化学腐蚀下砂岩三轴细观损伤机理及损伤变量分析

利用CT识别技术对化学腐蚀下的砂岩进行了三轴加载全过程的即时扫描试验，得到了在不同级荷载作用下砂岩的压密、微裂纹萌生、扩展和破裂的CT图像和CT数，分析了砂岩损伤演化的细观机理。同时，建立了一个基于化学腐蚀影响和CT数的损伤变量模型。     

广东茂名高岭土煅烧实验研究

对茂名高岭土进行煅烧，结合X-射线衍射、扫描电子显微镜分析，得到了茂名高岭土在不同温度点煅烧的性能参数，并确定出其非晶化转变的温度是550℃。同时对煅烧过程中的煅烧温度、恒温时间等影响因素进行探讨，结果表明，在茂名高岭土的煅烧过程中，适当延长恒温时间可降低非晶化转变的温度，缩短恒温时间，则非晶化转变温度升高。     

Thermal decomposition of NH4-analcime

The thermal decomposition of ammonium-exchanged natural analcime is characterized by gas chromatography, IR spectroscopy and X-ray diffraction. The de-ammoniation and dehydroxylation proceed in parallel throughout the decomposition, which evidences the instability of the protonated analcime framework. The mechanism of degassing of NH₄-analcime changes throughout its decomposition. At the initial step, the mechanism of de-ammoniation consists in thermal dissociation of NH₄⁺ molecule onto NH₃ and proton (framework OH group) and diffusion of NH₃ out of the structure. Subsequent decomposition and removal of the OH groups lead to a progressive loss of crystallinity. At this step, an apparent activation energy for NH₃ desorption is estimated to be 145(±13) kJ mol^–1. This value is within the upper limit of the activation energy characteristic for the NH₃ desorption from proton centres in large-pore zeolites. At the final step, the adsorption of NH₃ and protons onto the defect centres in the amorphosed aluminosilicate framework results in a significant increase of an apparent activation energy for the de-ammoniation and dehydroxylation up to 270(±20) kJ mol^–1.     

地图扫描数字化的质量分析与评价

通过分析地图扫描数字化的误差因素．运用质量控制图评价学生实验数据质量，能够直观地对学生实验数据做出判断，同时也能比较各个实验小组及班级之间总体实验水平，及时发现实验准备工作中及实验方法本身的有关问题。     

基于扫描矢量化地图数据生产的数据质量控制

概述了基于扫描矢量化GIS数据的生产过程 ,介绍了扫描矢量化质量控制的策略和方法 ,在地图扫描阶段采用栅格图纠正的方法对地图的变形进行纠正 ,以提高矢量化原图的质量 ,在基于扫描矢量化GIS数据的生产过程中 ,可从算法和软件使用工艺方面提高数据的质量     

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.     

Structural properties of (Mn1-x Fe x )Nb2O6 columbites from X-ray diffraction and IR spectroscopy

A suite of (Mn_1-x Fe _x )Nb₂O₆ (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented. The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe²⁺ for the larger Mn²⁺ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by Fe.     

Rb2Ca[B4O5(OH)4]2·8H2O溶解及相转化过程的研究

利用IR光谱和Raman光谱等实验手段,对25℃时Rb2Ca[B4O5(OH)4]2·8H2O的溶解及相转化过程进行了初步探索,结果表明,Rb2Ca[B4O5(OH)4]2·8H2O溶于水后,硼在溶液中主要以B(OH)3和[B(OH)4]-的形式存在,残留固相由开始的无定形水合三硼酸钙,最终部分转变为Ca2[B3O3(OH)5]2·8H2O晶体。     

真三维立体显示技术在不动产登记统一平台中的应用研究

随着国家不动产统一登记制度的实施,城市房屋、林地、草原、土地等不动产统一整合、调查和管理工作迫在眉睫。基于机载多角度倾斜摄影和激光雷达扫描技术的创新,真三维数据可为不动产登记提供真实统一、高精度、多层次的空间载体,保证了城市不动产登记应用创新和制度创新。     

三维激光扫描技术在曲面模型重建中的应用

利用地面三维激光扫描仪对目标物体表面进行多方位、多角度的扫描,可以获取其表面大量且密集的高精度点的三维坐标信息以及反射率信息,将这些信息存储到电脑中,使用专业软件进行处理,再使用建模软件生成建筑物的三维模型。本文所研究的是使用地面三维激光扫描仪,通过高速激光测量方式,快速、全面、精确地获取建筑物表面的三维信息,经过一系列的点云数据处理及模型处理,最终完成曲面模型三维重建的过程。