Heat capacity and phase equilibria of wadeite-type K2Si4O9

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

南海温跃层基本特征及一维预报模式

根据现有1907—1990年南海大面调查资料,按1°×1°网格进行逐月的标准水层的温度统计。在此基础上采用3次样条函数的插值方法计算出整个南海温跃层的深度、厚度和强度并予以相应分析。分析表明,南海温跃层主要分为两种类型:第一类为辐射型,主要分布在南海北部的陆架区内,季节变化显著;第二类为不同水体叠置型,主要分布在广大深水区,它长年存在,季节变化较小。一种温跃层的一维积分预报模式,该模式是基于忽略热平流作用和水平热扩散的前提下,从局部热平衡方程出发,建立了受海面热收支及风混合作用下求解温度垂直分布及温跃层的时空变化。在南海北部水深约300m处进行了单站温跃层后报,结果表明,温跃层的深度、厚度和强度的相对误差均在30％以下。     

胶州湾东北部岸滩改造方案的讨论

本文根据胶州湾东北部岸滩目前污染严重、脏乱不堪的现状及城市总体规划的要求.提出了胶州湾东北部岸滩的改造意见.着重从海洋动力、生态、水量平衡的角度论证了改造工程的必要性和可行性。     

渤海、黄海、东海海面热量平衡的平均状况——Ⅰ.资料处理和计算方法

渤、黄、东海海面热量平衡状况对该海域海洋水文和中国气候有着重要的影响。我们对该海域热量平衡各分量的年平均和年变化进行了计算,并分别就资料处理和计算方法、年平均状况、年变化特征等几个方面进行了分析。本文作为该项研究的第一部分,讨论了所用的资料和计算公式,提出了在稳定温度层结条件下的交换系数的校正方法。     

菲律宾海热含量分布及其变化的初步探讨

本文利用1986年及1987年秋季在菲律宾以东海域进行的CTD观测资料,分析了该海域上层海水热含量分布及变化,得出,热含量由南向北随纬度逐渐增大,这主要是北赤道流引起的等温线自南向北下倾造成的,另外也与南部和北部的冷涡和暖涡有关。本文认为,两年里热含量的差异可能与1986年生成的El Nin有关。另外,北太平洋赤道流体积输送量的变化与菲律宾海热含量的变化也有一定的联系。     

黑潮区台风域海-气热输送量的计算

根据1972和1974年经过黑潮区的两个台风个例,计算和分析了台风各部位在不同的海气条件下热量输送的垂直分布特点。表明,在台风前部信风带中,热量垂直输送限于700hPa以下,在1000hPa处有约167.47—209.34J/(cm~2·h)的最大值,700hPa以上热量向下输送;在台风中心区,热量输送量最大,在1000hPa处接近420J/(cm~2·h),在850hPa附近可能有热输送量的最大值,其上随高度减小;在台风后部偏南气流中,向上热输送量较小;各层最大值不超过84J/(cm~2·h)。     

青岛海陆风三维结构的数值模拟

本文采用 1个陡地形影响修正的三维中尺度流体静力的气象学模式 ,对青岛地区海陆风的日变化规律和三维结构进行了较细致的分析。结果显示 ,青岛有多支海陆风存在 ,且每支海陆风出现的时间、强度和向内陆伸展的距离有很大的不同。这其中沿岸山地的机械和热力作用扮演着重要的角色。在观测站 ,模拟结果和实测资料等方面有较好的一致性。     

Variation in Water Masses on Shelf of Northern Bering Sea in September 2016-2018

Abstract

Based on hydrological data obtained during the 7th to 9th Chinese National Arctic Research Expeditions in the summers of 2016–2018, the main water structure on the shelf of the northern Bering Sea and the volume and heat fluxes of the Bering Strait throughflow were analyzed. Distinct variability was identified in the three Pacific water masses feeding the strait - Anadyr Water (AW), Bering Shelf Water (BSW) and Alaskan coastal water (ACW). Overall, the temperature and salinity of the entire section increased each year, with 2018 showing significant anomalies, i.e., a temperature anomaly of up to 1?°C and a maximum salinity anomaly of 2. From 2016 to 2018, the extent of the ACW gradually narrowed in the eastern part of this section, while the AW expanded eastward each year. The net volume transport through each of the three sections increased poleward from 1.65?Sv to 2.76?Sv, with the AW increasing from 0?Sv to 1.03?Sv, the BSW varying between 0.52–1.65?Sv, and the ACW gradually decreasing from 1.04?Sv to disappearing completely. The net heat fluxes were also poleward, varying between 25.77 TW and 61.50 TW, and showing a significant increase. Significant variations in magnitude and extent were observed in each water mass of the Bering Strait throughflow, which could produce widespread effects in the Arctic Ocean and the global ocean beyond.     

热带西太平洋海洋上层热含量的分布特征及其年际变化的分析

选用海面至20℃等温线所处深度水层的平均温度来表征研究海域海洋上层热含量。利用这一特征值，分析1986—1990年期间热带西太平洋边缘海域海洋上层热含量在秋季的分布特征和年际变化。结果表明：（1）热含量呈南高北低分布，在7．5－22．1°N范围内。以130°E断面为代表，热含量的平均递减率为0．179（℃／纬度）；（2）热含量的分布主要取决于环流系统，其等值线因受黑潮和棉兰老海流的影响而由纬向分布转向经向分布。某些区域因受暖涡及冷涡的影响而呈封闭状分布；（3）热含量的年际变化与E1Nino事件存在着很好的相关性，在E1Nino事件发生期间，热含量变得很低，高热含量（大于26．5℃）海区的分布范围明显缩小。     

Sensitivity of a global ocean model to increased run-off from Greenland

We study the reaction of a global ocean–sea ice model to an increase of fresh water input into the northern North Atlantic under different surface boundary conditions, ranging from simple restoring of surface salinity to the use of an energy balance model (EBM) for the atmosphere. The anomalous fresh water flux is distributed around Greenland, reflecting increased melting of the Greenland ice sheet and increasing fresh water export from the Arctic Ocean. Depending on the type of surface boundary condition, the large circulation reacts with a slow-down of overturning and gyre circulations. Restoring of the total or mean surface salinity prevents a large scale redistribution of the salinity field that is apparent under mixed boundary conditions and with the EBM. The control run under mixed boundary conditions exhibits large and unrealistic oscillations of the meridional overturning. Although the reaction to the fresh water flux anomaly is similar to the response with the EBM, mixed boundary conditions must thus be considered unreliable. With the EBM, the waters in the deep western boundary current initially become saltier and a new fresh water mass forms in the north-eastern North Atlantic in response to the fresh water flux anomaly around Greenland. After an accumulation period of several decades duration, this new North East Atlantic Intermediate Water spreads towards the western boundary and opens a new southward pathway at intermediate depths along the western boundary for the fresh waters of high northern latitudes.