Porphyrin geochemistry of Atlantic Jurassic-Cretaceous black shales

Late Jurassic-early Cretaceous black shales and an overlying sequence of Albian-Campanian zeolitic claystones from the Falkland Plateau (DSDP/IPOD Leg 71, Site 511) were analyzed for tetrapyrrole pigment type and abundance. The “black shale” sequence was found to be rich in DPEP-series dominated free-base, nickel (Ni) and, to a lesser extent, vanadyl (V = 0) porphyrins. A low level of organic maturity (i.e. precatagenesis) is indicated for these strata as nickel chelation by free-base porphyrins is only 50–75% complete, proceeding down-hole to 627 meters sub-bottom. Electronic and mass spectral data reveal that the proposed benzo-DPEP (BD) and tetrahydrobenzo-DPEP (THBD) series are present in the free-base and Ni species, as well as the more usual occurrence in V = 0 porphyrin arrays. Highly reducing conditions are suggested by an abundance of the PAH perylene, substantial amounts of the THBD/BD series and a redox equilibrium between free-base DPEP and 7,8-dihydro-DPEP series, which exist in a 7:1 molar ratio. The Albian-Campanian claystone strata were found to be tetrapyrrolepoor, and those pigments present were typed as Cu/Ni highly dealkylated (C₂₆ max.) etioporphyrins, thought to be derived via redeposition and oxidation of terrestrial organic matter (OM). Results from the present study are correlated to our past analyses of Jurassic-Cretaceous sediments from Atlantic margins in an effort to relate tetrapyrrole quality and quantity to basin evolution and OM sources in the proto-Atlantic.     

Li-(Mg、Zn、Ni)钒酸盐三元体系相关系和结晶化学

对Li-(Mg、Zn、Ni)钒酸盐系统在500—800℃的相图研究发现:(Mg、Zn、Ni)V_2O_6和(Mg、Zn、Ni)_2V_2O_7,二个系统中都有两个主要固溶体,一个以NiV_2O_6(或Ni_2V_2O_7)为主结构,另一个在MgV_2O_6-ZnV_2O_6间形成完全连续型,Mg_2V_2O_7-Zn_2V_2O_7间为MgZnV_2O_7结构型。(Mg、Zn、Ni)_3V_2O_8系统中,整个就是一个固溶体,而Li(Mg、Zn、Ni)VO_4系统中,端员组分相互间也形成不同的固溶体。     

北京市土壤中Cr,Ni含量的空间结构与分布特征

本文以一个完整的省级行政单元(北京市)为例,进行系统的、大尺度的土壤Cr,Ni含量的空间分布与污染评价研究,通过地统计学方法分析揭示了北京市土壤中Cr,Ni的空间结构与分布特征,并探索其主要成因,为全面了解北京市的土壤环境质量和开展大规模的土壤环境质量评价研究等提供方法学借鉴和参考.结果表明:土壤Cr,Ni含量的空间结构具有较好的可迁性特点;指数模型拟合效果较好,变程分别为174.6km和15km;半变异函数的方向性分析表明,Cr,Ni均为各向同性,土壤中Cr,Ni具有中等程度的空间相关性.土壤中Cr含量的分布特征为空间相关范围较大,从总体趋势来看,土壤Cr含量的分布较为连续,呈明显的东高西低的分布趋势,大致可以分为3个大的斑块,西北方向(太行山山脉)土壤Cr含量较低,而东南方向(冲积平原)土壤Cr含量相对居中,东北部(燕山山脉)的土壤Cr含量最高.土壤Ni含量的空间分布比较零散,其分布大致表现为东北部地区最高,西南部居中,中部地区最低.研究还揭示,北京市土壤中Cr,Ni含量目前仍主要受成土母质的影响,但是个别地区也存在明显的Cr,Ni含量严重偏高现象.     

Tectonic Controls on the Formation of the Liwu Cu-rich Sulfide Deposit in the Jianglang Dome, S W China

Abstract. The Liwu Cu‐rich sulfide deposit occurs within the Jianglang dome in the eastern margin of the Tibetan plateau. The dome consists of a core, a middle slab and a cover sequence. The main deposit is hosted in the core with minor ore bodies in the middle slab. The protolith of the core consists of clastic sedimentary rocks with inter‐layered volcanic rocks. All of the ore bodies are substantially controlled by an extensional detachment fault system. The ore bodies within the core are distributed along the S₂ foliation in the hinge of recumbent fold (D₂), whereas ore bodies with en echelon arrangement are controlled by the mylonitic foliation of the lower detachment fault. Ore bodies within the middle slab are oriented with their axes parallel to the mylonitic foliation. Pyrite and pyrrhotite from the ores contain Co ranging from 37 to 1985 ppm, Ni from 2.5 to 28.1 ppm, and Co/Ni ratios from 5 to 71. These sulfides have δ³⁴S values ranging from 1.5 to 7.5 % whereas quartz separates have δ¹⁸O values of 11.9 and 14.3 % and inclusion fluid in quartz has δD value of‐88.1 %. These features suggest that the deposit was of hydrothermal origin. Two ore‐forming stages are recognized in the evolution of the Jianglang dome. (1) A low‐temperature ore‐forming process, during the tectonic transport of the upper plate above the lower detachment, and the initial phase of the footwall updom‐ing at 192–177 Ma. (2) A medium‐temperature ore‐forming stage, related to the final structural development of the initial detachment at 131–81Ma. Within the core, the ore bodies of the first stage were uplifted to, or near, the brittle/ductile horizon where the ore‐forming metals were re‐concentrated and enriched. A denudation stage in which a compressional tectonic event produced eastward thrusting overprinted the previous structures, and finally denuded the deposit. The Liwu Cu‐rich sulfide deposit was formed during a regional extensional tectonic event and is defined as a tectono‐strata‐bound hydrothermal ore deposit.     

Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.     

镍钴锰三元合金镀层应用于电镀金刚石钻头的初步研究

提出了一种能很好适应电镀金刚石钻头要求的新型胎体材料即镍钴锰三元合金镀层，给出了新镀层的电镀液配方，对比测量了镍钴锰镀层与目前广为采用的镍钴和镍锰镀层的硬度与韧性，结果指出，镍钴锰三元合金镀层具有比镍钴或镍锰镀层更高的综合机械性能和低得多的钴含量，更适合于制造电镀金刚石钻头，在适当条件下，镍钴锰胎体钻头可以分别更好地适应于镍钴和镍锰胎体钻头的应用领域。     

北京市近郊区土壤镍的空间结构及分布特征

通过对北京市近郊区349处土壤的取样调查，利用地统计学方法研究了北京市土壤中镍的空问结构和分布特征。结果显示，镍的空间结构性较好，具有明显的可迁性特点，块金效应所占的比例较大；实验变异函数可用指数模型拟合，利用所得模型进行克立格插值得到土壤镍含量的分布图，发现北京市土壤中，镍的含量分布具有明显的西北低而东南高的趋势。与北京市土壤镍含量的背景值进行对比，全市土壤并不存在非常严重的镍污染，其空间分布主要受成土母质制约；但是人类活动、风向、河流等人文和自然条件对镍的空间结构和分布格局也有一定程度的影响。     

硫化物熔离对岩浆硫化物含矿岩体中橄榄石Ni含量的影响——以金川岩体为例

为探讨硫化物熔离对含矿岩体中橄榄石Ni含量的影响,在前人橄榄石结晶硫化物熔离模型的基础上,定量模似计算了分离结晶过程中橄榄石Ni含量,并将其应用于金川橄榄石成园研究。研究表明,部分橄榄石落于无硫化物熔离橄榄石结晶趋势线下方,暗示其母岩浆为S饱和。根据模拟计算S饱和母岩浆橄榄石分离结晶趋势线,指出金川深部岩浆房中母岩浆橄榄石的分离结晶程度小于或等于3％,而由橄榄石结晶所导致熔离的硫化物熔体与橄榄石之间质量比约为40。     

大河超基性岩带岩体的含矿性

大河超基性岩带岩体大多呈透镜状、脉状产出,可分为南（S）北（N）两个岩带,北带又进一步划分为N-Ⅰ、N-Ⅱ亚带;N-Ⅰ亚带岩体总体属铁质超基性岩,N-Ⅱ亚带和S带中的岩体为偏镁质的超基性岩。岩带已发现有铬、镍矿体,但铬的矿化弱、矿体规模小;镍在岩带中矿化普遍,随岩体中MgO质量分数升高,镍的矿化强度也相应增加,并伴有钻、铂族等有益组分。     

南海在1997/1998年El Nio事件后的异常变化

基于NOAA OISST.V2月平均SST资料和FSU月平均风应力资料对南海的SST和风场异常进行了分析,发现：南海对1997/1998年El Nio事件响应最为强烈,并在1997/1998年冬季和次年的夏季SST存在2个异常高峰值,风速存在2个异常减小的极值。为研究南海环流在1997/1998年的异常变化,利用ECOM水动力模型计算了1995—2000年的南海环流场,分析了1998年1月和8月南海水位和环流的异常分布,二者均存在显著的异常：①1月,整个南海海盆为正的水位异常,流场为反气旋异常环流,冬季控制整个南海海盆的气旋式环流减弱;②8月,南海海盆水位为正异常,特别是越南东部海区出现较强的正水位异常,南海南部的高水位中心扩大北移;异常流场表现为南部为气旋式异常环流,北部为反气旋的异常环流,且在越南东部海区形成非常强的反气旋异常环流中心,使得控制南海南部的反气旋环流和北部的气旋环流均减弱。风应力的分析表明,风应力旋度的异常变化是南海环流年际异常变化的主要因素。