锂离子选择电极的研究 Ⅲ.：开链聚醚三（二环己酰胺）锂电极的制备和应用

以合成的开链聚醚三(二环己酰胺)等中性载体制成了PVC膜Li~+电极,研究了载体结构、膜成分与电极性能的关系,在聚醚三酰胺的胺基中,以环己基取代直链的烷基,显著地改善了Li~+—载体的性能,以邻苯二甲酸二癸酯或其和二苄醚混合增塑的1,1,1—三[1′—(2′—氧杂—3′—二环己胺基羰基)丙基]丙烷Li~+—电极的线性响应范围为2×10~(-5)～10~(-1)mol/L LiCl,K_(Li+Na)~(pot)～8×10~(-3),以Mg(Ac)_2为离子强度调节缓冲剂,用标准比较法或样品加入法测定了LiCl—HCl—H_2O或LiCl—MgCl_2—HCl—H_2O体系中的Li~+,LiCl含量≥2％的样品,测定误差≤5％。     

Chronology of Sanbagawa metamorphism

By collating age data based on the fossil age of the protoliths, radiometric dating of the metamorphic minerals, and sedimentary records of erosion at the earth's surface, the history of the Sanbagawa metamorphism can be summarized as follows. (1) The pre-metamorphic sedimentary rocks (Carboniferous-Jurassic + Early Cretaceous?) became mixed and formed a thickened packet in the vicinity of an ancient trench through a variety of subduction-related tectono-sedimentary processes, probably in Early Cretaceous time (c., 130-120 Ma). (2) The subducted protoliths underwent progressive metamorphism reaching a maximum depth of c. 30 km in late Early Cretaceous time (c. 116 ± 10 Ma). (3) The high-P/T metamorphic rocks began to rise toward the surface (during the interval 110-50 Ma) with minimum estimates for the average cooling rate around 9-12°C/Ma and an average uplift rate around 0.4-0.5 mm/year. (4) Finally, at some stage after reaching the erosional surface, the high-P/T metamorphic rocks were covered unconformably by the middle Eocene (c. 50-42 Ma) Kuma Group. On the basis of the present chronological summary of the Sanbagawa metamorphism, the areal extent of the Sanbagawa metamorphism is also discussed with respect to the weakly metamorphosed subduction-accretion complex of the next tectonic belt to the south, the Northern Chichibu belt.     

A digital model to evaluate the water balance in a typical hardrock environment

A digital model was designed and developed to study the water balance situation in a typical hardrock environment near Hyderabad, Andhra Pradesh. The model was calibrated over a period of six years with observed field hydrographs. An optimum error factor of 0.001 m was chosen and the computer took 47 iterations for outputting the results with the desired accuracy. Prognostic studies were carried out with progressively increasing draft conditions and water levels were observed to be declining even when the draft was less than the recharge. The analysis of the experiments further amended the belief of the earlier workers.     

单站点无地面控制摄影机自检校

“单站点无地面控制摄影机自检校”是一种利用纯摄影测量信息检校摄影机的方法。本文由共线条件方程出发导出了顾及到摄影机旋转中心与其摄影中心不一致时正直摄影象片与倾斜摄影象片同名象点坐标的几何关系式及线性化的误差方程式。编制了适用于VAX-11/750计算机使用的FORTRAN程序,并给出了用模拟数据和实际数据的计算结果。     

Gas chromatographic determination of peroxyacetyl nitrate: Two convenient calibration techniques

Two procedures for the calibration of an electron capture detector (ECD) for peroxyacetyl nitrate (PAN) are discussed. One is based on the first-order decay rate of the the PAN mixing ratio in conditioned glass storage vessels. The other method makes use of the photochemical generation of PAN in mixtures of acetone and NO₂ in air. For this purpose a Penray Hg lamp was inserted into a glass vessel filled with 1 atmosphere of air containing 10 ppm NO₂ and 1% acetone. After 3 min of irradiation, the average PAN mixing ratio formed was 8.87±0.25 ppmv as determined in six separate runs.     

A numerically calibrated reference level (MP28) for the terrestrial mammal-based biozonation of the European Upper Oligocene

The fauna of the Enspel (Westerwald) and the neighbouring Kärlich (Neuwied basin) fossil deposits correspond to the Upper Oligocene Mammal Paleogene (MP) reference level 28 and 28–30, respectively. Basaltic flows and a trachyte tuff terminating and predating the fossil deposit sedimentation allow to numerically calibrate the MP reference levels by radioisotope dating. Laser fusion ⁴⁰Ar/³⁹Ar step heating on volcanic feldspars yield a time interval of 24.9–24.5 Ma for reference level MP28 at Enspel and a maximum age of 25.5 Ma for the time interval MP28–MP30 at Kärlich. Interpolation between the time intervals determined for the Enspel reference level MP28 and the age of the global Oligocene/Miocene boundary of 24.0 ± 0.1 Ma taken from literature results in time intervals of 24.5–24.2 Ma and 24.2–23.9 Ma for the younger reference levels MP29 and MP30, respectively. These intervals of ≤ 0.4 m.y. for MP reference levels of the latest Oligocene are short relative to older Oligocene MP reference levels 21–27 between 34 and 25 Ma. Since subdivision into MP reference levels essentially is based on assemblages of mammal taxa and on evolutionary changes in tooth morphology of mammals short MP time intervals during the latest Oligocene indicate a rapid evolutionary change relative to the early Oligocene.     

光电测距仪测距标准差校准结果的不确定度评定

介绍光电测距仪的测距标准差计量校准方法并对校准结果的不确定度进行了评定,给出了测距仪的测距标准差校准结果的表示形式和20台测距仪的测距标准差校准结果及测量不确定度.     

全站仪近距离测距精度检验方法的探讨

提出了室内基线法，给出了相应的数据处理方法，并用实测数据进行了计算，结果显示全站仪在室内、短边条件下的测距精度较标称精度有很大的提高。该法所得结果与现存两种方法的结果基本相当，从而证明了该法能够客观地反映出工业测量用全站仪的近距离测距精度。     

利用二维DLT及光束法平差进行数字摄像机标定

利用共线方程和二维DLT之间的对应关系导出了由二维DLT的8个参数表达的主纵线方程式，讨论了主点初值和求解方法，给出了单张像片摄像机参数分解不惟一性及临界序列的证明，详细推导了利用二维DLT参数分解摄像机外方位元素初值的实用算法，论述了利用光束法平差进行摄像机标定的数学模型，实际图像数据实验取得了很好的结果，验证了本文所提出的摄像机标定算法的可行性。     

地形引起的雷达辐射畸变及其校正

合成孔径雷达影像由于其侧视特点 ,存在着严重的地形引起的几何畸变及辐射畸变。辐射畸变不仅对 SAR辐射标定造成困难 ,而且严重影响了影像分类、土壤湿度信息提取、森林蓄积量信息提取等应用。本文将辐射畸变归结为面积效应和局部入射角效应 ,推导了散射面积归一化因子 ,以消除辐射畸变的面积效应。提出了一种以局部入射角的线性函数表达的后向散射模型 ,在此基础上 ,给出了消除局部入射角效应的校正函数。最后 ,以RADARSAT SAR影像进行地形辐射畸变校正的试验与分析