质量传输和同位素交换:流动几何学和交换机制

耦合的质量传输和动力学限制的同位素交换模型综合考虑了平流、扩散、热液弥散 ,以及岩石与水之间的不平衡同位素交换等项因素。把耦合模型应用于 2个构造环境下的古热液系统 ,进而解释稳定同位素数据。对于造成环绕浅成侵入岩体分布的18O亏损环带的流体的流动几何学 ,以及浅部正断层流体流动的几何学 ,耦合模型提供了不同于单一同位素交换模型的解释。耦合模型也提供了关于同位素相对交换速率和同位素交换机制的信息。结果表明 ,断层带的动态重结晶促进了表面反应 ,进而便利了同位素交换 ;在化学不反应性和未变形的矿物中 ,同位素交换可能受制于固态条件下的扩散。     

海底天然气渗漏形成水合物量的线性动力学模型:以墨西哥湾GC185区块Bush高地为例

世界许多地区如墨西哥湾，存在着大量天然气渗漏并形成水合物的现象，出于科学，生态，气候和安全的需要。人类有必要弄清存在于海底以水合成形式存在的天然气的比例。因此，构建了水合物形成量的线性动力学模型，以分析墨西哥湾GC185块区Bush高地海底渗漏天然气的地质过程和行为。Bush高地渗漏的天然气来源于附近的Jolliet气藏，结果表明，渗漏天然气中约有9％的海底形成了水合物。     

25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.     

油压夯管锤蓄能器与活塞振动耦合性的数学解析

蓄能器容积的变化与夯管锤的工作过程是紧密联系在一起的，由于活塞的前后运动以及在运动过程中的每一时刻所需要的油量不同的，理想状态就要通过蓄能器的容积变化来调节，就是说蓄能器的容积变化要与夯管锤的冲击振动相耦合。简要介绍了油压夯管锤结构原理，分别解释了油压夯管锤蓄能器与夯管锤的容积压力耦合。     

A methodology for the evaluation of long-term volcanic risk from pyroclastic flows in Campi Flegrei (Italy)

The volcanological history of Campi Flegrei suggests that the most frequent eruptions are characterized by the emplacement of pyroclastic flow and surge deposits erupted from different vents scattered over a 150-km² caldera. The evaluation of volcanic risk in volcanic fields is complex because of the lack of a central vent. To approach this problem, we subdivided the entire area of Campi Flegrei into a regular grid and evaluated the relative spatial probability of opening of vents based on geological, geophysical and geochemical data. We evaluated the volcanic risk caused by pyroclastic flows based on the formula proposed by UNESCO (1972), R=H×V×Va, where H is the hazard, V is the vulnerability and Va is the value of the elements at risk. The product H×V was obtained by performing simulations of type eruptions centered in each cell of the grid. The simulation is based on the energy cone scheme proposed by Sheridan and Malin [J. Volcanol. Geotherm. Res. 17 (1983) 187–202], hypothesizing a column collapse height of 100 m for eruptions of VEI=3 and 300 m for eruptions of VEI=4 with a slope angle of 6°. Each simulation has been given the relative probability value associated with the corresponding cell. We made use of the GIS software ArcView 3.2 to evaluate the intersection between the energy cone and the topography. The superposition of the areas invaded by pyroclastic flows (124 simulations for VEI=3 and 37 for VEI=4) was used to obtain the relative hazard map of the area. The relative volcanic risk map is obtained by superimposing the urbanization maps.     

Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

Nonlinear earthquake response analysis and energy calculation for seismic slit shear wall structures

Based on the concept of structural passive control, a new type of slit shear wall, with improved seismic performance when compared to an ordinary solid shear wall, was proposed by the authors in 1996. The idea has been verified by a series of pseudo-static and dynamic tests. In this paper a macro numerical model is developed for the wall element and the energy dissipation device. Then, nonlinear time history analysis is carried out for a 10-story slit shear wall model tested on a shaking table. Furthermore, the seismic input energy and the individual energy dissipated by the components are calculated by a method based on Newmark-β assumptions for this shear wall model, and the advantages of this shear wall are further demonstrated by the calculation results from the viewpoint of energy. Finally, according to the seismic damage criterion on the basis of plastic accumulative energy and maximum response, the optimal analysis is carried out to select design parameters for the energy dissipation device.     

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架     

帕隆藏布河流纵剖面演化的最小功模式

河流地貌最小功原理表明河流纵误时面形态将向力示使流速增大的方向演化，据此推导出矩形流域全程流速的平均值（u^-）与河流纵误时面形态指数（N）的关系式：u^∝-f(N)={1/2-1/[(N 1)(N 2)]}^1/2，f(N)被称为流速函数。这一最小功模式表明河流纵剖面演化方向是N由小变大。以西藏帕隆藏布中上游流域系统、干流全程及Ⅰ级阶地为例，由最小功模式计算的全程流速均值与实测值相吻合，从而检验了上述最小功原理和数学模式。