南极长城站地区现代环境地球化学特征

本文通过环境背景值、风化壳地球化学、对流层(大气气溶胶)地球化学和人为地球化学异常,初步探讨了南极长城站地区的现代环境地球化学特征。分析表明:环境要素固有的地球化学性质、区域环境条件和自然环境演变之间具有深刻的内在联系。     

Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.     

Control of dust emissions by geomorphic conditions, wind environments and land use in northern China: An examination based on dust storm frequency from 1960 to 2003

The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence.     

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 2: a 200-Year Record of Atmospheric Lead-210 Flux Variations and its Palaeoclimatic Implications

Palaeovariations of the atmospheric ²¹⁰Pb flux in Northeast China (Long Gang area, Jilin province), quantified by high resolution ²¹⁰Pb measurements on seasonally laminated sediments of Lake Sihailongwan are presented on decadal scale. The mean flux of unsupported ²¹⁰Pb between 1790 and 1970 for the centre of the lake basin is 517 Bq m⁻² yr⁻¹ with maximum deviations between −23% and +27% of this value. Flux rates above this average were found between 1783 and 1813, around 1836, and between 1860 and 1901. The mean ²¹⁰Pb^exc flux rates derived were clearly lower around 1821, 1908, 1930, and 1953. The ²¹⁰Pb^exc flux reached its minimum of 344 Bq m⁻² yr⁻¹ during the period 1977–1982. The atmospheric flux of unsupported ²¹⁰Pb is correlated with the precipitation frequency during the summer monsoon and shows coinciding variability with geochemical proxies that document the groundwater inflow into the lake. Al₂O₃-rich dust of remote provenance scavenged by wet-deposition in the rainy season is the major carrier of the atmospheric ²¹⁰Pb^exc flux.     

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 1: Hydrological Conditions and Dust Flux

The varved sediments of the dimictic Lake Sihailongwan (Long Gang mountain area, Jilin Province, Northeast China) represent a palaeoclimatic archive which documents the local precipitation frequency during the summer monsoon, and variations in the aeolian flux of dust with their remote sources in the arid and semi-arid regions of inner Asia. Based on a detailed discussion of sediment genesis in Lake SHL, dust flux rates and palaeohydrological conditions were reconstructed on a decadal scale over the past 220 years. The aeolian influx by dry and wet deposition was quantified and characterised in its chemical composition. Photosynthetic production in the lake is positively correlated with the inflow of nutrient-rich groundwater. The groundwater discharge largely reflects the strength of the summer monsoon. Net accumulation rates for biogenic silica were determined for annually laminated sediments from the centre of the U-shaped lake basin based on sediment data. In a Si-balance model of the modern lake, the depositional flux of biogenic silica could be independently quantified on the base of hydrochemical monitoring data. Comparison of the both estimates allowed to asses the focussing of the particle flux in the lake. Though water retention in Lake SHL is rather high (ca. 30 years), changes in the hydrological conditions are sensitively recorded in the sediments because (i) nutrient-rich groundwater discharges into the productive zone of the lake, (ii) a substantial proportion of the total dissolved Si-inventory of the mixed lake (ca. 30%) is annually consumed by diatom growth, and (3) sediment accumulation is substantially focussed towards the flat bottom of the lake basin. The bulk siliciclastic sediment fraction (ca. 75 wt.%) largely originates from influx of dust of remote provenance. In sediment thin-sections, the dry-deposited dust fraction is microscopically identifiable as seasonal silt layer. Aeolian input by wet-deposition shows a distinctly higher variability than the influx of dust by dry-deposition. As diatom production, wet-deposition of dust is positively correlated with the rainfall during the summer monsoon. The inferred positive correlation between rainfall and dust flux during the summer monsoon implies that dust deposition is determined by the out-wash efficiency of mineral particles for a permanent high atmospheric dust concentration over Northeast China in the last 220 years.     

中国北方地区春季气溶胶光学特性地基遥感研究

基于中国北方地区地基太阳直接/散射辐射计观测,分析了2001年春季气溶胶光学厚度、尺度和吸收特性。沙尘期间,气溶胶光学厚度显著升高,而尺度上升,粗粒子浓度显著增加,大气气溶胶表现出中性或异常消光特征。除沙尘活动之外,中国华北地区人为排放也是导致气溶胶光学厚度偏高的一个重要原因。中国沙尘源区气溶胶单次散射反照率小于以往观测和模式结果。北京和香河两地气溶胶光学厚度、Angstrom指数和尺度谱基本相似,说明华北地区人为排放与沙尘活动类似,也表现出区域尺度的特点。由于沙尘气溶胶与人为排放气溶胶相比,折射指数实部偏大、虚部偏小,从而北京地区沙尘期间单次散射反照率明显大于非沙尘期间,特别是在近红外波段,说明沙尘活动不仅可以通过增加气溶胶光学厚度,同时也通过改变气溶胶物理、辐射特性来影响下游地区的气溶胶辐射强迫。     

基于EOS/MODIS资料的沙尘遥感监测模型研究

在EOS MODIS资料可见光波段光谱特性的深入分析的基础上，提出了一种完全用MODIS可见光波段监测沙尘信息的技术方法。充分利用MODIS资料可见光范围波段划分细致的特点，构造了不同的光谱特征判别函数作为决策树的分支，最后用决策树法成功地对几次沙尘暴过程进行了沙尘信息遥感监测。结果表明，该方法具有良好的效果和实用性。     

2001年春季中国北方沙尘暴的环流动力结构分析

通过对2001年春季中国北方5次沙尘暴的高度场，涡度场，散度场和风场的分析，研究了沙尘暴强盛期的环流动力结构。结果表明，在5次沙尘暴强盛期有相似的环流动力结构特征。在沙尘暴强盛期的高度场上，蒙古国有深厚的低值系统，乌拉尔高压发展，其间的强气压梯度是沙尘暴的动力源；低值系统有正涡度中心支持，外围是负涡度区，其间有强涡度梯度带；低值中心伴随有低层辐合高层辐散的垂直结构，易于发生近地面大风和上升气流，有利于地面起沙上扬，形成沙尘暴，大风区与强涡度梯度带一致，强风带切变形成的涡度输送有利于加强低值系统，进而增强风场。     

银川市初夏气溶胶粒子谱分布特征

利用美制APS—3310A型激光粒谱仪，在中国西北城市银川对大气气溶胶粒子进行现场观测，结合气象条件，并通过理论计算分析，给出了银川市初夏大气气溶胶的日变化特征、3种不同粒径粒子分布特点及飘尘谱分布特征，以期为银川市大气污染总量控制方案及对策提供科学依据。