Composition of selected heavy metals in road dust from Kuala Lumpur city centre

This study was carried out in order to determine the concentration of heavy metals, e.g., lead (Pb), cadmium (Cd), copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), nickel (Ni) and chromium (Cr) in road dust in Kuala Lumpur’s city centre. Samples were collected from four sampling locations, each of which had four sampling points and three replications. Heavy metals from different fractions of particles separated by different diameter sizes: d < 63 μm (Fraction A), 63 < d < 125 μm (Fraction B) and 125 < d < 250 μm (Fraction C) were analyzed using inductively coupled plasma mass spectrometry. The results from this study showed that concentration of heavy metals was dominated by the smallest particle size: <63 μm and that Fe was the most abundant heavy metal overall, followed by Cu > Mn > Zn > Pb > Ni > Cr > Cd. The fact that Cd had the highest enrichment factor value (EF) for all particle sizes indicates that anthropogenic activities contributed to the presence of this metal. There was also a higher EF value for heavy metals in small particle (Fraction A), compared to Fraction B and C, which suggests that fine particles were being produced through anthropogenic activities. Cluster analysis and principal component analysis demonstrated the likelihood of the heavy metals detected in the road dust, originating from road traffic and industrial activities.     

Tilted and non-tilted Gödel-type universe

This paper explores the dynamics of Gödel-type geometry for tilted and non-tilted congruences. The kinematical as well as dynamical quantities are investigated for both congruences with non-vanishing nature of vorticity vector. The obtained vorticity is of kinematical type, i.e., not produced by a circular flow of superenergy on the plane orthogonal to the vorticity vector. We conclude that super-Poynting vector is non-zero for the tilted congruence linked with heat flux of fluid distribution while it vanishes in non-tilted case.     

Hohlraum Targets Driven by Cluster Ion Beams for Inertial Confinement Fusion

Correlated ion stopping of charged debris resulting from the fragmentation of energetic cluster ions focussed on Au foam converters is considered for driving indirectly a thermonuclear capsule. The 1D simulation of converter time evolution demonstrates a very high conversion efficiency of projectile energy into hard X-ray photons building up a very hot (T_r > 300 eV) thermal bath. Intense and energetic cluster ion beams thus demonstrate considerable potential as a novel driver for inertial confinement fusion.     

Improvement in Engineering Properties of Expansive Soils using Ground Granulated Blast Furnace Slag

Improvement in engineering properties of expansive soils by mixing ground granulated blast furnace slag (GGBFS) is the main focus of this research. For this purpose two expansive soil samples were collected from DG Khan and Sialkot areas (Pakistan). Classification tests revealed that DG Khan sample belonged to fat clay (CH) while Sialkot soil was lean clay (CL) as classified by Unified Soil Classification System. GGBFS has been added in varying proportions between 0 and 55% in these soil samples to study its role in stabilizing these expansive soils. Based on the laboratory test performed on composite soil samples, it was observed that maximum dry unit weight increased up to 10 % by adding 50% GGBFS in both samples. California bearing ratio (CBR) value showed an increase from 3.2 % to 11.5% for DG Khan soil while CBR values varied from 2.4% to 10.7% for Sialkot soil by mixing 50% GGBFS. Addition of 30 % GGBFS to DG Khan soil reduced swell potential from 8 % to 2 % while in Sialkot soil, 20 % addition of GGBFS reduced swell potential from 5 % to 2 %. Unconfined compressive strength of remoulded sample cured for 28 days increased by about 35% with the addition of 30%GGBFS. The results indicated that mixing of GGBFS in the expansive soil samples have a marked increase in their engineering properties. Also, it is an affective and environmental friendly means to dispose waste of steel industry.     

Residual impact of biochar on cadmium uptake by rice (<Emphasis Type="Italic">Oryza sativa</Emphasis> L.) grown in Cd-contaminated soil

Cadmium (Cd) is the family member of toxic heavy metals, and its accumulation in food crops has become a global environmental constraint. Biochar potentially minimizes the metal contents in plants, but limited work has been reported on its residual effect on subsequent crops. The residual effect of various biochar levels (0, 1.5, 3.0, and 5.0% w/w) on Cd accumulation in rice has been investigated in this study. Biochar treatments enhanced the rice growth, photosynthesis, and antioxidant enzymes, whereas diminished the Cd contents and oxidative stress in rice. Cadmium concentration in shoots decreased by 24.4, 36.6, and 57.5% in 1.5, 3.0, and 5.0% biochar treatments over the control. Biochar supply enhanced the soil pH and electrical conductivity, whereas diminished the soil bioavailable Cd. Overall, the results depicted a significant residual impact of rice straw biochar on rice growth attributes and Cd uptake. However, studies are still needed to explore the long-term sustainability of biochars prepared from different feedstocks on bioavailability of toxic metals in soils and uptake by food crops under field conditions.     

Laboratory planetary physics using intense heavy ion beams at the Facility for Antiprotons and Ion Research at Darmstadt: the HEDgeHOB collaboration

Development of ultra-high power lasers has lead to the very interesting and important field of Laboratory Astrophysics. Recent progress and expected near future developments in the technology of strongly bunched intense particle beams has opened up the possibility of studying planetary interiors in the laboratory which hopefully will eventually converge in the new field of Laboratory Planetary Physics. GSI Helmholzzentrum für Schwerionenforschung, Darmstadt is a well known laboratory worldwide due to its unique particle accelerator facilities. Construction of the new huge accelerator complex, the Facility for Antiprotons and Ion Research (FAIR), will substantially improve the existing capabilities of the GSI. A dedicated program named, HEDgeHOB, that aims to study different problems in High Energy Density (HED) Physics at the FAIR facility, has been proposed. One of these proposed experiments LAPLAS (LAboratory PLAnetary Science), aim to study materials at extreme conditions as relevant for the interiors of giant planets. In this paper we present simulation results that show that various regions of the high-pressure phase diagram of water can be probed within the LAPLAS experiments. For instance, the plasma and the superionic phase are predicted to occur in the interior of water-rich planets such as Uranus and Neptune as well as in extrasolar planets such as GJ 436b.     

Comparison of two snowmelt modelling approaches in the Dudh Koshi basin (eastern Himalayas,Nepal)

Abstract

The glaciers in the Nepalese Himalayas are retreating due to rising temperatures. Lack of data and information on Nepal’s cryosphere has impeded scientific studies and field investigations in the Nepalese Himalayas. Therefore, IRD France and Ev-K2 CNR Italy have conducted the PAPRIKA (CryosPheric responses to Anthropogenic PRessures in the HIndu Kush-Himalaya regions: impacts on water resources and society adaptation in Nepal) project in Nepal with the financial support of the French and Italian scientific agencies. This project aims to address the current and future evolution of the cryosphere in response to overall environmental changes in South Asia, and its consequences for water resources in Nepal. Thus, two hydrological models, the GR4J lumped precipitation–runoff model and the snowmelt runoff model (SRM), were used in the Dudh Koshi basin. The GR4J model has been successfully applied in different parts of Europe. To obtain better results in such a harsh and rugged topography, modifications needed to be made, particularly in the snow module. The runoff pattern is analysed herein both for past years and, in a sensitivity analysis, for possible future climatic conditions (i.e. precipitation and temperature) using the SRM and GR4J modelling approaches. The results reveal a significant contribution of snow- and glacier-melt to runoff, and the SRM model shows better performance in Nepalese catchments than the GR4J model.

Editor D. Koutsoyiannis; Associate editor D. Gerten     

Chemical study of limestone and clay for cement manufacturing in Darukhula,Nizampur District,Nowshera, North West Frontier Province （N.W.F.P.）, Pakistan

Limestone and clay samples were collected from Darukhula and adjoining areas of the Nizampur District Nowshera, N.W.EE, Pakistan, and analyzed for different parameters in order to search for new reserves of suitable material for the manufacture of different types of cements in N.W.F.P. It was found that the area under study contains three types of limestones, including high grade limestone, Darukhula limestone and siliceous limestone, which contain 53%, 49.03% and 45.19% CaO, respectively, and three types of clay, including maroon color, yellow to yel- lowish-green color and green color clay containing 57.76%, 65.47% and 61.24% SiO2, respectively. Chemical analysis of the limestone and clay samples collected from the deposits in the area under study showed that all the elements found in these samples are within the range of permissible limits for the production of high-strength Portland cement, sulphate resisting cement and white cement. This paper covers the detailed version of the potential raw material deposits at Darukhula and adjoining areas of the Nizampur District.     

Complexation and reduction as factors in the link between metal ion concentrations and organic matter in the Indian River

Complexation of metal ions by organic matter is frequently considered to play a part in metal ion dissolution in natural waters. A field study of a relatively unperturbed stream, high in organics, associates this with the fraction related to soil organic acids (humic acids). The association might have two origins. The first is complexation. However, well known sequences of complexing tendency do not predict the behaviour. A better theory uses the additional factor of the reducing capacity of dissolved organic matter toward Fe(III) and Mn(IV).