Evaluation of Estrogenic Activity and Measurement of EDCs in Wastewater Treatment Plants

1IntroductionDuringthe past several years,concern hasincreasedover the potential pollution of watershed by estrogeniccompounds,including steroidal hormones fromhumanand ani mal sources.Effluents from wastewater treat-ment plants are sources of endocrine-d…     

Reactions of nitriles in ices relevant to Titan, comets, and the interstellar medium: formation of cyanate ion, ketenimines, and isonitriles

Motivated by detections of nitriles in Titan's atmosphere, cometary comae, and the interstellar medium, we report laboratory investigations of the low-temperature chemistry of acetonitrile, propionitrile, acrylonitrile, cyanoacetylene, and cyanogen (CH₃CN, CH₃CH₂CN, CH₂CHCN, HCCCN, and NCCN, respectively). A few experiments were also done on isobutyronitrile and trimethylacetonitrile ((CH₃)₂CHCN and (CH₃)₃CCN, respectively). Trends were sought, and found, in the photo- and radiation chemical products of these molecules at 12-25 K. In the absence of water, all of these molecules isomerized to isonitriles, and CH₃CN, CH₃CH₂CN, and (CH₃)₂CHCN also formed ketenimines. In the presence of H₂O, no isonitriles were detected but rather the cyanate ion (OCN⁻) was seen in all cases. Although isonitriles, ketenimines, and OCN⁻ were the main focus of our work, we also describe cases of hydrogen loss, to make smaller nitriles, and hydrogen addition (reduction), to make larger nitriles. HCN formation also was seen in most experiments. The results are presented in terms of nitrile ice chemistry on Titan, in cometary ice, and in the interstellar medium. Possible connections to prebiotic chemistry are briefly discussed.     

Spectral alteration of the Meteorite Epinal (H5) induced by heavy ion irradiation: a simulation of space weathering effects on near-Earth asteroids

We present results obtained for Epinal (H5), an ordinary chondrite meteorite, irradiated with 60 keV Ar⁺⁺ ions, simulating solar wind heavy particle irradiation. Bidirectional reflectance spectra (0.3-2.67 μm) measured after irradiating Epinal samples with different ion fluences exhibit a progressive reddening that is similar to the spread of spectra observed for S-type near-Earth asteroids. The timescales for inducing the same effects in space as those obtained in laboratory are estimated to be ¹⁰⁴-¹⁰⁶ yr. These results suggest irradiation by heavy ions may be a very efficient weathering process in near-Earth space.     

Chemical evolution of the high redshift galaxies

We have tried to determine the rate of chemical evolution of high redshift galaxies from the observed redshift distribution of the heavy element absorption systems in the spectra of QSOs, taking into account the evolution in the intensity of the metagalactic UV ionizing radiation background, the radius and/or the co-moving number density of, and the fraction of mass in the form of gas in, the absorbers. The data for both the Lyman limit systems and the C IV systems have been fitted simultaneously. It seems that the abundance of carbon has possibly increased by about a factor of 5 to 20 from the cosmic time corresponding to the redshift ≃ 4 to 2. The data also suggest that either the radius or the co-moving number density of the galaxies increased with redshift up to z = 2.0 and decreased slowly thereafter. The total mass of the halo gas was higher in the past, almost equal to the entire mass of the galaxy at z = 4. The hydrogen column density distribution for Lyman limit systems predicted by the model is in agreement with the observed distribution.     

台湾省辐射气候特征

本文根据一些实测资料,选配了适合本地区的经验公式,计算台湾省辐射平衡各分量并讨论其时空分布特征,作出辐射气候分区。     

Modelling the Gross Primary Productivity of West Africa with the Regional Biomass Model RBM+, using optimized 250 m MODIS FPAR and fractional vegetation cover information

Global warming associated with climate change is one of the greatest challenges of today’s world. Increasing emissions of the greenhouse gas CO₂ are considered as a major contributing factor to global warming. One regulating factor of CO₂ exchange between atmosphere and land surface is vegetation. Measurements of land cover changes in combination with modelling the Gross Primary Productivity (GPP) can contribute to determine important sources and sinks of CO₂.The aim of this study is to accurately model the GPP for a region in West Africa with a spatial resolution of 250 m, and the differentiation of GPP based on woody and herbaceous vegetation. For this purpose, the Regional Biomass Model (RBM) was applied, which is based on a Light Use Efficiency (LUE) approach. The focus was on the spatial enhancement of the RBM from the original 1000–250 m spatial resolution (RBM+). The adaptation to the 250 m scale included the modification of two main input parameters: (1) the fraction of absorbed Photosynthetically Active Radiation (FPAR) based on the 1000 m MODIS MOD15A2 FPAR product which was downscaled to 250 m using MODIS NDVI time series; (2) the fractional cover of woody and herbaceous vegetation, which was improved by using a multi-scale approach. For validation and regional adjustments of GPP and the input parameters, in situ data from a climate station and eddy covariance measurements were integrated.The results of this approach show that the input parameters could be improved significantly: downscaling considerably reduces data gaps of the original FPAR product and the improved dataset differed less than 5.0% from the original data for cloud free regions. The RMSE of the fractional vegetation cover varied between 5.1 and 12.7%. Modelled GPP showed a slight overestimation in comparison to eddy covariance measurements. The in situ data was exceeded by 8.8% for 2005 and by 2.0% for 2006. The model results were converted to NPP and also agreed well with previous NPP measurements reported from different studies. Altogether a high accuracy and suitability of the regionally adjusted and downscaled model RBM+ can be concluded. The differentiation between vegetation growth forms allows a separation of long-term and short-term carbon storage based on woody and herbaceous vegetation, respectively.     

The Cherenkov Telescope Array potential for the study of young supernova remnants

Supernova remnants (SNRs) are among the most important targets for γ-ray observatories. Being prominent non-thermal sources, they are very likely responsible for the acceleration of the bulk of Galactic cosmic rays (CRs). To firmly establish the SNR paradigm for the origin of cosmic rays, it should be confirmed that protons are indeed accelerated in, and released from, SNRs with the appropriate flux and spectrum. This can be done by detailed theoretical models which account for microphysics of acceleration and various radiation processes of hadrons and leptons. The current generation of Cherenkov telescopes has insufficient sensitivity to constrain theoretical models. A new facility, the Cherenkov Telescope Array (CTA), will have superior capabilities and may finally resolve this long standing issue of high-energy astrophysics. We want to assess the capabilities of CTA to reveal the physics of various types of SNRs in the initial 2000 years of their evolution. During this time, the efficiency to accelerate cosmic rays is highest. We perform time-dependent simulations of the hydrodynamics, the magnetic fields, the cosmic-ray acceleration, and the non-thermal emission for type Ia, Ic and IIP SNRs. We calculate the CTA response to the γ-ray emission from these SNRs for various ages and distances, and we perform a realistic analysis of the simulated data. We derive distance limits for the detectability and resolvability of these SNR types at several ages. We test the ability of CTA to reconstruct their morphological and spectral parameters as a function of their distance. Finally, we estimate how well CTA data will constrain the theoretical models.     

射电天文台址电子设备电磁辐射评估

射电望远镜具有极高的系统灵敏度,且系统内、系统间及台址内电子设备众多,电磁环境复杂,科学合理地评估台址内电子设备辐射发射对射电天文观测的影响,对系统电磁兼容性设计、无线电管理、屏蔽改造等有重要的指导意义。浅析了射电望远镜系统灵敏度及射电天文领域仪器设备辐射发射相关评估标准;基于射电望远镜系统灵敏度及观测需求,计算了南山25 m射电望远镜馈源口面干扰电平限值,并给出了天线旁瓣增益的计算方法;提出一种基于干扰电平限值、旁瓣增益、干扰测量、路径衰减的电子设备电磁辐射评估方法,并针对南山25 m射电望远镜天线驱动电磁辐射进行了评估,给出了屏蔽需求。     

青藏高原东北部地区闪电特征初步分析

利用VHF辐射源三维定位系统及快、慢天线资料,对青海大通地区5次雷暴过程中云闪、负地闪、正地闪的起始高度、持续时间、辐射源数目及正、负地闪云内放电过程的持续时间和回击次数进行了统计分析.研究表明,该地区闪电持续时间较短,平均＜0.5 s;正、负地闪首次回击发生前均有较长时问的云内放电过程,正地闪的云内放电过程持续时间略长于负地闪;负地闪的回击次数较少,平均为2.5次,其中40％的负地闪只有1次回击,而正地闪回击次数均为1次;云闪的起始高度最高,负地闪的起始高度低于云闪,正地闪的起始高度最低;云闪产生的辐射源数目最多,负地闪少于云闪,正地闪产生的辐射源数目最少.     

多回击负地闪先导通道的辐射和光学特征

利用闪电VHF窄带干涉仪辐射源定位系统和高速摄像系统,对青海大通地区一次有5次回击的负地闪放电过程进行了同步观测,对比分析了通道传输过程的辐射和光学特征.结果表明,光学通道亮度能补充VHF干涉仪定位先导通道的电流特征,VHF干涉仪定位弥补了光学设备拍摄弱放电和云内流光通道的不足;在通道分枝结构上,干涉仪定位的通道和光学通道呈现出很好对应.干涉仪定位分枝通道的辐射源点较明显,但分枝光学通道的出现明显落后于干涉仪定位辐射源通道.对用两种不同观测手段探测的先导通道进行速度计算,发现两者计算的直窜先导和直窜梯级先导速度量级一致,均为106m·s-1,但干涉仪在时间的获取及精确量化上有优势,干涉仪定位计算先导速度的精确度高于光学通道定位.