煎茶岭镍矿床成矿作用特征

煎岭镍矿与同类矿床相比,具有特殊的地质、地球化学物征，是一种特殊类型镍矿。本矿床流体包裹体同位素特征，表现出成矿体为岩浆与地层两端元混合趋势，成矿流体分属于Mg2+-Ca2+-Na+-F-(Cl-)型。根据 Pb、Sr、O、H、C 同位素及 REE资料，作者认为该镍矿的形成与后期酸性岩浆活动有密切关系，后期岩浆活动为成矿提供热力与热液，使成矿元素活化迁移、富集。本文最后提出了初步的成矿模式。     

小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

热带大气季节内振荡的异常与1997年El Nino 事件的发生

利用美国NCEP资料分析热带大气季节内振荡(ISO)与ENSO的关系,揭示了1997年E1Nino事件的发生,与赤道中西太平洋地区大气ISO在1996年冬到1997年春期间的异常增强有重要关系.而且该地区ISO的异常增强并不主要由赤道印度洋地区移来,主要表现为ISO在印度尼西亚上空被激发增强和东传.印度尼西亚地区ISO的被激发,则是由于东亚冬季风强异常在该地区引起的强对流活动的结果.     

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究(英文)

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。     

南海北部1987～1988年颗粒物质和硅藻通量的季节性变化:季风气候与 El Nino的响应

南海北部1987年9月～1988年10月沉积物捕获器中颗粒物质和硅藻通量的季节性变化受到季风气候的控制.颗粒物质与硅藻在东北和西南季风盛行期增加,在季风转变期减少.浅层和深层的颗粒总通量、蛋白石通量、碳酸钙通量、蛋白石/颗粒总通量比值、碳酸钙/颗粒总通量比值、有机碳/磷的比值以及浅层硅藻Thalassionema nitzschioides、Coscinodiscus excentricus、Coscinodiscus nodulifer、Nitzschia marina和Rhizosolenia bergonii的通量在东北季风期间明显地增加了,这些变化可能与1987年～1988年发生的EINino事件相关.     

吉林基性超基性岩的地质特征及找矿方向

从多旋回大地构造演化的观点,分析吉林区域多旋回的构造运动,控制多旋回的基性超基性岩浆活动及其相应的成矿作用,认为与含镍有关的基性超基性岩体,主要受“台槽边界”赤峰—开源深断裂控制,沿深断裂一侧或两侧成带分布,分群集中。为铜镍矿床区域勘查工作,提供地质资料。     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

Conceptual model about the interaction between El Ni(n)o/ Southern Oscillation and Quasi-Biennial Oscillation in far west equatorial Pacific

Interaction between the Quasi-Biennial Oscillation in far west equatorial Pacific (QBOWP) and the El Nino/Southern Oscillation (ENSO) is studied using a new conceptual model. In this conceptual model, the QBOWP effects on ENSO are achieved through two ways: (1) the oceanic Kelvin wave along equatorial Pacific, and (2) the Atmospheric Walker Circulation anomaly, while ENSO effects on QBOWP can be accomplished by the atmospheric Walker Circulation anomaly. Diagnosis analysis of the model results shows that the Atmospheric bridge (Walker circulation) plays a more important role in interaction between the ENSO and QBOWP than the oceanic bridge (oceanic Kelvin wave along equatorial Pacific); It is found that by the interaction of the ENSO and QBOWP, a free ENSO oscillation with 3-5 years period could be substituted by a oscillation with the quasi-biennial period, and the dominant period of SST anomaly and wind anomaly in the far west equatorial Pacific tends to be prolonged with enhanced ENSO forcing. Generally, the multi-period variability in the coupled Atmosphere-Ocean System in the Tropical Pacific can be achieved through the interaction between ENSO and QBOWP.     

热带太平洋地区风场异常和与El Ni(~n)o有关的年际变化

利用1964～1993年NCEP/NCAR再分析风应力资料和中国科学院大气物理研究所发展的14层热带太平洋环流模式(OGCM),对热带太平洋与El Ni(~n)o有关的年际变化进行了研究.首先,分析了西太平洋暖池次表层海温异常(SOTA)与Ni(~n)o 3区海表温度异常(SSTA)的年际变化关系,发现在El Ni(~n)o事件之前,暖池的次表层海温都有明显正异常出现,它的东传导致了El Ni(~n)o的发生,并且SOTA的传播随纬度变化,沿赤道东传,在赤道外西传.然后,选取了20世纪70年代和80年代两次最强的El Ni(~n)o事件讨论了引起这种机制的可能原因--西风异常的作用.最后,对1964～1993所有的El Ni(~n)o年的风场、次表层海温和海表温度的异常进行了综合分析.     

Connections Between Different Types of El Ni~no and Southern/Northern Oscillation

It has long been acknowledged that there are two types of El Ni(n)o events,i.e.,the eastern Pacific El Ni(n)o (EE) and the central Pacific El Ni(n)o (CE),according to the initial position of the anomalous warm water and its propagation direction.In this paper,the oceanic and atmospheric evolutions and the possible mechanisms of the two types of El Ni(n)o events were examined.It is found that all the El Ni(n)o events,CE or EE,could be attributed to the joint impacts of the eastward advection of warm water from the western Pacific warm pool (WPWP) and the local warming in the equatorial eastern Pacific.Before the occurrence of CE events,WPWP had long been in a state of being anomalous warm,so the strength of eastward advection of warm water was much stronger than that of EE,which played a major role in the formation of CE.While for the EE events,most contribution came from the local warming of the equatorial eastern Pacific.It is further identified that the immediate cause leading to the difference of the two types of El Ni(n)o events was the asynchronous variations of the Southern Oscillation (SO) and the Northern Oscillation (NO) as defined by Chen in 1984.When the transition from the positive phase of the NO (NO+) to NO- was prior to that from SO+ to SO-,there would be eastward propagation of westerly anomalies from the tropical western Pacific induced by NO and hence the growth of warm sea surface temperature anomalies in WPWP and its eastward propagation.This was followed by lagged SO-induced weakening of southeast trade winds and local warming in the equatorial eastern Pacific.These were conducive to the occurrence of the CE.On the contrary,the transition from SO+ to SO- leading the transition of NO would favor the occurrence of EE type events.