多元统计在化探数据分析中的应用——以沂源县鲁村镇崮山村地区土壤化探测量为例

地球化学元素的多元统计分析可以推测地球化学元素在复杂的成矿过程中的组合及演化特征,从而为预测找矿提供有用的微观信息。应用多元统计方法,对沂源县鲁村镇崮山村地区土壤、岩石地球化学测量数据进行研究分析,得出:与中国东部岩石丰度对比,研究区岩石背景特征为Au,Ag,Pb,Sb,As,Hg元素富集,Cu,Zn贫化;与山东省土壤背景值对比,研究区土壤背景值中Au,Ag,Cu,Pb,Zn元素都出现了不同程度的富集。区内成矿元素组合特征表现为:Ag,Pb,Zn元素之间相关性较强,其中Ag、Pb元素之间的相关性最强,反应出了组合成矿的可能性;而Au与其他元素几乎不具相关性,Cu元素与Ag,Pb,Zn元素均具有弱相关性。通过因子分析得出成矿元素的富集与矿化过程大致可以划分3个阶段:Ag-Pb-Zn元素组合的富集与矿化;Cu元素的富集与矿化;Au元素的富集与矿化;反映出了该区多期富集或蚀变矿化特点。利用因子得分圈定元素组合异常,通过异常分析,并结合地质背景、地质构造特征,最终圈定找矿有利靶区,为进一步找矿提供了科学依据。     

Three dimensional elasto‐plastic interface for embedded beam elements with interaction surface for the analysis of lateral loading of piles

This paper presents a numerical formulation for a three dimensional elasto‐plastic interface, which can be coupled with an embedded beam element in order to model its non‐linear interaction with the surrounding solid medium. The formulation is herein implemented for lateral loading of piles but is able to represent soil‐pile interaction phenomena in a general manner for different types of loading conditions or ground movements. The interface is formulated in order to capture localized material plasticity in the soil surrounding the pile within the range of small to moderate lateral displacements. The interface is formulated following two different approaches: (i) in terms of beam degrees of freedoms; and (ii) considering the displacement field of the solid domain. Each of these alternatives has its own advantages and shortcomings, which are discussed in this paper. The paper presents a comparison of the results obtained by means of the present formulation and by other well‐established analysis methods and test results published in the literature. Copyright © 2016 John Wiley & Sons, Ltd.     

Probabilistic analyses of soil consolidation by prefabricated vertical drains for single‐drain and multi‐drain systems

Natural soils are one of the most inherently variables in the ground. Although the significance of inherent soil variability in relation to reliable predictions of consolidation rates of soil deposits has long been realized, there have been few studies that addressed the issue of soil variability for the problem of ground improvement by prefabricated vertical drains. Despite showing valuable insights into the impact of soil spatial variability on soil consolidation by prefabricated vertical drains, available stochastic works on this subject are based on a single‐drain (or unit cell) analyses. However, how the idealized unit cell solution can be a supplement to the complex multi‐drain systems for spatially variable soils has never been addressed in the literature. In this study, a rigorous stochastic finite elements modeling approach that allows the true nature of soil spatial variability to be considered in a reliable and quantifiable manner, both for the single‐drain and multi‐drain systems, is presented. The feasibility of performing an analysis based on the unit cell concept as compared with the multi‐drain analysis is assessed in a probabilistic context. It is shown that with proper input statistics representative of a particular domain of interest, both the single‐drain and multi‐drain analyses yield almost identical results. Copyright © 2016 John Wiley & Sons, Ltd.     

AUSTRALIS: A new tool for the study of isotopic systems and geochronology in mineral systems

AUSTRALIS (AMS for Ultra Sensitive TRAce eLement and Isotopic Studies) is a microbeam accelerator mass spectrometry (AMS) system designed for in situ microanalysis of geological samples for trace elements and radiogenic and stable isotope data. The AMS method eliminates molecular and isobaric interferences in in situ mass spectrometric measurements, opening up new opportunities in geochronology and tracer applications. Tests have been carried out for measurements of Pb, S and Os isotopes, conducted mainly at 1.5 MV accelerating voltage. In Pb and S tests, precision as high as 0.3‰ has been obtained, made possible by a fast isotope switching system to counter the effect of instabilities in the ion source and beam transport system. In trace‐element analysis, a detection limit for Au at the sub‐ppb level was obtained.     

琼东南盆地深水区钻井岩屑稀土元素地球化学特征及其对沉积物源和环境的指示

对琼东南盆地深水区YL19A钻井岩屑样品进行了稀土元素(REE)地球化学特征分析,旨在研究琼东南盆地深水区的沉积物源及古环境变化。钻井岩屑样品的球粒陨石标准化REE配分模式总体呈轻稀土(LREE)富集、重稀土(HREE)亏损的右倾式,但在各时代地层之间表现出一定的差异。崖城组和陵水组岩屑呈明显的Eu正异常,而梅山组、三亚组和黄流组岩屑呈Eu的弱负异常,指示了沉积环境和沉积物源上的变化。在早渐新世时期,研究区物源以来自周边凸起的火山碎屑和陆源碎屑为主,沉积环境为海陆过渡相;自渐新世晚期开始,随着琼东南盆地全区发生海侵,研究区水深逐渐加大,沉积环境由海陆过渡相变为浅海相,物源变为远源陆源物质,并具有红河与海南岛多物源混合的特征,红河沉积物对物源的贡献相对较大,基性火山物质对物源的贡献减弱。YL19A钻井岩屑的REE地球化学特征在距今30、28.5、25.5和23.8Ma等地层界面处均发生明显的突变,对区域性构造运动事件有明显的响应。     

海水中大分子有机质对铂族元素的吸附动力学研究

Adsorption kinetics of the interaction between Pt, Pd and Rh(defined here as platinum group elements, PGEs)ions and macromolecular organic compounds(MOCs, 10 kDa), including humic acid, carrageenan and bovine serum albumin, and different cutoff fractions of natural organic matter(1 kDa and 3 kDa) obtained from seawater using centrifugal ultrafiltration devices were investigated. For a given element, all the adsorption kinetics did not reach equilibrium except the interaction between Pt and 1 kDa cutoff, and between Pd and humic acid.For all the tested MOCs, the adsorption kinetics could be divided into two stages, a rapid adsorption process in the first 8 h and the desorption stage after the first 8 h until the equilibrium. The change trend of partition coefficient(log_(10)K_d) values with experiment time was consistent with that of the kinetic curves. However, in the interaction between PGE ions and natural dissolved organic matter(NDOM), an obvious difference in the change trends of log_(10)K_d and kinetic curves was observed. It indicated that the partition behavior of PGE ions interacting with NDOM in seawater was a combined effect of different organic constituents. The adsorption and log_(10)K_d of PGEs in the 1 kDa NDOM fraction were higher and more stable than those in the 3 kDa NDOM fraction. The results also indicated that the 1–3 kDa NDOM may dominate the interaction between PGEs ions and NDOM. Moreover, no kinetic model could perfectly simulate the adsorption process. It indicated that the colloidal struction and morphology of MOCs or NDOM in seawater might be inhomogeneous. Hence, the interaction between PGE ions and organic matter in seawater was a complicated process and needs further research.     

台湾以东黑潮沉积物中的生源要素对近千年来气候环境变化的响应

基于台湾以东黑潮主流系沉积物中碳、氮、磷等生源要素指标的变化，在沉积物年代学的基础上，探讨了近千年来气候环境变化在黑潮沉积物中的历史记录。结果表明，近千年来台湾以东、琉球岛弧南侧斜坡的黑潮主流区平均沉积速率可达34.2 cm/ka，据其变化可大致分成的3个沉积阶段，与中世纪暖期、小冰期和现代暖期的划分基本一致。沉积物中碳以无机碳为主，总无机碳（TIC）的含量从1850年开始逐渐增大并伴随剧烈波动，恰好与大气CO₂水平的快速升高相对应；总有机碳（TOC）含量的变化则与东亚夏季风强度的变化关系密切，在夏季风较弱的小冰期其含量明显高于夏季风较强的中世纪暖期和现代暖期，这是由于较弱的夏季风有利于亚洲大陆风尘的产生和向海输送，从而促进了研究海域的初级生产力。1850年以来，沉积物中的C∶N∶P逐渐从低于转变为高于Redfield比，反映了上层水体营养盐结构从氮缺乏到氮充足的转变，这与近现代以来急剧增加的全球氮排放密切相关。总体来说，黑潮主流系沉积物中的生源要素指标，明确记录和响应了近千年来的气候环境变化，尤其是近150多年以来不断加剧的人类活动所造成的气候环境剧变。     

相对轨道根数的重轨InSAR卫星基线分析与控制

星载重轨干涉SAR卫星在高程测绘和形变测量中有着全天时全天候和大范围的优势,其中干涉基线是决定干涉性能的重要指标,而卫星重访轨道对干涉基线起着决定性的作用。通过对现有高分三号干涉数据轨道参数的分析,发现干涉基线相比国外先进卫星过长且稳定性有待提高。本文通过对相对轨道根数和机动控制的分析,得到满足重轨干涉SAR系统要求的稳定基线。以第一次观测的轨道为参考轨道,基于在摄动情况下重复观测轨道与参考轨道的相对轨道根数,计算得到重轨干涉基线的变化规律,并对不同纬度的观测目标进行了样例分析。在基线变化规律的基础上,利用机动速度和相对轨道根数的关系,进一步计算得到满足基线状态需求的机动控制方法。通过实际数据分析,给出了相对轨道根数变化对初始理想构型的影响,验证了重轨干涉基线变化规律符合本文的分析,并利用仿真样例给出了使得重轨干涉基线达到预期要求的机动控制方案。实际数据和仿真实验表明该模型能够通过可长时间观测并准确获得的轨道根数直接计算基线状态,并能从干涉基线需求出发,快速准确的得出对卫星的控制策略。     

南海神狐海域表层沉积物稀土元素地球化学

南海神狐海域表层沉积物稀土元素总量变化较大,分布范围为66.8～218.3μg/g,平均值为128.1μg/g,相对接近于中国黄土(w(∑REE)=170.66μg/g);∑REE受"粒度效应"控制,主要富集于黏土质粉砂中;各类沉积物及与中国黄土、上陆壳和珠江口沉积物的稀土元素标准化曲线的变化趋势基本一致,表明这些沉积物具有相同的物源区,且具有大陆地壳性质。铈的负异常主要受陆源源区气候环境变化控制,而与海水关系不大。∑REE与CaO、CaCO3和Sr元素呈负相关,与Al2O3、K2O、SiO2呈正相关,表明稀土元素与生物作用基本无关,可能主要吸附于黏土矿物表面和赋存于陆源碎屑矿物的晶格中。     

Orbital imprint on Holocene palaeohydrological variations in west‐central Europe as reflected by lake‐level changes at Cerin (Jura Mountains,eastern France)

This paper presents a lake‐level record for the Holocene at Lake Cerin (Jura Mountains, eastern France). It is based on a range of sedimentological techniques validated in previous studies, with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin, and sediment analyses of two selected cores. The chronology is based on 10 radiocarbon dates and pollen stratigraphy. On a millennial scale, the Cerin lake‐level record shows three distinct successive phases characterised by higher lake‐level conditions until ca. 9000 cal. a BP, followed by a maximal lowering at ca. 9000–8500 cal. a BP, and a progressive rise until the present. This rise was punctuated by centennial‐scale fluctuations, with major events around 4000, 2800 and after 1500 cal. a BP. Considered on a multimillennial scale, the general pattern of palaeohydrological changes reconstructed at Cerin reflects the impact of orbitally driven summer insolation. This is in agreement with other regional and extra‐regional palaeoclimatic records, although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction. In this general context, centennial to multicentennial oscillations appear to have been second‐order events in comparison with the major influence of the orbital factor. Copyright © 2011 John Wiley & Sons, Ltd.