A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.     

河北省粮食生产发展趋势及其地区差异

河北省2002年粮食作物播种面积为6484.4千hm2,其中小麦占37.8%,玉米39.7%;粮食、棉花、油料的种植比例为15.9:1.0:1.6。北部四地市粮食播面占全省的23.3%,南部七地市76.7%。2002年粮食总产2435.8万t,为1949年的5.2倍;粮食单产3756kg/hm2,为1949年的5.8倍;人均粮食362kg,为1949年的2.4倍。北部地区粮食总产占全省的17.2%,南部地区82.8%。据回归分析与双向差分建模分析,2010年粮食总产可达3087.5万t,粮食单产4478kg/hm2,人均粮食460kg。据灰关联分析,影响粮食总产的主要因子有:粮食单产、农副产品收购价格总指数(1978年=100)、农业机械总动力、农村用电量、农田化肥施用量与有效灌溉面积等。根据笔者预测,若2010年农业机械总动力达8989万kw,农村用电量240.8亿kwh,农田化肥施用量356.1万t,有效灌面4549.2千hm2,则其粮食单产可达4664kg/hm2;若2010年仍保持2000年小麦播面所占比例(0.387),玉米播面所占比例达0.439,则其单产可达4387kg/hm2。     

Measuring the k–S–p relations on DNAPLs migration

Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.     

Land subsidence caused by groundwater exploitation in Suzhou City,China

Suzhou City, located at the lower reaches of the Yangtze River in southeastern Jiangsu Province, is one of the few cities in China which suffer from severe ground settlement. A research project was carried out to investigate this problem. Geological and hydrogeological studies show that there is a multi-layered aquifer system with three distinct, soft mud layers of marine and lagoonal origins. An examination of historical records of groundwater extraction, water levels, and ground settlement shows that the ground subsidence is associated with the continuously increasing groundwater extraction in the deep, confined aquifer. It is believed that the consolidation of the soft mud layers, especially the third layer which is thick and close to the main pumped aquifer, contributes to the ground settlement. A three-dimensional finite difference numerical model representing the multi-layered aquifer system was developed to study the ground settlement in response to groundwater extraction. By calibrating the model with both the measured groundwater level and ground settlement, the aquifer parameters were estimated. The model outputs fit reasonably well with the observed results, which indicates that the numerical model can reproduce the dynamic processes of both groundwater flow and soil consolidation. The hydraulic conductivity of the third mud layer near the center of the ground settlement has been reduced by over 30% in the last 14 years. The gradual deterioration in the hydraulic conductivity of the mud may have significant adverse effect on the sustainable groundwater resource of the deep confined aquifer, since the recharge from the shallow aquifers through the mud layer is the only source of water to the deep aquifer. An analysis of the spatial distributions of groundwater drawdown and ground settlement shows that the area with maximum drawdown is not necessarily the area with maximum ground settlement due to the occurrence of the soft mud layer. A simple reallocation in pumping rates on the basis of the spatial distribution of the thick mud layer could significantly reduce the ground settlement. Electronic Publication     

Numerical models of tectonic deformation at the Baltica–Avalonia transition zone during the Paleocene phase of inversion

Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence.     

Global thermal and dynamical perturbations due to Cretaceous mantle avalanche

The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone.     

地球流体力学的研究与进展

简要介绍中国科学院大气物理研究所七十多年来在理论与计算地球流体力学方面的若干研究及其新的进展.在理论地球流体力学方面,介绍了长波动力学及线性稳定性问题、弱非线性理论及行星波动力学以及用Arnold方法(能量-Casimir方法)研究大气和海洋中各种流体运动的非线性稳定性问题的成果.此外,对扰动演变、扰动和基流相互作用及热带大气动力学中的第二类不稳定条件(CISK)也作了简要的介绍.在计算地球流体力学方面,主要内容包括:用物理观点和数学分析相结合的方法阐述了造成计算紊乱和计算不稳定的机理,论证计算稳定性、算     

自动变形监测系统在地铁结构变形监测中的应用

介绍了以TCA自动化全站仪为基础组成的自动变形监测系统和广州地铁“非地铁施工时地铁结构变形监测”项目的现场方案及优化设计。实际应用表明，该系统稳定可靠，可以胜任地铁结构变形监测的工作。     

对地观测小卫星的相位噪声分析与控制

结合传输型对地观测小卫星一体化设计的特点，介绍了一种用于对地观测小卫星系统的锁相接收机的-构成及原理，并对系统的相位噪声性能进行了详尽的分析，提出了对其相位噪声进行技术控制的方法。通过文中的分析与研究，消除了由于对地观测小卫星相位噪声所引起的系统误码率的恶化，提高了系统的可靠性，为下一步对地观测小卫星的发展与应用打下了良好的技术基础。     

500 hPa气候高度场强度及谱结构的季节变化与半球际差异

用半球气候场强度指数(Ic)及球函数分析改进方案，分析了北、南半球500hPa气候高度场的环流特征，得到如下主要结论：1)半球500hPa气候高度场强度冬强于夏，南半球强于北半球；半球环流向夏季的转换速度北南半球相当，而向冬季的转换北半球较南半球快。2)半球500hPa气候高度场具有简单的球函数谱结构，它们主要由超长波波段的球函数(0≤m、κ≤3，m、κ不全为0)、特别是其中的带状球函数(m=0)构成，因而具有低阶、低维的特征。3)对北半球用约20个重要球函数分量(按-↑rm,κ^*≥0．05％标准)即可相当精确地拟合其500hPa气候高度场，而对南半球仅用10个重要球函数分量即可相当精确地拟合其500hPa气候高度场；因此，北半球气候高度场球函数谱结构较南半球复杂。4)北半球500hPa气候高度场的季节变化较南半球明显。