Significance of adakites in petrogenesis of early Silurian magmatism at the Yudai copper deposit in the Kalatag district,NW China

Yudai is a newly discovered copper deposit associated with a porphyritic quartz diorite, in the Kalatag district of the eastern Tianshan, China. SHRIMP U-Pb dating of zircons from the diorite yielded an age of 432 ± 3 Ma. The diorite is peraluminous (ASI = 0.98–1.10), calc-alkaline to tholeiitic with high Al₂O₃ of 16.6–17.7 wt% and Mg^# of 57.4–67.4. Trace element characteristics of the diorite show it is enriched in Ba, K and Sr, and depleted in Nb, Ta, Ti, with a positive Eu anomaly and high Sr/Y and La/Yb ratios. This diorite has positive ε_Nd(t) values ranging from 6.2 to 8.4 with low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.704336 to 0.704450. These geochemical and isotopic characteristics indicate that the adakite-like diorite, associated with the copper mineralization, was emplaced in an island arc setting and resulted from partial melting of subducted oceanic plate in a mantle wedge.     

Re-examining urban region and inferring regional function based on spatial–temporal interaction

Urban system is shaped by the interactions between different regions and regions planned by the government, then reshaped by human activities and residents’ needs. Understanding the changes of regional structure and dynamics of city function based on the residents’ movement demand are important to evaluate and adjust the planning and management of urban services and internal structures. This paper constructed a probabilistic factor model on the basis of probabilistic latent semantic analysis and tensor decomposition, for purpose of understanding the higher order interactive population mobility and its impact on urban structure changes. First, a four-dimensional tensor of time (T)?×?week (W)?×?origin (O)?×?destination (D) was constructed to identify the day-to-day activities in three time modes and weekly regularity of weekday/weekend pattern. Then we reclassified the urban regions based on the space clustering formed by the space factor matrix and core tensor. Finally, we further analysed the space–time interaction on different time scales to deduce the actual function and connection strength of each region. Our research shows that the application of individual-based spatial–temporal data in human mobility and space–time interaction study can help to analyse urban spatial structure and understand the actual regional function from a new perspective.     

曹妃甸围填海工程对近海环境的影响综述

曹妃甸明显的区位优势、独特的地理特征、较强的资源支撑为其成为我国北方天然深水大港提供了必要条件。曹妃甸临港工业区的开发建设将大大加快环渤海经济一体化的进程。规模宏大的曹妃甸围填海工程在带来显著社会经济效益的同时,也对近海环境产生了巨大影响。本文在结合前人调查研究的基础上,对曹妃甸海域概况及围填海工程背景进行了介绍;然后从地貌景观、水沙动力、海洋污染、生物多样性4个方面详细论述曹妃甸围填海工程对近海环境的影响;针对曹妃甸海域生态环境问题,提出加强科学研究、优化评估方法、落实管理制度、注重生态补偿的思考与建议,以期为曹妃甸围填海区域及其周边的可持续发展提供一定的科学依据。     

渤海湾曹妃甸深槽海区地形地貌特征及控制因素

通过研究浅层地震剖面、侧扫声纳和水深地形等数据资料,得出,曹妃甸沙岛的岬角地貌引起深槽海域局部潮流流速增大,甸头前沿深槽区以冲刷为主,最大水深达42 m,刷新了渤海湾最大水深记录,深槽部位的侵蚀量最大,深槽南坡冲刷幅度大于北坡,工程建设后期深槽区侵蚀冲刷程度有变小变缓趋势。早期深槽的形成是由于浅部断层受深部构造影响发生阶梯状错断沉陷,海底地层形成古凹槽,但深槽海底地层沉陷速率略大于沉积速率,使得深槽海域长期保持了渤海湾最大的水深环境。初步得出在历史时期曹妃甸深槽经过2万a以上长期存在,深槽的走向经历了南北向-北东向-北西向的转化过程。认为地质构造、古滦河三角洲演变、海洋水动力作用和人类活动等内外营力作用共同控制了曹妃甸海区地貌体系的发育与演化。达到了研究渤海湾曹妃甸深槽海区地形地貌控制因素和深槽的地质演化的目的,为曹妃甸港的规划、运营期维护和未来发展提供科学依据具有重要意义。     

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.     

Hydrochemical characterization of groundwater in Balad district,Salah Al-Din Governorate,Iraq

The assessment of hydrochemical quality of groundwater is very important to explore its nature and usefulness. In this paper, groundwater quality evaluation is carried out in the Balad district, Salah Al-Din Governorate, Iraq. A total of 28 groundwater samples are collected from shallow tube wells and analyzed for various physicochemical parameters. Groundwater suitability for drinking is evaluated based on the World Health Organization (WHO) and Iraqi standards, and suitability of groundwater for irrigation is assessed based on various hydrochemical parameters. The results reveal that the dominant types of groundwater based on piper diagram are mixed CaMgCl and CaCl. Gibbs ratio indicates that the groundwater in the studied area is affected by the evaporation process. The cation-anion exchange reaction in the studied area demonstrates that 54% of the groundwater samples indicate a direct base (cation-anion) exchange reaction, while 46% of the groundwater samples indicating the chloro-alkaline disequilibrium. Furthermore, generally all of the groundwater samples are unsuitable for drinking and irrigation. Cluster analysis reveals two different groups of similarities between the groundwater samples, reflecting different pollution levels in the studied area.     

大数据环境下内蒙古浩布高地区铅锌多金属矿智能矿产预测研究

传统机器学习算法已广泛应用于矿产预测,但面对地质大数据的高维稀疏、不平衡小样本等特性仍缺乏有效处理和分析的方法,设计适合地质大数据特点的机器学习算法是智能矿产预测亟需解决的新问题。本文以内蒙古浩布高地区的铅锌多金属矿产预测为例,提出了一种面向地质大数据的半监督协同训练矿产预测模型。首先对研究区地质找矿信息和地球化学异常信息进行定量分析,提取断裂构造、二叠系地层、燕山期侵入岩、地层与岩体接触带、围岩蚀变及Pb、Zn、Sn、Cu地球化学异常共9种找矿因子。然后利用递归特征消除法优选找矿因子组合,不包括Sn异常在内的8个找矿因子组合被选为最优组合。最后,利用支持向量机和随机森林算法作为基分类器进行半监督协同训练矿产预测,绘制成矿概率分布图。ROC曲线和预测度曲线分析结果表明,半监督协同训练模型的AUC值和预测效率都高于随机森林和支持向量机模型。研究结果也为大数据环境下的智能矿产预测提供了一种新的思路。     

华北克拉通东缘金岭杂岩体岩浆源区及构造背景:来自岩相学、岩石地球化学及年代学的证据

金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。     

湖南大义山晚侏罗世富硼型成锡矿A型花岗岩成因及地质意义

位于南岭成矿带和钦-杭成矿带(简称钦-杭带)交汇部位的湖南大义山锡矿是南岭地区典型的富硼型锡多金属矿床。为厘清大义山锡矿成矿动力学背景,深化南岭地区钨锡矿成矿机制,本文以大义山成锡矿黑云母二长花岗岩为研究对象,开展了系统的岩石学和地球化学研究。研究发现,大义山锡矿具有富硼的特征,成矿黑云母二长花岗岩发育电气石"囊包",电气石在蚀变矿物中广泛发育,并与锡矿化紧密共生,这些特征表明成矿花岗岩具有富硼的特征,并发生了岩浆热液流体出溶。地球化学分析显示,黑云母二长花岗岩具有较高含量的Al_2O_3 (13.67%～14.00%)、Na_20(3.65%～3.90%)、K_2O(3.49%～4.24%)以及较高的FeO~T/(FeOT+MgO)比值(0.95～0.97)、FeO~T/MgO 比值(18.75～32.69)、A/CNK 比值(1.15～1.26)和 10000 × Ga/Al 比值(3.48～4.08),较低的CaO(0.54%～0.59%)、P_2O_5(0.04%～0.06%)含量和锆饱和温度(716～725℃)。球粒陨石标准化稀土元素配分具有明显的四分组效应,强烈的Eu负异常,微量元素富集Rb、Th、U、Ta和Nd等元素,亏损Ba、Nb、Sr、Eu等元素。表明成矿花岗岩具有高分异的特征,与A2型花岗岩特征相近。Nd-Hf同位素分析显示,黑云母二长花岗岩与南岭地区成锡矿花岗岩及钦-杭带A型花岗岩同位素特征基本一致,表明岩浆主要来源于中元古代壳源物质熔融,并有幔源物质的加入。综合本文及前人研究成果,推测南岭地区燕山期伸展作用与Izanagi俯冲板块开天窗或撕裂有关,在此背景下,软流圈物质上涌,引发下地壳物质熔融,形成了富硼的壳幔源混合型花岗质岩浆。岩浆中较高的硼含量促使岩浆发生强烈的结晶分异,并有利于晚期锡矿的形成。     

西秦岭夏河—合作地区早子沟和加甘滩金矿床石英微量元素特征及意义

西秦岭造山带发育有大量三叠纪的金矿床,早子沟和加甘滩金矿床是其中最典型的两个矿床,其金资源量分别为116 t和154 t,均为特大型金矿床。早子沟、加甘滩金矿床均位于夏河—合作区域性逆冲推覆断裂以南。早子沟赋矿地层为三叠统古浪堤组,赋矿岩石为泥质板岩、条带状硅质板岩及粉砂质板岩;加甘滩矿区出露地层为三叠统隆务河组,金矿体赋存于长石石英变砂岩夹粉砂质板岩岩性段内。加甘滩金矿床的研究程度相对较低,属中低温构造蚀变岩型金矿床;早子沟金矿床研究程度较高,但是对它的成因仍有不同的认识。石英的微量元素地球化学特征能够提供成矿流体来源与演化的信息,通过对早子沟和加甘滩金矿床开展石英的微量元素地球化学特征研究,探讨其成矿流体来源、成矿条件以及石英微量元素对金矿床形成的指示,为西秦岭造山带金矿床成因研究提供重要的信息。早子沟和加甘滩金矿床不同类型矿石中石英具有相似的稀土元素球粒陨石标准化配分曲线,总体表现出轻稀土元素相对富集、重稀土元素轻微亏损的特征,而且轻稀土元素与重稀土元素分馏程度高,重稀土元素内部分馏程度弱。 早子沟金矿床成矿期热液石英中Rb与Li呈负相关,Rb与Cs呈正相关,而加甘滩金矿床热液石英中Rb与Li、Cs相关性不明显,表明早子沟金矿床石英中Li含量随流体含量的增加而减少,而Cs含量随流体含量的增加而增加。大多数样品具有Eu负异常和弱的Ce正异常,表明早子沟和加甘滩金矿床形成于还原环境,成矿温度较低。样品的(La/Yb)_N较大,反映成矿深度相对较浅。石英的Y/Ho值分别为25.14~30.14和23.40~28.94,指示成矿流体与地壳关系密切。大多数石英样品的Th/La和 Nb/La 值小于1,在大陆地壳标准化图解中具有明显的Sc负异常,Cr、W、Pb和U正异常,表明成矿流体富Cl^-,相对富集Cr、W、Pb和U等元素。结合大地构造背景分析,早子沟和加甘滩金矿形成于大陆边缘环境。