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61.
Zi-Fu Zhao Yong-Fei Zheng Chun-Sheng Wei Fu-Kun Chen Xiaoming Liu Fu-Yuan Wu 《Chemical Geology》2008,253(3-4):222-242
The crustal structure of the Dabie orogen was reconstructed by a combined study of U–Pb ages, Hf and O isotope compositions of zircons from granitic gneiss from North Dabie, the largest lithotectonic unit in the orogen. The results were deciphered from metamorphic history to protolith origin with respect to continental subduction and exhumation. Zircon U–Pb dating provides consistent ages of 751 ± 7 Ma for protolith crystallization, and two group ages of 213 ± 4 to 245 ± 17 Ma and 126 ± 4 to 131 ± 36 Ma for regional metamorphism. Majority of zircon Hf isotope analyses displays negative εHf(t) values of − 5.1 to − 2.9 with crust Hf model ages of 1.84 to 1.99 Ga, indicating protolith origin from reworking of middle Paleoproterozoic crust. The remaining analyses exhibit positive εHf(t) values of 5.3 to 14.5 with mantle Hf model ages of 0.74 to 1.11 Ga, suggesting prompt reworking of Late Mesoproterozoic to Early Neoproterozoic juvenile crust. Zircon O isotope analyses yield δ18O values of − 3.26 to 2.79‰, indicating differential involvement of meteoric water in protolith magma by remelting of hydrothermally altered low δ18O rocks. North Dabie shares the same age of Neoproterozoic low δ18O protolith with Central Dabie experiencing the Triassic UHP metamorphism, but it was significantly reworked at Early Cretaceous in association with contemporaneous magma emplacement. The Rodinia breakup at about 750 Ma would lead to not only the reworking of juvenile crust in an active rift zone for bimodal protolith of Central Dabie, but also reworking of ancient crust in an arc-continent collision zone for the North Dabie protolith. The spatial difference in the metamorphic age (Triassic vs. Cretaceous) between the northern and southern parts of North Dabie suggests intra-crustal detachment during the continental subduction. Furthermore, the Dabie orogen would have a three-layer structure prior to the Early Cretaceous magmatism: Central Dabie in the upper, North Dabie in the middle, and the source region of Cretaceous magmas in the lower. 相似文献
62.
Xiaoan Zuo Halin Zhao Xueyong Zhao Yirui Guo Yulin Li Yayong Luo 《Environmental Geology》2008,54(5):1111-1120
A survey was conducted in an 11-year recovery mobile dune (RMD11) and a 20-year recovery mobile dune (RMD20), in Horqin Sandy
Land, Northern China, to determine plant distribution at the mobile dune scale and its relevance to soil properties and topographic
features. The results showed that (1) vegetation cover and species number increased from dune top to bottom in the restoration
process of mobile dune; (2) the average value of soil organic C, total N, pH, relative height of sampling site, very fine
sand content and soil water contents (40−60 and 60−80 cm) of RMD11 were less than that of RMD20, respectively, and there were
significant differences (P < 0.05) between the two dunes; (3) soil resources were redistributed by shrub restoration and relative height of sampling
site on dune. The distribution of sand pioneer plant, Agriophyllum squarrosum, was positively related to the relative height of sampling site and soil water content, while that of other herbaceous plants
was positively related to soil nutrients in the restoration process of mobile dune. These results suggest that at mobile dune
scale, plant distributions are determined by a combination of soil properties and topographic feature. Much effort should
be made to preserve the interdune lowland and to improve the level of soil nutrients on mobile dune. 相似文献
63.
Quick-look assessments to identify optimal CO2 EOR storage sites 总被引:1,自引:0,他引:1
Vanessa Núñez-López Mark H. Holtz Derek J. Wood William A. Ambrose Susan D. Hovorka 《Environmental Geology》2008,54(8):1695-1706
A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of
reservoirs to generate a workable set of sites that closely match the requirements for optimal CO2 enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO2 EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities
of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that
the CO2 EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO2 sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of
technical and practical feasibility for miscible CO2 EOR. The second stage provides quick estimates of CO2 EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set
of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties,
disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow
in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves
time and allows more resources to be applied to the best candidate sites. 相似文献
64.
On CO<Subscript>2</Subscript> fluid flow and heat transfer behavior in the subsurface,following leakage from a geologic storage reservoir 总被引:1,自引:0,他引:1
Karsten Pruess 《Environmental Geology》2008,54(8):1677-1686
Geologic storage of CO2 is expected to produce plumes of large areal extent, and some leakage may occur along fractures, fault zones, or improperly
plugged pre-existing wellbores. A review of physical and chemical processes accompanying leakage suggests a potential for
self-enhancement. The numerical simulations presented here confirm this expectation, but reveal self-limiting features as
well. It seems unlikely that CO2 leakage could trigger a high-energy run-away discharge, a so-called “pneumatic eruption,” but present understanding is insufficient
to rule out this possibility. The most promising avenue for increasing understanding of CO2 leakage behavior is the study of natural analogues. 相似文献
65.
Curtis M. Oldenburg 《Environmental Geology》2008,54(8):1687-1694
A screening and ranking framework (SRF) has been developed to evaluate potential geologic carbon dioxide (CO2) storage sites on the basis of health, safety, and environmental (HSE) risk arising from CO2 leakage. The approach is based on the assumption that CO2 leakage risk is dependent on three basic characteristics of a geologic CO2 storage site: (1) the potential for primary containment by the target formation; (2) the potential for secondary containment
if the primary formation leaks; and (3) the potential for attenuation and dispersion of leaking CO2 if the primary formation leaks and secondary containment fails. The framework is implemented in a spreadsheet in which users
enter numerical scores representing expert opinions or published information along with estimates of uncertainty. Applications
to three sites in California demonstrate the approach. Refinements and extensions are possible through the use of more detailed
data or model results in place of property proxies. 相似文献
66.
Laura Chiaramonte Mark D. Zoback Julio Friedmann Vicki Stamp 《Environmental Geology》2008,54(8):1667-1675
This paper reports a preliminary investigation of CO2 sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk
of CO2 leakage along reservoir-bounding faults. CO2 injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically
fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone
is evaluated as the target horizon for a pilot CO2 EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical
model of the Tensleep Formation has been developed to evaluate the potential for CO2 injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault
geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic
risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage
pathway. This would correspond to a CO2 column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed
100 m. It is therefore apparent that CO2 injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to
establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock. 相似文献
67.
Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in
the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project,
were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and
international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir
exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin
water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their
mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results
would help develop water resource management and conservation strategy for the interbasin water transfer project. 相似文献
68.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146
The low-temperature heat capacity (C
p) of Si-wadeite (K2Si4O9) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical
properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured
heat capacity data is 253.8 ± 0.6 J mol−1 K−1, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the
system K2O–Al2O3–SiO2 are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil
experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between
the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order
approximations were undertaken to calculate the phase diagram in the system K2Si4O9 at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously
published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure
phase relations of the K2Si4O9 polymorphs.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
69.
H2O-undersaturated melting experiments of synthesized basalt (SiO2 = 50.7 wt.%, MgO = 8.3 wt.%, Mg# = 60) were conducted at fO2 corresponding to NNO+1 and NNO−1 to clarify the effects of pressure (2–7 kbar) and H2O on fractional crystallization in island arcs. H2O content was ranged from nominally anhydrous to 4.4 wt.%. Differentiation trends, namely the liquid lines of descent, change
sensitively according to pressure-H2O relations. Tholeiitic differentiation trends are reproduced with H2O ≤ ∼2 wt.% in primary magma. With such quantities of H2O, fractional crystallization is controlled by olivine + plagioclase at 2 kbar. Increasing the pressure from 2 to ≥4 kbar
induces early crystallization of orthopyroxene instead of olivine and therefore SiO2 enrichment in the residual melts is suppressed. Increasing H2O (≥ ∼2 wt.% in primary magma) stabilizes clinopyroxene relative to orthopyroxene and/or magnetite. Although the phase relations
and proportions strongly depend on fO2 and H2O content, differentiation trends are always calc-alkaline. 相似文献
70.
Serena C. Tarantino Michele Zema Tiziana Boffa Ballaran Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76
High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li2VOSiO4, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature.
Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V
0 and K
0 using the data weighted by the uncertainties in V. The bulk modulus is K
0 = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K
0(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K
0(a) = 195 ± 3 GPa). 相似文献