北缘库鲁克塔格地区新元古代花岗岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义

采用LA-ICP-MS法分析了塔里木北缘库鲁克塔格一带二长花岗岩锆石U-Pb年龄,获得该二长花岗岩岩体的年龄为(832.3±3.3)Ma(MSWD=2.8,n=24)。岩石地球化学特征显示,二长花岗岩属于准铝质高钾钙碱性系列,为I型花岗岩。微量元素富集大离子亲石元素(LILE)Ba、K、Sr、U等,亏损高场强元素(HFSE)Nb、Ta、Ti、P等;稀土元素总体含量较低(29.88×10^-6~63.57×10^-6),具有弱Eu正异常(δEu=0.87~1.39),整体配分模式与下地壳一致。结合区域地质背景对岩浆岩地球化学特征进行综合分析,认为二长花岗岩形成于岛弧环境。区域构造演化特征指示832 Ma该区洋壳已经开始俯冲,使得这一地区的地壳加厚,同时地幔柱的上涌加热作用导致古老地壳物质发生部分熔融而形成该期花岗岩。     

超大超深灌注桩施工关键技术研究与应用

以深圳某项目桩基础施工为依托,综合考虑地质特点和施工工艺要求,对超大超深灌注桩在花岗岩地层施工开展了相关研究,并将研究成果应用到实际施工中,有效地解决了该类型桩基础施工中的难点,保证了项目的顺利实施,为后续类似项目提供了参考依据。     

浙中一次多风暴类型强对流天气成因及多普勒雷达特征

利用常规资料、区域自动站加密资料、探空资料、GFS 0.25°×0.25°逐6h的分析场数据和SB多普勒天气雷达资料对2018年5月18日发生在浙中地区的一次强对流天气过程进行分析。结果表明:此次过程产生了脉冲风暴、中等到强多单体风暴和飑线这3种风暴类型,分别出现冰雹、大范围强降水和雷雨大风等强天气。3种风暴的雷达回波在回波形态、强度、垂直结构、平均径向速度、垂直累积液态水含量VIL等特征如下:①脉冲风暴呈块状,初始回波高度在6～9km,强回波所在高度在-10℃等温线附近,强回波值达60dBz以上,VIL值出现跃升且最大值在50kg·m-2以上,冰雹出现在反射率因子核和VIL值迅速下降之后;②中等到强多单体风暴呈带状,大降水效率和"列车效应"是发生大范围强降水的主要原因,雷雨大风天气则与反射率因子核迅速下降、MARC、低层强辐散区有关;③飑线呈弓形回波形态,移速快,引起了大范围的雷雨大风天气。此次过程影响系统多,天气复杂,存在较大预报难点,在短时临近预报技术研究上有重要借鉴意义。     

Effect of slow-solvent-vapour treatment on performance of polymer photovoltaic devices

In this work, enhanced poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) bulk-heterojunction photovoltaic devices are achieved via slow-solvent-vapour treatment. The correlations between the morphology of the active layer and the photovoltaic performance of polymer-based solar cell are investigated. The active layers are characterized by atomic force microscopy and optical absorption. The results show that slow-solvent-vapour treatment can induce P3HT self-organization into an ordered structure, leading to the enhanced absorption and efficient charge transport.     

Development and characterization of a cell line from the embryos of half smooth tongue sole (Cynoglossus semilaevis)

A new cell line,CSEC,has been successfully established from embryos at gastrula stage of a cultured marine fish,half smooth tongue sole(Cynoglossus semilaevis).CSEC cells grow actively and stably more than 50 passages for over 200 d in DMEM medium supplemented with 15% FBS(fetal bovine serum),2.5 ng/cm 3 bFGF(basic fibroblast growth factor),1 ng/cm 3 LIF(leukemia inhibitory factor) and 50 mmol/dm 3 2-ME(2-mecaptoethanol).The cells grew well in the temperature range of 24-30 ℃ and the optimal growth temperature was 24℃.FBS and bFGF concentrations are the two key components for CSEC cells proliferation.Chromosome analysis reveals that CSEC cells have a normal diploid karyotype with 2n=42t.The significant fluorescent signals were observed in CSEC after transfection with the GFP reporter gene,suggesting that the CSEC cell line can be used as a useful tool for transgenic and genetic manipulation studies.CSEC cells showed the cytopathic effect(CPE) after infection with lymphosystis disease virus(LCDV) in 2 d.Moreover,the LCDV particles can be observed in the cytoplasm of virus-infected cells by electron microscopy.It suggests that CSEC could be potentially used for the study of aquatic virus.     

Stable 85Rb micro vapour cells: fabrication based on anodic bonding and application in chip-scale atomic clocks

We describe the microfabrication of ⁸⁵Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions, the pure metallic Rb drops and buffer gases were obtained in the cells with a few mm³ internal volumes during the cell sealing process. At an ambient temperature of 90 ℃ the optical absorption resonance of ⁸⁵Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 kHz, have been detected. The sealing quality and the stability of the cells have also been demonstrated experimentally by using the helium leaking detection and the after-9-month optoelectronics measurement which shows a similar CPT signal as its original status. In addition, the physics package of chip-scale atomic clock (CSAC) based on the cell was realized. The measured frequency stability of the physics package can reach to 2.1×10^-10 at one second when the cell was heated to 100 ℃ which proved that the cell has the quality to be used in portable and battery-operated devices.     

陕西金堆城花岗岩类主要造岩矿物特征及其岩石学意义

本文依据大量测试数据,对金堆城地区花岗岩类主要造岩矿物学特征同钼迁移富集成矿关系进行了探讨。研究结果表明:异常晶胞条纹长石和正长石以及富重稀土和具明显负铕异常的黑云母是含钼花岗岩类标型矿物,并且可作为花岗岩类岩石发育地区寻找隐伏钼矿体的指示性矿物。钾钠长石和斜长石的结构状态和成分不仅可以提供有关花岗岩类成因演化的信息,其矿物本身亦可成为钼的载体矿物。岩浆期后,强烈的热液蚀变作用可造成钾钠长石和斜长石分解,并且引起钼的释放,从而形成高品位钼矿石。     

自然金—银类质同象系列矿物晶胞参数变化规律及其表述方程

本文提出了自然金-银类质同象系列矿物的晶胞参数与金、银原子数百分比成二次函数关系,推导出了表示二者之间函数关系的方程式。利用该方程式,可以用金原子数百分比计算出晶胞参数,反之亦然。并且从金、银二者的电负性出发,对a值的变化作了解释。