Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.     

中国北方地区春季气溶胶光学特性地基遥感研究

基于中国北方地区地基太阳直接/散射辐射计观测,分析了2001年春季气溶胶光学厚度、尺度和吸收特性。沙尘期间,气溶胶光学厚度显著升高,而尺度上升,粗粒子浓度显著增加,大气气溶胶表现出中性或异常消光特征。除沙尘活动之外,中国华北地区人为排放也是导致气溶胶光学厚度偏高的一个重要原因。中国沙尘源区气溶胶单次散射反照率小于以往观测和模式结果。北京和香河两地气溶胶光学厚度、Angstrom指数和尺度谱基本相似,说明华北地区人为排放与沙尘活动类似,也表现出区域尺度的特点。由于沙尘气溶胶与人为排放气溶胶相比,折射指数实部偏大、虚部偏小,从而北京地区沙尘期间单次散射反照率明显大于非沙尘期间,特别是在近红外波段,说明沙尘活动不仅可以通过增加气溶胶光学厚度,同时也通过改变气溶胶物理、辐射特性来影响下游地区的气溶胶辐射强迫。     

银川市初夏气溶胶粒子谱分布特征

利用美制APS—3310A型激光粒谱仪，在中国西北城市银川对大气气溶胶粒子进行现场观测，结合气象条件，并通过理论计算分析，给出了银川市初夏大气气溶胶的日变化特征、3种不同粒径粒子分布特点及飘尘谱分布特征，以期为银川市大气污染总量控制方案及对策提供科学依据。     

改性碳酸氢铵的结构特征及其肥效增效机理研究

利用有机-无机(矿物)控释材料对碳酸氢铵进行改性，制成改性碳酸氢铵。盆栽试验结果显示，在等重条件下，改性碳酸氢铵较普通碳酸氢铵有较大幅度的增产。运用X射线衍射分析及红外光谱对改性碳酸氢铵的结构进行研究，发现其晶体结构发生较大的变化，差热分析结果也表明，改性碳酸氢铵的热分解温度比普通碳酸氢铵提高30℃。这种晶体结构的变化增加了改性碳酸氢氨的稳定性，从而延长了其肥效并提高了N的利用率。     

China''''s First Exploration of Chukchi Sea and Its Adjacent Waters in the ArcticA Study on Lead Geochemistry of Atmospheric Aerosol

1ＩｎｔｒｏｄｕｃｔｉｏｎＷｉｔｈｔｈｅｒａｐｉｄｄｅｖｅｌｏｐｍｅｎｔｏｆｈｕｍａｎｓｏｃｉｅｔｙ ,ｉｎｄｕｓｔｒｉａｌｉｚａｔｉｏｎｈａｓｂｅｅｎｓｐｅｅｄｅｄｕｐ .Ａｓａｒｅｓｕｌｔ,ｍｅｔａｌｍｉｎｉｎｇａｎｄｍｅｔａｌｌｕｒｇｙ ,ｃｏａｌａｎｄｇａｓｏｌｉｎｅｃｏｍｂｕｓｔｉｏｎａｎｄｃｈｅｍｉｃａｌｓｐｒｏｄｕｃｔｉｏｎｈａｖｅｇｉｖｅｎｏｆｆａｌｏｔｏｆＰｂ ｃｏｎｔａｉｎｉｎｇｉｎｄｕｓｔｒｉａｌｐｏｌｌｕｔａｎｔｓｗｈｉｃｈｈａｖｅｄｏｎｅｇｒｅａｔｈａｒｍｔｏｔｈｅｅｃｏｌｏｇ…     

GMS卫星遥感中国地区气溶胶光学厚度

讨论了利用GMS卫星遥感湖面上空气溶胶光学厚度的方法,根据在5个湖面附近与多波段光度计遥感结果的比较,对卫星遥感的方法和结果进行了检验,然后利用该方法遥感了中国大陆25个湖面上空气溶胶光学厚度.结果显示,利用卫星反演湖面光学厚度可以提供大陆上空气溶胶的信息,是研究大陆上空气溶胶光学厚度一个可行的方法.     

The Global Distribution of Secondary Particulate Matter in a 3-D Lagrangian Chemistry Transport Model

A global 3-D Lagrangian chemistry-transport model STOCHEM is used to describe the tropospheric distributions of four components of the secondary atmospheric aerosol: nitrate, sulphate, ammonium and organic compounds. The model describes the detailed chemistry of the formation of the acid precursors from the oxidation of SO₂, DMS, NO_x, NH₃ and terpenes and their uptake into the aerosol. Model results are compared in some detail with the available surface observations. Comparisons are made between the global budgets and burdens found in other modelling studies. The global distributions of the total mass of secondary aerosols have been estimated for the pre-industrial, present day and 2030 emissions and large changes have been estimated in the mass fractions of the different secondary aerosol components.     

MODELING THE EFFECTS OF ANTHROPOGENIC SULFATE IN CLIMATE CHANGE BY USING A REGIONAL CLIMATE MODEL

1 INTRODUCTION Being an important composition of the atmosphere, aerosol attracts increasing attention from the scientific community in recent years, together with the radiative forcing it causes and effects it imposes on the climate system. The anthropogenic aerosol affects the climate both directly and indirectly. The climate is directly affected when solar shortwave radiation is scattered and absorbed in what is known as the 搖mbrella effect? which can be dated back to as early as mor…     

大气气溶胶光学厚度的宽带消光遥感方法及其应用

该文发展了遥感气溶胶光学厚度的一个宽带消光遥感方法 ,它应用地面上太阳直射表探测的宽波段太阳直射信息反演 0 75 μm大气柱光学厚度。这方法的主要误差因子是气溶胶谱的不确定性。数值试验表明 ,气溶胶谱分布的误差所引起光学厚度解的误差一般小于 5 %。 1995年 1— 10月进行的 12 6 7组对比实验表明 ,由本方法探测的气溶胶光学厚度与光度计探测的气溶胶光学厚度的标准差为 10 5 % ,两者平均结果的偏差只有 0 7%。该文还应用这个方法 ,从气象台站辐射观测资料反演得到北京、沈阳等 10个地方 1980— 1994年间晴天气溶胶光学厚度资料 ,并分析其变化规律     

铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。