Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

新疆库车县盐水沟北铜矿床地质特征及成因探讨

盐水沟北铜矿区位于新疆库车县北部,其大地构造位置处于塔吉克-塔里木陆块区、塔里木陆块、塔里木北缘隆起、库车前陆盆地,区内构造活动强烈。铜矿床赋存于新近纪中新统康村组第一岩性段,矿体呈层状,严格受地层控制。区内共圈定10个铜矿体,矿石矿物主要为孔雀石、赤铜矿、水胆矾、自然铜等,矿体内无夹石,顶、底板围岩均为褐红色及浅红色粉质泥岩。该矿床为砂岩型铜矿床。     

Geography Deserts: State and Regional Variation in the Formal Opportunity to Learn Geography in the United States, 2005–2015

The formal opportunity to learn geography in the United States is unevenly distributed across space, creating possible geography deserts. Data on the number of exams taken in Advanced Placement Human Geography (APHG) and bachelor’s degrees earned in geography are mapped at the state and regional scales. Normalized rates are ranked and grouped into quintiles. For APHG exams, states in the southeastern region of the United States are in the uppermost quintiles while states in the northeastern region are in the lowermost quintiles. The pattern for bachelor’s degrees in geography is somewhat the spatial inverse of that for APHG.     

海岸破波带内悬沙空间分布试验研究和解析表达式

关于海岸破波带内悬沙浓度水平和垂向分布的研究对于计算海岸输沙率和地形演变具有重要意义。本研究进行了规则波、波群和不规则波三种波浪情况破波带内悬沙浓度的水平和垂向分布的试验测量。试验在大尺度波浪水槽进行,接近实际海岸波况尺度。给出了破波带内多断面悬沙垂向分布的细致测量结果,并以此为基础给出了预报实际海岸破波带内悬沙浓度水平和垂向分布解析表达式,讨论了形成这些分布的物理原因和不同波况、不同破波带区域对分布的影响。     

300 BC-1900 AD无定河流域城镇时空格局演变

通过分析和整理从战国中晚期（约300 BC）至清末（约1900 AD）无定河流域历代县级及以上城址的位置、兴废年代数据,结合行政区划沿革、经济社会发展、政权更迭等资料,分析流域城镇格局的时空演变过程。研究表明：① 受气候周期性波动影响,无定河流域城镇的兴起与衰废具有明显的周期性特征,城镇几何中心的移动轨迹具有明显的“西北—东南”向潮汐性运动特征;② 城址存续年限普遍较短,具有明显的阶段性特征,流域内曾存在过4个阶段性中心城镇,中心城镇移动的方向和过程与城镇几何中心的潮汐性移动过程趋势一致;③ 流域城镇空间格局可分为3种类型,即秦汉与隋唐时期的沿河流谷地分布,宋、明两代的沿边境线与长城分布,以及元、清两代集中于流域下游分布。流域城镇未来的发展布局应重视气候变化对城镇分布的长期影响,关注区域环境的脆弱性,合理安排城镇体系发展规模与布局。     

京津冀协同发展重要地理国情监测研究与应用

文章阐述了开展京津冀协同发展重要地理国情监测的现实背景和意义,依托地理国情普查和常态化监测,结合京津冀一体化发展需求,提出了京津冀协同发展重要地理国情监测的总体思路、研究内容、关键技术和研究方法等,并开展了京津冀地区自然生态空间变化监测、高等级公路和铁路交通网络变化监测、重点大气颗粒物污染源空间分布监测等重要地理国情信息监测研究,成果已经在京津冀地区可持续发展评价、京津冀生态文明建设、空间规划管理等工作中得到了广泛应用。     

Otolith microchemistry indicates regional phylopatry in the larval phase of an amphidromous fish (Gobiomorphus hubbsi)

Knowledge of stock structure is key for the effective management of any fish species. Amphidromous fish, which live and spawn in freshwater but spend a pelagic larval period at sea, have typically been assumed to disperse widely during their larval phase, resulting in populations being sourced from a single unstructured larval pool. We used otolith microchemical analysis to examine the stock structure of bluegill bully (Gobiomorphus hubbsi), a declining amphidromous eleotrid endemic to New Zealand, along the west coast of South Island, New Zealand. Some drainages – even those in close proximity (c. 20?km) – were readily distinguishable based on otolith trace element concentrations, while little structure was evident between other geographically disparate locations. These results indicate that, at least in some cases, locally retained larvae, rather than a single unstructured larval pool, dominates recruitment. Management of bluegill bully and other amphidromous species must therefore consider the possibility of regionally distinct populations.     

浙南近海虾类群落结构及其多样性分析

作者根据2015年11月(秋季)、2016年2月(冬季)、2016年5月(春季)和2016年8月(夏季)对浙南近海进行的渔业资源调查数据,用生物量作为虾类资源分布的数量指标,对该海域虾类的组成、数量分布以及季节变化进行分析。结果显示:该区域共鉴定出虾类30种,隶属于10科21属,以对虾科(Penaeidae)虾类最多,其次为管鞭虾科(Solenoceridae),长臂虾科(Palaemonida)位居第3位。按季节来看,秋季共鉴定虾类27种,各站位平均生物量为6.97 kg/km2,优势种为凹陷管鞭虾(Solenocera koelbeli)、中国毛虾(Acetes chinensis)和中华管鞭虾(Solenocera crassicornis)等3种;冬季鉴定出虾类25种,平均生物量为1.65 kg/km2,优势种为凹陷管鞭虾、扁足异对虾(Atypopenaeus stenodactylus)、日本鼓虾(Alpheus japonicus)、鲜明鼓虾(Alpheus digitalis)、中国毛虾、中华管鞭虾和周氏新对虾(Metapenaeus joyneri)等7种;春季20种,平均生物量为2.22 kg/km2,优势种为戴氏赤虾(Metapenaeopsis dalei)、东海红虾(Metapenaeopsis dalei)和中华管鞭虾等3种;夏季16种,平均生物量为10.36 kg/km2,优势种有鹰爪虾(Trachysalambria curvirostris)和中华管鞭虾等2种。Margalef丰富度指数(D)、Shannon-Wiener多样性指数(H′)和Pielou均匀度指数(J′)秋季均低于冬季。秋冬季受到浙闽沿岸流影响,温度、盐度相对较低,夏季受到台湾暖流外侧影响,温度、盐度相对较高,且各季节间由于瓯江、椒江、飞云江、鳌江等陆源性冲淡水的影响,盐度、温度变化相对较大,使得该区域的物种不得不适应一个跨度较大的温盐范围,广温广盐性种类为主。     

杭州湾中部实测波浪特性分析

利用杭州湾中部一年实测波浪资料,分析该地区的波参数统计变化特性,采用最小二乘法拟合得出相关参数之间的关系式,并统计分析了频谱特性。结果表明:杭州湾中部以小浪和轻浪为主,在各月分布较为均匀,年平均周期为2.97 s;最大一次波浪过程为冷空气影响所致,影响强度大于台风莫拉克;常浪向分布在东北至东南向,其中又以小浪出现较多,对应的波周期以2~4 s为主;强浪向主要分布在西北和东北方向,对应的波周期主要分布在3~5 s;多数特征波参数之间相关关系较好;由谱分析得知风浪占多数,且以单峰为主。研究结果可为相关工程和理论研究提供基础资料。     

利用超快速精密星历约束的北斗卫星实时精密定轨

以广播星历为起算轨道的北斗卫星实时滤波精密定轨往往需要较长收敛时间，针对此，提出利用超快速精密星历约束的实时精密定轨方法。通过MGEX跟踪网全球分布的51个测站连续7 d的实测数据，利用平方根信息滤波对北斗卫星实时精密轨道进行确定，并以3 d解事后轨道作为参考，评估北斗卫星实时滤波轨道精度。结果表明，利用广播星历作起算轨道时，北斗实时滤波轨道平均需要经过15 h收敛才能达到稳定，而新方法在这段时间内轨道变化较为平稳，未出现明显的收敛现象，并且7 d时间内GEO卫星在切向、法向和径向上RMS分别优于2.5 m、20 cm和30 cm，IGSO和MEO卫星在3个方向上分别优于30 cm、15 cm和10 cm。