内陆盆地的盐分布与平衡分析研究

在总结已有研究成果和系统分析水文、土壤、灌溉、水盐监测资料的基础上,应用系统分析方法、水盐运移理论和水盐平衡原理,通过对盆地、流域、灌区、农田和土壤剖面等不同层次盐分分布与盐平衡分析计算,分析了内陆盆地不同层次的“干排盐”形成与特征,认为干排盐是必不可少的,必须系统地考虑不同层次干排盐出路与动力条件,才能有效地治理灌区盐渍化问题。     

水稻灌区节水灌溉的尺度效应

探讨了节水灌溉尺度问题,指出产生节水灌溉尺度现象的原因是由于灌溉过程中回归水的重复利用.结合漳河灌区的实际,讨论了水稻种植区在不同尺度下的水平衡要素及其在节水尺度效应中的作用;说明随尺度的增大,水平衡过程变得复杂化,节水尺度效应现象也更突出.利用漳河灌区田间试验数据和灌区长系列的历史资料,分别从田间、中等、灌溉干渠和灌区共四个尺度,定量地分析了水稻节水灌溉对水分生产率以及水分利用率的影响.结果表明,节水灌溉技术的采用不仅可以提高田间尺度的灌溉水分生产率,也促进了漳河灌区灌溉水分生产率的整体上升.     

东中国海海温的一维模式研究

根据近海深度浅、热容量小的特点，建立了一个一维能量平衡模式，对东中国海年平均海温进行了模拟。模式较好地模拟出了平均海温的经向分布与纬向分布情况，结果与观测基本相符。同时还检验了模式对海温年际变化的模拟能力，得到了较好的结果。最后简要分析了能量平衡模式应用在近海上的优缺点。     

土壤热异常对地表能量平衡影响初探

将来自土壤深部的热通量引入off line的陆面过程模式 (NCAR—LSM ) ,通过长达 2a的数值试验对比分析了它对各层次土壤温度和地表能量平衡的影响。　　在土壤底部引入 5W /m2 的热通量使底层土壤显著升温 ,但升温随着接近表层而迅速衰减。积分 3个月后 ,由地下进入地表的热流量增幅可达 1W/m2 以上 ,并持续增大到 5W /m2 ,地表最大升温约 0 .5K ,同时地表感热、蒸发潜热及长波辐射通量均有 1W /m2 左右的正异常 ;若将土壤热传导系数放大一个量级以加速热量交换 ,则地表升温提高到 1K以上 ,长波辐射增加 3W /m2 以上 ,超过了气溶胶全球平均的辐射效应。结果表明 :一定量值的土壤热异常对地表能量平衡和短期气候变化 (10 -1～ 10 1a)有着不可忽略的影响。同时 ,深入的资料分析、完善的陆面过程模式以及它与大气模式的耦合试验也是亟待进行的相关工作。     

青藏高原对其东北侧干旱形成的数值试验

应用再分析资料，指出高原边界层内存在北高南低偶极子型涡旋对的独特气候现象。根据当雄站1998年5月31日至6月4日感热通量的连续观测资料，确定了高原热力作用的时变特征，分别用不同的理想高原初始涡度场加定常热源强迫和时变热源强迫代入正压准地转涡度模式，研究了高原东北侧干旱的形成。认为有三种过程在起着重要作用，它们是：基流对上游反气旋涡旋的平流输送、南侧气旋涡旋的能量频散以及高原热力强迫引起的频散生成高值系统的增强。     

东南极Lambert冰川-Amery冰架系统平衡通量分布的计算

通过对Lambert冰川盆地(LGB)考察路线上约1 700 km长的LGB剖面和距冰架末端约50 km、长150 km的A剖面, 分别利用GPS冰流速值及雷达测厚值进行冰通量的计算得出:每年流过LGB剖面的冰通量为43.95 Gta-1, 而通过A剖面的冰通量仅为26. 42 Gt*a-1, Amery冰架底部净融化量为7.8 Gt*a-1. 整个Lambert冰川-Amery冰架系统(LAS)地区的表面净物质平衡总量约为90 Gt*a-1; LGB地区的表面净物质平衡总量为46 Gt*a-1. 通过分析得出, 整个LAS地区及LGB地区均处于物质正平衡状态, 而LAS流域的上游区域S'则处于物质负平衡状态.     

Heat flow and thermal modeling of the Yinggehai Basin, South China Sea

Geothermal gradients are estimated to vary from 31 to 43 °C/km in the Yinggehai Basin based on 99 temperature data sets compiled from oil well data. Thirty-seven thermal conductivity measurements on core samples were made and the effects of porosity and water saturation were corrected. Thermal conductivities of mudstone and sandstone range from 1.2 to 2.7 W/m K, with a mean of 2.0±0.5 W/m K after approximate correction. Heat flow at six sites in the Yinggehai Basin range from 69 to 86 mW/m², with a mean value of 79±7 mW/m². Thick sediments and high sedimentation rates resulted in a considerable radiogenic contribution, but also depressed the heat flow. Measurements indicate the radiogenic heat production in the sediment is 1.28 μW/m³, which contributes 20% to the surface heat flow. After subtracting radiogenic heat contribution of the sediment, and sedimentation correction, the average basal heat flow from basement is about 86 mW/m².Three stages of extension are recognized in the subsidence history, and a kinematic model is used to study the thermal evolution of the basin since the Cenozoic era. Model results show that the peak value of basal heat flow was getting higher and higher through the Cenozoic. The maximum basal heat flow increased from 65 mW/m² in the first stage to 75 mW/m² in the second stage, and then 90 mW/m² in the third stage. The present temperature field of the lithosphere of the Yinggehai Basin, which is still transient, is the result of the multistage extension, but was primarily associated with the Pliocene extension.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

A New Model for Heat Flow in Extensional Basins: Estimating Radiogenic Heat Production

Radiogenic heat production (RHP) represents a significant fraction of surface heat flow, both on cratons and in sedimentary basins. RHP within continental crust—especially the upper crust—is high. RHP at any depth within the crust can be estimated as a function of crustal age. Mantle RHP, in contrast, is always low, contributing at most 1 to 2 mW/m² to total heat flow. Radiogenic heat from any noncrystalline basement that may be present also contributes to total heat flow. RHP from metamorphic rocks is similar to or slightly lower than that from their precursor sedimentary rocks. When extension of the lithosphere occurs—as for example during rifting—the radiogenic contribution of each layer of the lithosphere and noncrystalline basement diminishes in direct proportion to the degree of extension of that layer. Lithospheric RHP today is somewhat less than in the distant past, as a result of radioactive decay. In modeling, RHP can be varied through time by considering the half lives of uranium, thorium, and potassium, and the proportional contribution of each of those elements to total RHP from basement. RHP from sedimentary rocks ranges from low for most evaporites to high for some shales, especially those rich in organic matter. The contribution to total heat flow of radiogenic heat from sediments depends strongly on total sediment thickness, and thus differs through time as subsidence and basin filling occur. RHP can be high for thick clastic sections. RHP in sediments can be calculated using ordinary or spectral gamma-ray logs, or it can be estimated from the lithology.     

层控夕卡岩型矿床成矿系统的元素活动性及质量迁移--以铜陵冬瓜山铜矿床为例

应用改善了的质量平衡方程研究冬瓜山层控夕卡岩型铜矿床成矿系统的元素活动性及质量迁移，结果表明：系统中Zr,Hf,Y和Nb为不活动元素，其余均为活动元素。主量元素中仅CaO为迁出组分，其质量迁移量为84％，其余均为带入组分，带入量最大的SiO2的质量迁移量高达2384％；稀土元素均为带入组分，其中，中稀土较轻稀土和重稀土的活动性更强；其它微量元素中，带入序列由强到弱为：Cr→Ta→Sn→Th，迁出序列由强至弱依次为：U→Sb→Ni—Sr→Ba→Bb→Co→W；成矿元素Cu和Ag为带入组分，其中Cu的带入量最大，质量迁移量高达1200％。本文还得出两点具普适性认识：①稀土元素较其它微量元素对体系条件的变化更为敏感，且往往表现出明显的规律性变化，能更好地示踪地质地球化学过程。②不同元素在不同体系中的行为特征差异极大，仅凭经验判定某一元素为不活动元素往往不可靠。因此，在开展质量平衡研究时，首先采用适当方法确认体系的不活动元素是一项不可或缺的前提工作。