ICP-MS测定生物样品中的微量金属元素

采用SP-60型恒压消解罐消解生物样品,用ICP-MS测定8种金属元素(Mn、Zn、Pb、La、Ce、Mo、Cr和Fe)的质量分数。依据分析结果,比较了消解程序的效果。结果表明,由10.0 mLHNO3对生物样品具有很好的消解能力,各元素的测定值与推荐值相符。     

水下收缩裂隙形成过程及裂缝充填模式研究

通过野外实地考察测试,对水下收缩裂隙整体形成过程、裂隙内充填物沉积模式、影响因素等进行了详细讨论,并且建立了相应的地质理论模型。水下收缩裂隙的形成共分4个阶段,依次为:泥水混合物进入低洼地带的初始混浊状态;沉积压实稳定阶段;水位线下降,盐度增大,裂隙形成阶段;沉积裂隙充填阶段。其中“异常高压作用”,对于初始裂隙的形成、沉积物孔隙水的有效排出以及主要渗流通道的发育起到了重要作用。单一泥质地层裂隙内充填物沉积模式与沙泥互层的多旋回地层略有差异,主要表现为沙层的润滑作用以及对早期裂隙内充填物类型的影响。上述两种地层裂隙内充填物沉积特征均与后期充注期次相对应,表现出很好的韵律性。裂隙纵剖面中生物发育层的出现,对裂隙内充填物的物理、化学性质将产生重要影响。     

现场测试地层平均热物性参数方法初探——以北京某工程地源热泵系统地层热物性测试评价工程为例

地层热物性参数是地源热泵系统地下换热器设计所需要的非常重要的参数,热物性参数的大小对钻孔的数量及钻孔的深度均有显著的影响,进而影响地源热泵系统的初投资。笔者以北京某工程地源热泵系统地层热物性测试评价工程为例,阐述了现场测试获取平均热物性参数的测试方法和原理,并通过建立传热模型,利用参数估算法计算了工程场区的热物性参数。为验证结果的可靠性,又采用了线源理论对测试数据进行计算并将计算结果与参数估算法进行了分析比较。最后,笔者对两种计算方法的求解方法和适用条件进行了归纳总结。由于目前地层热物性参数确定方法还很不成熟,可借鉴的经验不多,所以笔者提出的热物性参数确定方法只是尝试性的探索,还有待今后的实践检验和进一步的理论研究工作。     

利用水源热泵开采浅层地热能若干问题的探讨

地下水源热泵采能技术作为一种浅层低温地热能的可持续开发方式,在我国推广应用已有近十年的时间。尽管推广时间不长,但发展速度非常之快,尤其是近3～5年。由于多方面的原因,我国部分地下水源热泵采能工程逐渐暴露出一些问题,需要给予足够的重视。本文介绍了地下水源热泵采能系统的运行模式及特点,简要地对国内外热泵采能技术的应用现状进行了综述,并对该项技术在我国推广应用过程中存在的一些问题,进行了一定的分析和讨论。     

鲁北平原地下咸水浅层地热能开发利用条件研究

为了解决鲁北平原区农村冬季清洁供暖问题,扩大地下水地源热泵系统的应用规模,以区内广泛发育的咸水体为研究目标,在简述第四纪地层特征的基础上,阐明了第四纪含水砂层与咸水体的分布特征,总结了区内以往开展的4个浅层地热能勘查项目所施工的水文地质勘探孔抽水试验与回灌试验成果。结果表明: 研究区咸水含水层单井涌水量320~475 m³/d,单位涌水量12.76~28.3 m³/(d·m),自然回灌条件下单井回灌量30~56 m³/d,单位回灌量5.85~17.5 m³/(d·m); 单眼开采井可供暖面积为3 481.02 m²,可满足约35户农村住宅的冬季供暖需求; 研究区在进行浅层地热能开发时建议优先选择地下水地源热泵系统,对于供暖/制冷能耗需求较小的农村单户建筑,可选择地埋管地源热泵系统进行分散式供暖/制冷。     

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.     

Hydrothermal circulation beneath Mount Pelée inferred by self potential surveying. Structural and tectonic implications

Self-potential (SP) surveys were made on Mount Pelée volcano (Martinique Island, French West Indies) in 1991 and 1992 in order to recognize its hydrothermal system, the associated groundwater channeling and the main superficial structures of the massif. Almost 70 km of profiles were carried out with an average sample spacing of 50 m. Measurements essentially reveal negative SP anomalies, down to −1700 mV, with high gradients (−1.83 mV/m) due to the infiltration of meteoric water into the massif. Rims of summit calderas Morne Macouba and Etang-Sec present sharp negative SP anomalies on the western, northern, and eastern flanks. Negative SP anomalies indicate no upward water flow beneath Mount Pelée summit. On the southwestern volcano flank, a 3.5×6 km horseshoe-shaped structure corresponding to a southwest flank collapse event, older than 25,000 years BP, is clearly identified by the SP mapping. High gradients border the inner southern rim from Morne Calebasse to St Pierre town and the Caribbean Sea. Along the northern rim of the horseshoe-shaped structure the negative SP anomalies give place to a positive SP anomaly, up to 200 mV, of SW–NE trend. This zone covers the area of two active hot springs (Sources Chaudes and Puits Chaud: 40–65°C). Marine magnetic surveys and bathymetry show that the horseshoe-shaped structure spreads into the Caribbean Sea up to about 10 km from the coast. Buried structural discontinuities are evidenced inside the flank collapse structure. The upper one deviates the groundwater flow coming from the summit toward the south flank where the flow finds an indentation to expand again downwards. This discontinuity is either an old hypothetical caldera rim partly destroyed by the collapse of the south–southwestern flank and covered by recent pyroclastic deposits, or more probably the trace of a bulge landslide. A circulation model of the hydrothermal waters is proposed. Rainfall (5–6 m/year) is partly drained inside the summital calderas and the flank collapse zone through pyroclastic flows down to an impermeable basement. There the groundwater constitutes perched aquifers at the contact of the bulge landslide, or of the hypothetical old caldera rim. Along the inner northern border of the flank collapse structure the phreatic water is reheated. Warm groundwater flows along the northern avalanche structure rim and discharges near the coast in ground and marine outcrops, of medium temperature. Finally, the main part of the meteoric water is channeled along the old caldera rim, or along the bulge landslide towards the south flank of Mount Pelée, where some gaps in the rim exist. There the groundwater finds again a subhorizontal gravitational circulation along Mount Pelée slopes into the Caribbean Sea.     

On the volcanology of the Gibeon Kimberlite Field, Namibia

Kimberlite volcanism in the Upper Cretaceous Gibeon Kimberlite Field, southern Namibia, consisting of at least 42 diatremes and a number of associated dykes, is closely related to carbonatitic and ultrabasic volcanic and intrusive activity which occurred at the margin of the Field. The volcanology of the diatremes and dykes as well as their structural setting is reported here. Because of the paleohydrogeological setting, and since juvenile kimberlite occurring in dykes, intrusive plugs, and spherical lapilli is devoid of vesicles, a phreatomagmatic eruption mechanism is proposed for the genesis of the kimberlite diatremes. Karoo dolerite, basalt and sediment xenoliths in the diatremes provide evidence for the former extent of Karoo strata at the time of eruption.     

Seismic study of the Mesozoic carbonate basement around Mt. Somma–Vesuvius, Italy

Fifteen seismic reflection lines from AGIP surveys, in and around the Campanian Plain and Mt. Somma–Vesuvius (south Italy) have been interpreted. The attention has been focused to the horizon pertinent to the top of the Mesozoic carbonate sequence and the Quaternary faults dissecting it. As a matter of fact, both are very important elements for understanding the origin of the volcanic activity in the area, that often in the past, has been the topic of debates not supported by reliable data. In the study area, referring to the depth of the carbonate basement, comparison between the result achieved by the seismic prospecting and previous gravity studies has been made. It shows coherence in some areas but large discrepancy within others. Near the town of S. Anastasia, the gravity and seismic depth estimates differ as much as 1000 m or more. Furthermore, the seismic data show that the source of the greatest volcanic eruption in the area (the so-called ‘Campanian Ignimbrite') is probably not located in the Acerra depression, as suggested by other authors. A main NE–SW fault directed toward Vesuvius, considered as playing a primary role on volcanogenetic processes and previously recognised only offshore by marine seismic survey, has been now identified also inland using this new seismic information. The results presented here strengthen the hypothesis that Mt. Vesuvius is located at the crossing point of two regional Quaternary sets of fault heading NW–SE and NE–SW.     

Numerical flow and performance analysis of a water-jet axial flow pump

The purpose of the present study is to investigate the performance and three-dimensional flow fields in a water-jet pump. TASCflow is employed to simulate the rotator-stator coupling flow field. A standard k-ε turbulence model combined with standard wall functions is used. In order to investigate the effect of a rear stator on flow fields, the flows in two water-jet pumps with and without a rear stator are studied. Computational fluid dynamics (CFD)-predicted overall performances are in good agreement with the experimental results. Then the flow fields, such as the pressure distribution on the blade surfaces, and the axial and tangential velocity distribution, especially the radial loading distribution, are investigated at different flow rates. In addition, the effects of a rear stator and different spacings between the rotor and the stator on the overall performance and the flow fields of the water-jet pump are also investigated.