Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

多尺度细节增强的遥感影像超分辨率重建

鉴于现有超分辨率重建方法难以突显重建影像细节信息的问题,提出多尺度细节增强的遥感影像超分辨率重建模型框架。首先,通过最小二乘滤波方法将序列影像分解成包含大尺度边缘的平滑信息和包含中小型尺度的细节信息;其次,利用插值方法得到相应的高分辨率细节信息和平滑信息,构造纹理细节增强函数,提升中小型细节的增强幅度;最终,融合细节信息和平滑信息,得到初始的超分辨率重建结果,并利用局部优化模型进一步改善重建影像质量。选取同时相和多时相遥感影像作为试验数据。试验结果表明,本文重建结果与插值方法、TV方法和MAP方法相比,在客观评价指标上均有显著提高,明显改善了重建影像的纹理细节。论文提出的多尺度细节增强的超分辨率重建方法,可以使重建影像提供更多高频细节信息,具有较好鲁棒性和普适性。     

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.     

海上油田开发井钻井优化设计和应用实践

LF7-2油田位于我国南海珠江口盆地LF区块,是一个小规模油田,根据前期探井揭示,上部地层以厚层泥岩为主,极易水化、分散,使钻井液性能变差;起下钻过程中钻具遇卡、遇阻等复杂情况频繁发生;钻头选型不尽合理,易泥包;下部地层以砂泥岩互层为主,岩石致密、可钻性变差,钻具扭矩、摩阻增加,定向钻进时滑动困难,井眼轨迹控制难度大,给钻井提速增效带来诸多困难。根据探井地质情况和岩石力学剖面,利用钻井软件优选平台位置,对开发井井身结构、井眼轨迹、钻柱力学、钻井液、固井等方面进行钻井仿真模拟,制定出科学的钻井设计方案,在直井段采用“牙轮钻头+直螺杆+MWD”钻具开展防斜打直,造斜段使用“PDC钻头+弯螺杆+MWD/LWD”开展复合钻井,水平段采用“PDC钻头+PowerDriver+MWD/LWD”开展旋转导向钻井,实现精准化钻井,顺利完成6口开发井施工。现场应用单井平均机械钻速29.43 m/h,钻井工期191.59 d,工期比设计提前28.41 d,钻井提速增效显著,降低开发成本。通过PowerDriver的近钻头井斜、自然伽马实时测量和传输,减少地质误判,实现对储层顶界面的实时探测,使储层钻遇率达100%,收到较好的经济效益和投资回报,实现小油田的效益开发。     

顺北油田钻井参数强化的提速效果评价

X、Y井是部署在塔里木盆地顺北油田的2口勘探井,X井为钻井参数强化试验井,X井较Y井在实钻中更好地执行了钻井参数强化措施,三开5600~7500 m井段X井机械钻速较Y井提高了119%。对比分析,X井通过配置压力级别更高的地面设备,实钻实现了更高的排量和泵压,X、Y井的钻头冲击力分别为0.73~1.02 kN、0.61~0.85 kN,钻头水功率分别为6.79~11.38 kW、5.37~8.79 kW,机械比能为0.23~2.15 MPa、0.52~3.5 MPa。钻井参数强化的实验过程中,X井获得了更高的井底机械能量与水力能量以及更理想的破岩环境,其机械钻速明显高于Y井,符合钻井参数强化提速的预期。     

2018年常州一次罕见持续性雾-霾天气分析

利用常规气象观测资料、探空资料、污染物浓度及AQI资料、NCEP再分析资料等,对2018年11月24日至12月3日夜间常州持续11 d的强浓雾和严重霾天气过程进行了分析。结果表明：（1）此次雾-霾过程持续时间长、范围广、强度大、污染重。（2）中纬度地区高层持续纬向环流控制、中低层暖脊稳定存在,地面持续受均压场或弱倒槽顶部、弱冷锋前部影响,是这次持续性雾-霾过程的重要天气条件。（3）边界层内弱辐散、负涡度及弱的下沉气流是此次雾-霾天气得以长时间维持、发展的动力因子。近地层长时间水汽饱和且维持小风速利于雾-霾的长时间维持。（4）近地面高强度的贴地逆温长时间维持和持续较低的混合层高度是此次雾-霾形成、发展和长时间维持的重要热力条件。雾比霾的平均混合层高度明显偏低且霾等级越高混合层高度越低,混合层高度的变化先于能见度变化,对雾-霾临近预警有较好的指导作用。（5）弱冷空气渗透、风速适当增加、混合层高度的先期快速下降、负净辐射曝辐量绝对值的明显增大是雾爆发性增强的主要原因。     

Estimation of flow enhancement in the Kinneret watershed due to cloud seeding

A comparison is carried out between historical records of the flow measured in Kinneret watershed during and prior to the time of cloud seeding for rainfall enhancement. Precipitation series for the control area of the meteorological experimentation serve as a reference for the comparison. The fluctuations of the flow, which would have occurred unless the effect of the seeding, are estimated by a linear regression on the precipitation as the control. The regression parameters are calibrated separately for the unseeded and for the seeded time series. The model with the parameters calibrated for the unseeded series is applied on the rainfall recorded during the seeded time, and vice versa. The difference between the measured and the computed data is attributed to the effect of cloud seeding. Similar comparisons are carried out with respect to rainfall series recorded at the target area and at the edge of the enhanced area.The results indicate that the flow from the affected sector of the watershed has been enhanced, with respect to the control, by 31×10⁶ m ³/year, at a significance level of 31. This enhancement is 5% of the volume which is generated in that area. The rates found with respect to the rainfall at the edge are higher than those found with respect to the control, while those with respect to the rainfall at the center of the target area are lower.     

从熵原理得出的雨量时程方程

本文从熵极大原理出发导出了在一次降水过程中降水强度与其历时为负指数关系。并从中引出几个实用方程。这一结果与Paulhus等给出的经验方程在函数形状上类似。 本文通过对400多次遍及中国各地的降水自记记录分析证实,此理论公式与实况的平均相对偏差为10.7％,比Paulhus等的公式相对偏差小了5％。 此结果可用于暴雨、防洪服务和水利工程设计中。这启示人们熵极大原理在气象水文领域有应用潜力。     

200hPa非地转风和非均匀层结与梅雨暴雨的关系

本文通过1991年梅雨后期，7月1—13日200hPa非地转场分析得出，梅雨期200hPa非地转风主要由积云对流动量转换形成。其次是风速平流，并通过数值试验得以证明。非地转风形成的高层辐散，可进一步使暴雨增强与维持。另外梅雨期非均匀层结对非地转风及暴雨也有较大的影响。     

广州前汛期暴雨各层天气系统特征分析

本文对广州前汛期暴雨的地面、850hPa、500hPa、200hPa系统特征进行了分析，给出了各层系统配置图，为日常预报业务提供分析依据。